以中国川西地区发现的一种新型矿物资源微晶白云母为原料,以铝酸酯偶联剂F-1为改性剂,对微晶白云母进行改性研究,并将表面改性后的微晶白云母加入聚氯乙烯（PVC）中制得微晶白云母/PVC复合材料。测试了改性粉体与石蜡体系的黏度及复合材料的力学性能,并采用扫描电子显微镜表征了其微观结构。结果表明,铝酸酯偶联剂F-1能有效改善微晶白云母表面与有机物质的界面结合,并且将经铝酸酯偶联剂F-1改性的微晶白云母加入PVC基体中能提高微晶白云母/PVC复合材料的力学性能,当铝酸酯偶联剂的用量为1.0%（质量分数,下同）、微晶白云母用量为15%时,微晶白云母/PVC复合材料的力学性能最好。
The micro-crystal muscovite is a new kind of minerals found in west Sichuan area. The surface of the micro-crystal muscovite powders was modified by aluminate coupling agent F-1 and was added into plasticized poly （vinyl chloride） （PVC）. The viscosity of the modified micro-crystal muscovite powders/paraffin was tested. The structure and mechanical properties of micro-crystal muscovite/PVC composite were studied by SEM and tesl：er. The results show that aluminate coupling agent F-I can effectively improve the interracial bond strength of micro-crystal muscovite and the organic matter, and the micro-crystal muscovite modified by aluminate coupling agent F-1 can improve mechanical properties of PVC. When aluminate coupling agent F-1 is 1.0 % and the micro-crystal muscovite content is 15 %, the mechanical properties of micro-crystal museovite/PVC composites materials are great.
参考文献
| [1] | Kemal, I;Whittle, A;Burford, R;Vodenitcharova, T;Hoffman, M .Toughening of unmodified polyvinylchloride through the addition of nanoparticulate calcium carbonate[J].Polymer: The International Journal for the Science and Technology of Polymers,2009(16):4066-4079. |
| [2] | Nakamura Y.;Iida T.;Fukuoka Y. .Tensile test of poly(vinyl chloride) filled with ground calcium carbonate particles[J].Journal of Applied Polymer Science,1998(2):311-316. |
| [3] | S.C. Tjong .Structural and mechanical properties of polymer nanocomposites[J].Materials Science & Engineering, R. Reports: A Review Journal,2006(3/4):73-197. |
| [4] | Q.Yuan;R.D.K.Misra .Polymer nanocomposites: current understanding and issues[J].Materials Science and Technology: MST: A publication of the Institute of Metals,2006(7):742-755. |
| [5] | 林金辉,汪灵,邓苗,叶巧明,刘菁,常嗣和,范良明.川西地区微晶白云母的矿物学特征研究[J].矿物岩石,2005(03):14-17. |
| [6] | 叶巧明,汪灵,刘菁,林金辉,邓苗.微晶白云母活性填料的铝酸酯表面改性研究[J].矿物岩石,2005(03):83-87. |
- 下载量()
- 访问量()
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%