利用高锰酸钾和硫酸锰溶液之间的化学共沉淀法制备出氧化锰作为超级电容器的活性电极材料.通过循环伏安法和恒流充放电法,研究了不同热处理温度获得的氧化锰电极,不同循环次数以及不同放电电流条件下,在1mol/L Na2SO4水溶液中的电容特性.结果表明,经低温处理的氧化锰在电位窗口为-0.2~+0.8 V(vs SCE)范围内,表现出典型的电容行为.其中经45℃和80℃处理的氧化锰在放电电流为7.32mA/cm2条件下,比容量分别为147.97F/g和112.26F/g.80℃处理的氧化锰电极循环性能较好.
参考文献
[1] | Conway B E .Transition from "supercapacitor" to "battery" behavior in electrochemical energy storage[J].Journal of the Electrochemical Society,1991,138:1539-1548. |
[2] | Burke A .Ultracapacitors:why,how,and where is the technology[J].Journal of Power Sources,2000,91:37-50. |
[3] | 张治安,邓梅根,胡永达,杨邦朝.电化学电容器的特点及应用[J].电子元件与材料,2003(11):1-5. |
[4] | Zheng JP.;Jow TR.;Cygan PJ. .HYDROUS RUTHENIUM OXIDE AS AN ELECTRODE MATERIAL FOR ELECTROCHEMICAL CAPACITORS[J].Journal of the Electrochemical Society,1995(8):2699-2703. |
[5] | Liu KC.;Anderson MA. .POROUS NICKEL OXIDE/NICKEL FILMS FOR ELECTROCHEMICAL CAPACITORS[J].Journal of the Electrochemical Society,1996(1):124-130. |
[6] | Srinivasan V;Weidner J W .Capacitance studies of cobalt oxide films formed via electrochemical precipitation[J].Journal of Power Sources,2002,108:15-20. |
[7] | Pang S.C.;Anderson M.A. .Novel Electrode Materials for Thin-Film Ultracapacitors: Comparison of Electrochemical Properties of Sol-Gel-Derived and Electrodeposited Manganese Dioxide[J].Journal of the Electrochemical Society,2000(2):444-450. |
[8] | Lee H Y;Kim S W;Lee H Y .Expansion of active site area and improvement of kinetic reversibility in electrochemical pseudocapacitor electrode[J].Electrochemical and Solid-State Letters,2001,4:A19-A22. |
[9] | Reddy R N;Reddy R G .Synthesis and electrochemical characterization of amorphous MnO2 electrochemical capacitor electrode material[J].Journal of Power Sources,2004,132:315-320. |
[10] | 罗旭芳,张雪纯,王先友,汪形艳.超级电容器用纳米γ-MnO2制备及性能[J].电池,2004(05):334-336. |
[11] | 于维平,张世超,张驰.复合氧化钼电极的制备和电容特性研究[J].材料热处理学报,2004(03):22-24. |
[12] | Kordesch K V.电池组:二氧化锰[M].北京:中国轻工业出版社,1981:77-81. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%