以凹凸棒石粘土(ATP)为载体,通过酸性溶胶法制备了纳米TiO2/ATP复合催化剂.利用x射线衍射仪(XRD)、扫描电镜(SEM)、分光光度计等手段研究了复合催化剂的形貌、粒径、结构及光催化特性等.结果表明,ATP的加入提高了纳米TiO2晶型转变温度,并有效地抑制了TiO2晶粒的长大,复合体中TiO2晶粒尺寸比采用相同工艺获得的纯TiO2晶粒小,锐钛矿相和金红石相的相变温度分别提高了300℃和350℃.光催化甲醛试验结果证实,复合催化剂的光催化效果明显优于纯TiO2,复合体经850℃煅烧后的光催化效果最佳,甲醛实际降解率达到98%以上,ATP的吸附作用促进了光催化反应的深入进行.
参考文献
[1] | Akira Fujishima;Tata N. Rao;Donald A. Tryk .Titanium dioxide photocatalysis[J].Journal of photochemistry and photobiology, C. Photochemistry reviews,2000(1):1-21. |
[2] | 尚静,徐自力,杜尧国,李静敏.TiO2纳米粒子的结构、表面特性及其光催化活性研究[J].无机材料学报,2001(06):1211-1216. |
[3] | 沈伟韧,赵文宽,贺飞,方佑龄.TiO2光催化反应及其在废水处理中的应用[J].化学进展,1998(04):349-361. |
[4] | 刘吉平;廖莉玲.无机纳米材料[M].北京:科学出版社,2004:17-21. |
[5] | Zhang Z;Wang C C;Zakaria R .Role of particle size in nanocrystafine TiO2-based photocatalysts[J].Journal of Physical Chemistry B,1998,102:10871-10878. |
[6] | Juehidah hobs;Yaneyamah .Photocatalytie decomposition of propyzamide using TiO2 supported on activated carbon[J].Chemistry Letters,2001,22:203-205. |
[7] | Kumar K P .Growth of futile erystallites during the initial stage of anatase-to-rutile transformation in pure titania and in titania-alumina nanocomposites[J].Scripta Materialia,1995,32:873-877. |
[8] | 尹琳,陆现彩,艾飞.Ti-凹凸棒石催化剂对染料废水的臭氧氧化降解的影响[J].硅酸盐学报,2003(01):66-69. |
[9] | 陈天虎.凹凸棒石粘土吸附废水中污染物机理探讨[J].高校地质学报,2000(02):265-270. |
[10] | 陈天虎,王健,庆承松,彭书传,宋垠先,郭燕.热处理对凹凸棒石结构、形貌和表面性质的影响[J].硅酸盐学报,2006(11):1406-1410. |
[11] | 彭书传,谢晶晶,庆承松,陈天虎,徐惠芳,陈菊霞,袁君.负载TiO2凹凸棒石光催化氧化法处理酸性品红染料废水[J].硅酸盐学报,2006(10):1208-1212. |
[12] | 周广宏,韩涛,丁红燕,林岳宾.纳米TiO2/凹凸棒土复合体的制备及其表征[J].煤炭学报,2007(03):314-316. |
[13] | 王丽敏;经丽洁;李阳 等.废水中甲醛含量的测定[J].吉林化工学院学报,1998,15(02):32-35. |
[14] | Basa R R;Kiwi J .Atomic force microscopy and ellipsometry study of the nucleation and growth mechanism of polyerystalline silicon films on silicon dioxide[J].Appl Catal B Environment,1998,16:19-29. |
[15] | Matyi R J;Schwartz L H;Butt J B .Particle size,particle size distribution and related measurements of supported metal catalysts[J].Catalysts Review Soience and Engineering,1987,29:41-99. |
[16] | Masanori Hirano;Chiaki Nakahara;Keisuke Ota et al.Photoaetivity and phase stability of ZrO2-doped anataze-type TiO2 directly formed as nanometor-sized particles by hydrolysis under hydrothermal conditions[J].Journal of Solid State Chemistry,2003,170:39-47. |
[17] | 杜敬梅 .纳米凹凸棒土性质及其改性机理的研究[D].北京化工大学,2004. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%