在N2+H2还原气氛中以ZnO粉末为原料制备了ZnO:Zn发光膜和粉末.利用X射线衍射、电子扫描显微镜、红外光谱仪、XPS、荧光分光光度计等测试手段表征了样品的结构、形貌、缺陷和发光性能.ZnO:Zn发光膜具有六角纤锌矿晶体结构和良好的c轴取向,结晶性较好,晶粒颗粒均匀.ZnO:Zn发光膜和粉末具有绿色的单谱光致发光和电致发光.发光薄膜的O1s结合能表明,此绿色发光与薄膜内的点缺陷状态密切相关.
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