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采用离子交换树脂法吸附铬(Ⅲ),通过树脂选型确定强酸性阳离子交换树脂001×14.5对铬(Ⅲ)吸附容量最大,用所选的001×14.5树脂研究铬(Ⅲ)的吸附性能.静态吸附实验表明:转速大于120 r/min时,对树脂吸附的影响可忽略,即外扩散基本消除,pH=7.0时,吸附最佳,铬(Ⅲ)吸附率随树脂用量的增加而增大;001×14.5树脂吸附铬(Ⅲ)的过程符合Langmuir等温曲线,且为优惠吸附;吸附过程符合拟二级动力学方程,吸附过程的表观活化能Ea=23.4 kJ/mol,颗粒内扩散为吸附速率的主要控制步骤;用1 mol/L的硫酸对吸附后的饱和树脂进行脱附再生,脱附率可达99%.

参考文献

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