采用离子交换树脂法吸附铬(Ⅲ),通过树脂选型确定强酸性阳离子交换树脂001×14.5对铬(Ⅲ)吸附容量最大,用所选的001×14.5树脂研究铬(Ⅲ)的吸附性能.静态吸附实验表明:转速大于120 r/min时,对树脂吸附的影响可忽略,即外扩散基本消除,pH=7.0时,吸附最佳,铬(Ⅲ)吸附率随树脂用量的增加而增大;001×14.5树脂吸附铬(Ⅲ)的过程符合Langmuir等温曲线,且为优惠吸附;吸附过程符合拟二级动力学方程,吸附过程的表观活化能Ea=23.4 kJ/mol,颗粒内扩散为吸附速率的主要控制步骤;用1 mol/L的硫酸对吸附后的饱和树脂进行脱附再生,脱附率可达99%.
参考文献
[1] | 范建凤,宋美蓉.腐植酸及其树脂对水中三价铬吸附性能的研究[J].电镀与精饰,2010(02):4-6,33. |
[2] | 裴东波,卢志强,伉沛崧,亓学梅,薛军,王琳.还原沉淀法处理含铬废水[J].城市环境与城市生态,2006(02):25-26. |
[3] | Barbara Wionczyk;Wieslaw Apostoluk .Solvent extraction of Cr(III) from alkaline media with quaternary ammonium compounds. Part II[J].Hydrometallurgy,2004(3/4):195-203. |
[4] | 梁志冉,涂勇,田爱军,白永刚.离子交换树脂及其在废水处理中的应用[J].污染防治技术,2006(03):34-36. |
[5] | TAYEB R;ZAGHBANI A;TINGRY S;SETA P DHAHBI M .Carrier-mediated trransport of Cr(Ⅲ) across Lasalocid A-NPOE supported liquid membrane[J].Desalination,2007,204(1/3):234-240. |
[6] | 范娟,詹怀宇.木素磺酸盐树脂对六价铬的吸附实验研究[J].湖南大学学报(自然科学版),2009(10):59-62. |
[7] | Jian Hua Chen;Guo Ping Li;Qing Lin Liu .Cr(III) ionic imprinted polyvinyl alcohol/sodium alginate (PVA/SA) porous composite membranes for selective adsorption of Cr(III) ions[J].Chemical engineering journal,2010(2):465-473. |
[8] | Gode F;Pehlivan E .Sorption of Cr(III) onto chelating b-DAEG-sporopollenin and CEP-sporopollenin resins[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2007(4):904-911. |
[9] | JUANG Ruey-shin;LIN Su-hsia;WANG Tsung-yuan .Removal of metal ions from the eomplexed solutions in fixed bed using a strong-acid ion exchange resin[J].Chemosphere,2003,53(10):1221-1228. |
[10] | RENGARAJ S;YEON K H;KANG S Y;LEE J U KIM K W MOON S H .Studies on adsorptive removal of Co(Ⅱ),Cr(Ⅲ)and Ni(Ⅱ) by IRN77 cation-exchange resin[J].Journal of Hazardous Materials,2002,92(02):185-198. |
[11] | Ibrahim Narin;Yavuz Surme;Mustafa Soylak;Mehmet Dogan .Speciation of Cr(Ⅲ) and Cr(Ⅵ) in environmental samples by solid phase extraction on Ambersorb 563 resin[J].Journal of hazardous materials,2006(3):579-584. |
[12] | M.M. Hassanien;I.M. Kenawy;A.M. El-Menshawy;A.A. El-Asmy .A Novel Method For Speciation Of Cr(iii) And Cr(vi) And Individual Determination Using Duolite C20 Modified With Active Hydrazone[J].Journal of hazardous materials,2008(1):170-176. |
[13] | 郭崇武,王吉民.镀铬溶液中六价铬和三价铬的快速测定[J].电镀与精饰,2006(04):50-52. |
[14] | 张慧.分光光度法测定铬的改进[J].宁波大学学报(理工版),2002(02):42-44. |
[15] | NAMASIVAYAM C;RANGANATHAN K .Removal of Cd(Ⅱ)from wastewater by adsorption on "waste" Fe(Ⅲ)/Cr(Ⅲ)hydroxide[J].Water Research,1995,29(07):1737-1744. |
[16] | HO Y S;JOHN W D A;FORSTER C F .Batch nickel removal from aqueous solution by Sphagnum moss peat[J].Water Research,1995,299(05):1327-1332. |
[17] | 孟冠华,刘宝河,郑俊,李爱民.水杨酸修饰聚苯乙烯对Pb2+和Cu2+的吸附[J].应用化学,2009(02):219-223. |
[18] | Zacaria Reddad;Claire Gerente;Yves Andres;Pierre Le Cloirec .Adsorption of several metal ions onto a low-cost biosorbent: kinetic and equilibrium studies[J].Environmental Science & Technology: ES&T,2002(9):2067-2073. |
[19] | 北川浩;铃木谦一郎.吸附的基础与设计[M].北京:化学工业出版社,1983:51-55. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%