通过对贵州毕节地区两个处于不同石漠化等级条件下的洞穴朝营洞(潜在)与韩家冲洞(强度)滴水的滴率与元素进行了为期1年的监测,分析了各洞穴上覆的土壤、基岩元素,探讨了滴水的元素来源及其石漠化效应.结果表明,朝营洞上覆土壤元素Ca、Mg、Sr含量高于韩家冲洞;朝营洞滴水Ca2+、Mg2+、Ba2+、Sr2+平均浓度分别为60.81、3.24、0.012、0.085 mg·L-1,韩家冲洞滴水分别为58.39、2.47、0.01、0.074 mg·L-1;地表石漠化程度越严重,洞穴滴水滴率对大气降雨的响应越敏感,季节变幅越大,滴水元素受到上覆基岩的贡献程度越高;受地表石漠化效应的差异影响,朝营洞滴水元素离子浓度呈现出雨季高旱季低的变化规律,而韩家冲洞滴水元素离子浓度呈现出雨季低,旱季高的变化规律.
The elements source and rocky desertification effect of drip water were explored in caves under different rocky desertification, which are Chaoying Cave ( potential) and Hanjiachong Cave ( intense) in Bijie, Guizhou. An in situ monitoring was carried out on their drip elements and drip rates throughout a year to analyze the overlying soil and bedrock elements respectively. Results indicated that the contents of Ca, Mg and Sr in the overlying soil of Chaoying Cave were higher than those of Hanjiachong Cave. The mean concentrations of Ca2+, Mg2+, Ba2+and Sr2+in the drip water were 60. 81, 3. 24, 0. 012 and 0. 085 mg·L-1 in Chaoying Cave and 58. 39, 2. 47, 0. 01 and 0.074 mg·L-1 in Hanjiachong Cave. Drip rates responded more sensitively to rainfall along with more severe surface rocky desertification. The overlying bedrock contributed more to drip water elements when the seasonal variation was large. Ion concentration of drip water in Chaoying Cave rose in the rainy season and fell in the dry season, while in Hanjiachong Cave the pattern was opposite. This was attributed to the discrepancy of surface rocky desertification effect.
参考文献
[1] | 袁道先.我国岩溶资源环境领域的创新问题[J].中国岩溶,2015(02):98-100. |
[2] | 熊康宁;池永宽.中国南方喀斯特生态系统面临的问题及对策[J].生态经济,2015(1):23-30. |
[3] | Huang YM.;Fairchild IJ..Partitioning of Sr2+ and Mg2+ into calcite under karst-analogue experimental conditions[J].Geochimica et Cosmochimica Acta: Journal of the Geochemical Society and the Meteoritical Society,20011(1):47-62. |
[4] | Wong, C.I.;Banner, J.L.;Musgrove, M..Seasonal dripwater Mg/Ca and Sr/Ca variations driven by cave ventilation: Implications for and modeling of speleothem paleoclimate records[J].Geochimica et Cosmochimica Acta: Journal of the Geochemical Society and the Meteoritical Society,201112(12):3514-3529. |
[5] | Fairchild, IJ;Treble, PC.Trace elements in speleothems as recorders of environmental change[J].Quaternary Science Reviews,20095/6(5/6):449-468. |
[6] | Helen Rutlidge;Andy Baker;Christopher E. Marjo;Martin S. Andersen;Peter W. Graham;Mark O. Cuthbert;Gabriel C. Rau;Hamid Roshan;Monika Markowska;Gregoire Mariethoz;Catherine N. Jex.Dripwater organic matter and trace element geochemistry in a semi-arid karst environment: Implications for speleothem paleoclimatology[J].Geochimica et Cosmochimica Acta: Journal of the Geochemical Society and the Meteoritical Society,2014:217-230. |
[7] | Baldini, J.U.L.;McDermott, F.;Baldini, L.M.;Ottley, C.J.;Linge, K.L.;Clipson, N.;Jarvis, K.E..Identifying short-term and seasonal trends in cave drip water trace element concentrations based on a daily-scale automatically collected drip water dataset[J].Chemical geology,2012:1-16. |
[8] | Zhou Yunchao;WANG Shijie;XIE Xingneng;LUO Weijun;LI Tingyu.Significance and dynamics of drip water responding to rainfall in four caves of Guizhou, China[J].科学通报(英文版),2005(02):154-161. |
[9] | LI JunYun;LI TingYong;WANG JianLi;XIANG XiaoJing;CHEN YunXuan;LI Xuan.Characteristics and environmental significance of Ca, Mg, and Sr in the soil infiltrating water overlying the Furong Cave, Chongqing, China[J].中国科学:地球科学(英文版),2013(12):2126-2134. |
[10] | 陈松;桂和荣;孙林华.安徽宿州地区石灰岩-土壤元素迁移及质量评价?[J].环境化学,2013(6):987-992. |
[11] | 王德炉;朱守谦;黄宝龙.石漠化过程中土壤理化性质变化的初步研究[J].山地农业生物学报,2003(3):204-207,213. |
[12] | 周运超;王世杰.贵州将军洞上覆土层对滴水水化学特征的影响[J].环境科学,2006(10):1986-1991. |
[13] | Karmann I;Cruz FW;Viana O;Burns SJ.Climate influence on geochemistry parameters of waters from Santana-Perolas cave system, Brazil[J].Chemical geology,20071-2(1-2):232-247. |
[14] | Tatar E;Mihucz VG;Zambo L;Gasparics T;Zaray G.Seasonal changes of fulvic acid, Ca and Mg concentrations of water samples collected above and in the Beke Cave of the Aggtelek karst system (Hungary)[J].Applied Geochemistry: Journal of the International Association of Geochemistry and Cosmochemistry,200411(11):1727-1733. |
[15] | 刘肖;杨琰;彭涛;赵景耀;任小凤;张银环;聂旭东;李建仓;凌新有;张志钦.河南鸡冠洞洞穴水对极端气候的响应及其控制因素研究[J].环境科学,2015(5):1582-1589. |
[16] | 沈蔚;王建力;王家录;蒋先淑;毛庆亚;陈挚秋;刘肖.贵州纳朵洞洞穴水水文地球化学变化特征及其环境意义[J].环境科学,2015(12):4455-4463. |
[17] | Fairchild IJ.;Tooth AF.;Frisia S.;Hawkesworth CJ.;Huang YM.;McDermott F.;Spiro B.;Borsato A..Controls on trace element (Sr-Mg) compositions of carbonate cave waters: implications for speleothem climatic records[J].Chemical geology,20003-4(3-4):255-269. |
[18] | Huang HM.;Borsato A.;Frisia S.;Cassidy NJ.;McDermott F. Hawkesworth CJ.;Fairchild IJ..Seasonal variations in Sr, Mg and P in modern speleothems (Grotta di Ernesto, Italy)[J].Chemical geology,20013-4(3-4):429-448. |
[19] | 曹建华;袁道先;潘根兴;姜光辉.不同植被下土壤碳转移对岩溶动力系统中碳循环的影响[J].地球与环境,2004(1):90-96. |
[20] | 王明达;胡超涌;周炼;朱昌杰.土壤和围岩地球化学组成及气候对洞穴滴水水化学的影响--以湖北清江和尚洞为例[J].地质科技情报,2010(3):97-103. |
[21] | 衣成城;李延勇;李俊云;王建力;向晓晶;白莹;唐亮亮;谢世友.芙蓉洞洞穴水离子浓度和元素比值变化特征及其环境意义[J].中国岩溶,2011(2):200-207. |
[22] | 曹建华;袁道先;潘根兴.岩溶生态系统中的土壤[J].地球科学进展,2003(1):37-44. |
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