作为一种剧毒元素，汞的毒性与其化学形态密切相关。环境介质中汞的化学形态监测分析主要涉及样品的采集、保存、前处理、分离和测定等步骤。本文综合国内外相关文献，系统介绍了开展环境介质中汞化学形态监测分析的相关测试技术和方法，并阐述了我国开展汞化学形态监测存在的问题及其意义。
As an extremely toxic element, the toxicity of mercury is closely related to its chemical speciation. Chemical speciation monitoring of mercury in environmental media mainly includes sample collection, storage, pretreatment, separation and determination. This brief review focuses on the related technologies and methods for chemical speciation analysis of mercury in environmental samples. The problems and significances of mercury speciation monitoring in china is also put forward.
参考文献
| [1] | Li Y;Yan XP;Dong LM;Wang SW;Jiang Y;Jiang DQ .Development of an ambient temperature post-column oxidation system for high-performance liquid chromatography on-line coupled with cold vapor atomic fluorescence spectrometry for mercury speciation in seafood[J].Journal of Analytical Atomic Spectrometry,2005(5):467-472. |
| [2] | J.L.Capelo;C.Maduro;A.M.Mota .Advanced oxidation processes for degradation of organomercurials:determination of inorganic and total mercury in urine by FI-CV-AAS[J].Journal of Analytical Atomic Spectrometry,2004(3):414-416. |
| [3] | Qiang Tu;Willie Johnson Jr.;Brian Buckley .Mercury speciation analysis in soil samples by ion chromatography, post-column cold vapor generation and inductively coupled plasma mass spectrometry[J].Journal of Analytical Atomic Spectrometry,2003(7):696-701. |
| [4] | 吴宏,黄德乾,金焰,田野,毕树平.环境样品中铅、锑、汞、硒形态分析研究进展[J].环境监测管理与技术,2008(04):9-17. |
| [5] | Thomas W.Clarkson .The Three Modern Faces of Mercury[J].Environmental Health Perspectives,2002(Suppl 1):11-23. |
| [6] | Mergler D;Anderson H A;Chan L H M et al.Methymercury exposure and health effects in humans:A worldwide concern[J].A Journal of the human Environment,2007,36(1):3-11. |
| [7] | Clarkson T W .The toxicology of mercury[J].Critical Reviews in Clinical Laboratory Science,1997,34(4):369-403. |
| [8] | Jitaru P;Adams F .Toxicity, sources and biogeochemical cycle of mercury[J].Journal de Physique.IV,2004(0):185-193. |
| [9] | 童银栋,郭明,胡丹,欧浪波,魏文,张巍,王学军.北京市场常见水产品中总汞、甲基汞分布特征及食用风险[J].生态环境学报,2010(09):2187-2191. |
| [10] | GB 2762-2012.食品安全国家标准食品中污染物限量[S]. |
| [11] | GB/T 17132-1997.环境甲基汞的测定气相色谱法[S]. |
| [12] | DB35/T 895-2009.环境样品中甲基汞、乙基汞及无机汞高效液相色谱-电感耦合等离子体质谱法(HPLC-ICP-MS)测定[S]. |
| [13] | EPA 1630. Methyl Mercury in Water by Distillation, Aqueous Ethylation, Purge and Trap, and CVAFS, EPA-821-R-01-020[S].,2001. |
| [14] | Havezov I .Atomic absorption spectrometry(AAS)-a versatile and selective detector for trace element speciation[J].Fresenius Journal of Analytical Chemistry,1996,355:452-456. |
| [15] | Li-Ping Yu;Xiu-Ping Yan .Factors affecting the stability of inorganic and methylmercury during sample storage[J].TrAC: Trends in Analytical Chemistry,2003(4):245-253. |
| [16] | 商立海,冯新斌,阎海鱼,仇广乐.环境样品中甲基汞的分析方法综述[J].地球与环境,2004(01):17-22. |
| [17] | Ahmed R;Stoeppler M .Storage and stability of mercury and methylmercury in sea water[J].Analytica Chimica Acta,1987,192:109-113. |
| [18] | Method 245.7,Mercury in water by cold vapor atomic fluorescence spectrometry[S].U.S. Environmental Protection Agency of ice of Water, Office of Science and Technology Engineering and Analysis Division (4303), Arid Rios Building, 1200 Pennsylvania Avenue, N. W. Washington,DC 20460,2001. |
| [19] | 余海洋,廖梦霞,邓天龙.水环境中痕量、超痕量元素汞的形态分析技术进展[J].世界科技研究与发展,2006(02):52-56. |
| [20] | 蒋红梅,冯新斌,梁琏,商立海,阎海鱼,仇广乐.蒸馏-乙基化GC-CVAFS法测定天然水体中的甲基汞[J].中国环境科学,2004(05):568-571. |
| [21] | Brito E M S;Guimaraes J R D .Comparative tests on the efficiency of three methods of methylmercury extraction in environmental samples[J].Applied Organometallic Chemistry,1999,13:487-493. |
| [22] | Lee Y H;Mowrer J .Determination of methylmercury in natural waters at the sub-nanograms per litre level by capillary gas chromatography after adsorbent preconcentration[J].Analytica Chimica Acta,1989,221:259-268. |
| [23] | Cai Y;Jaffe R;Alli A et al.Determination of organomercury compounds in aqueous samples by capillary gas chromatography-atomic fluorescence spectrometryfollowing solid-phase extraction[J].Analytica Chimica Acta,1996,334:251-259. |
| [24] | 刘保献,李新中,常淼,邹本东,华蕾.固相萃取-气相色谱法测定饮用水中甲基汞[J].环境监测管理与技术,2011(01):54-56,60. |
| [25] | Heyong Cheng;Chunling Wu;Lihuan Shen.Online anion exchange column preconcentration and high performance liquid chromatographic separation with inductively coupled plasma mass spectrometry detection for mercury speciation analysis[J].Analytica chimica acta,2014:9-16. |
| [26] | Cai Y.;Bayona JM. .DETERMINATION OF METHYLMERCURY IN FISH AND RIVER WATER SAMPLES USING IN SITU SODIUM TETRAETHYLBORATE DERIVATIZATION FOLLOWING BY SOLID-PHASE MICROEXTRACTION AND GAS CHROMATOGRAPHY MASS SPECTROMETRY[J].Journal of chromatography, A: Including electrophoresis and other separation methods,1995(1):113-122. |
| [27] | 史建波,廖春阳,王亚伟,江桂斌.气相色谱和原子荧光联用测定生物和沉积物样品中甲基汞[J].光谱学与光谱分析,2006(02):336-339. |
| [28] | 顾昱晓,孟梅,邵俊娟,史建波,何滨,江桂斌.在线吹扫捕集-气相色谱-原子荧光光谱法测定土壤中甲基汞[J].分析化学,2013(11):1754-1757. |
| [29] | 刘现明;谢立国 .苯萃取-气相色谱法测定沉积物中的甲基汞[J].海洋环境科学,1996,15(2):32-34. |
| [30] | Hempel M;Hintelmann H;Wilken R D .Determination of organic mercury species in soils by high-performance liquid chromatography with ultraviolet detection[J].ANALYST,1992,117(3):669-672. |
| [31] | 孙瑾,陈春英,李玉锋,李柏,高愈希,柴之芳.超声波辅助溶剂萃取-电感耦合等离子体质谱法测定生物样品中的总汞和甲基汞[J].光谱学与光谱分析,2007(01):173-176. |
| [32] | Lorenzo RA.;Carro AM.;Cela R.;Vazquez MJ. .Methylmercury extraction from aquatic sediments - A comparison between manual, supercritical fluid and microwave-assisted techniques[J].TrAC: Trends in Analytical Chemistry,1999(6):410-416. |
| [33] | 何滨,江桂斌.固相微萃取毛细管气相色谱-原子吸收联用测定农田土壤中的甲基汞和乙基汞[J].岩矿测试,1999(04):259-262. |
| [34] | Armstrong HL.;Stockwell PB.;O'Connor G.;Ebdon L.;Evans EH.;Corns WT. .Comparison of AFS and ICP-MS detection coupled with gas chromatography for the determination of methylmercury in marine samples[J].Analytica chimica acta,1999(1/3):245-253. |
| [35] | Harrington C F .The speciation of mercury and orgnomercury compounds by using high-performance liquid chromatography[J].Trends in Analytical Chemistry,2000,19(2/3):167-179. |
| [36] | Jitaru P;Adams FC .Speciation analysis of mercury by solid-phase microextraction and multicapillary gas chromatography hyphenated to inductively coupled plasma-time-of-flight-mass spectrometry[J].Journal of chromatography, A: Including electrophoresis and other separation methods,2004(1/2):197-207. |
| [37] | Garcia,Fernandez-R;Montes,Bayon-M;Garcia,Alonso-JI;Sanz,Medel-A .Comparison of different derivatization approaches for mercury speciation in biological tissues by gas chromatography/inductively coupled plasma mass spectrometry.[J].Journal of Mass Spectrometry,2000(5):639-646. |
| [38] | 朱霞萍,张勇,汪模辉,苏茜,倪师军,何秋玲.毛细管气相色谱法测定生物样品中痕量甲基汞[J].理化检验-化学分册,2006(05):344-346. |
| [39] | Giuseppe C;Elisa B G;Ignacio G A et al.Isotope dilution SPME GC/MS for the determination of methymercury in tuna fish samples[J].Journal of Mass Spectrometry,2006,41:77-83. |
| [40] | Maria JM;Jaime P A;Pabio RG et al.Simultaneous determination of monomethylmercury,monobutyltin,dibutyltin and tributyltin in environmental samples by multi-elemental-species-specific isotope dilution analysis using electron ionisation[J].Journal of Mass Spectrometry,2006,41:1491-1497. |
| [41] | 梁立娜,江桂斌.高效液相色谱及其联用技术在汞形态分析中的应用[J].分析科学学报,2002(04):338-343. |
| [42] | Maximilian Popp;Stephan Hann;Gunda Koellensperger .Environmental application of elemental speciation analysis based on liquid or gas chromatography hyphenated to inductively coupled plasma mass spectrometry-A review[J].Analytica chimica acta,2010(2):114-129. |
| [43] | 颜雪,司友斌,邹嫣,陈宁,颜世红.碱消解-HPLC同时测定土壤中的无机汞和甲基汞[J].环境科学与技术,2012(09):89-93,128. |
| [44] | Timerbaev A R .Element speciation analysis by capillary electrophoresis[J].TALANTA,2000,52:573-606. |
| [45] | Peng ZL;Qu F;Song G;Lin JM .Simultaneous separation of organomercury species by nonaqueous capillary electrophoresis using methanol containing acetic acid and imidazole.[J].Electrophoresis: The Official Journal of the International Electrophoresis Society,2005(17):3333-3340. |
| [46] | Lai EPC.;Trier X.;Georgi A.;Kowalski S.;Kennedy S. MdMuslim T.;Dabek-Zlotorzynska E.;Zhang WG. .Speciation of mercury at ng/ml concentration levels by capillary electrophoresis with amperometric detection[J].Analytica chimica acta,1998(1/3):63-74. |
| [47] | Medina I;Rubi E;Mejuto M C et al.Speciation of organomercurials in marine samples using capillary electrophoresis[J].Tanata,1993,40(11):1631-1636. |
| [48] | Liu W;Lee H K .Simultaneous analysis of inorganic and organic lead,mercury and selenium by capillary electrophoresis with nitrilotriacetic acid as derivation agent[J].Journal of Chromatography A,1998,796:385-395. |
| [49] | Liu W;Lee H K .Use of triethylenetetraminehexaacetic acid combined with field-amplified sample injection in speciation analysis by capillary electrophoresis[J].Analytical Chemistry,1998,70:2666-2675. |
| [50] | Liu W;Lee H K .Simultaneous analysis of lead,mercury and selenium species by electrophoresis with combined ethylenediaminetetraacetic acid complexation and field-amplified stacking injection[J].ELECTROPHORESIS,1999,20:2475-2483. |
| [51] | 卢瑞宏.毛细管电泳汞形态分析[J].广东化工,2006(04):43-45. |
| [52] | 梁立娜,江桂斌,胡敬田.冷蒸气发生-原子荧光光谱法测定化工废水中的无机汞和总有机汞[J].分析化学,2001(04):403-405. |
| [53] | Ariane V Z;Sergio C;Carmen IP et al.Method development for the simultaneous determination of methylmercury and inorganic mercury in seafood[J].FOOD CONTROL,2014,46:351-359. |
| [54] | 殷学锋;刘梅 .在线固相萃取预富集-液相色谱分离冷原子吸收联机测定不同形态汞[J].分析化学,1996,24(11):1248-1252. |
| [55] | 孙维萍,潘建明,翁焕新,朱利中,郑旻辉.环境样品中甲基汞的检测方法综述[J].海洋学研究,2010(02):45-51. |
| [56] | Sommer Y L;Verdon C P;Fresquez M R et al.Measurement of mercury species in human blood using triple spike isotope dilution with SPME-GC-ICP-DRC-MS[J].Analytical Biochemistry,2014,406:5039-5047. |
| [57] | 张兰,陈玉红,施燕支,王英锋,米健秋,张之旭.高效液相色谱-电感耦合等离子体质谱联用技术测定二价汞、甲基汞、乙基汞与苯基汞[J].环境化学,2009(05):772-775. |
| [58] | 李保会,余莉萍,王朝晖,刘礼文,严秀平.基于低流速雾化器和可拆卸接口的毛细管电泳-电感耦合等离子体质谱联用技术应用于汞的形态分析[J].光谱学与光谱分析,2005(08):1336-1338. |
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