将钒钛铁精矿内配碳球团分别进行干燥、750℃和1 000℃焙烧,采用XRD、SEM/EDS、化学分析及强度测试方法,研究了球团在低温焙烧条件下的物相、微观形貌、成分及强度的变化.结果表明:钒钛铁精矿粉、煤粉、水和复合黏结剂按照质量比100∶9∶9∶1.0混合压球,干球团强度较湿球团强度有明显提高;750℃焙烧球团与干球的主要物相差别不大,但Fe3O4衍射蜂强度增加,矿粉颗粒空隙增大,球团强度急剧下降;1000℃焙烧球团主要物相为钛铁晶石(Fe2TiO4)和还原铁,球团收缩,强度增大.
Vanadium and titanium iron concentrate pellets conaining carbon after drying,750 ℃ and 1 000 ℃ roasting had been used to investigate phase,microstructure,composition and intensity change under low temperature calcination by means of XRD,SEM/EDS,chemical analysis and strength testing.The results show that the vanadium and titanium iron ore concentrate,pulverized coal,water,and composite binder mix in accordance with the mass ratio of 100 ∶ 9 ∶ 9 ∶ 1.0,the resulted dry pellets strength is significantly higher than wet pellets.While main phase of pellet roasted at 750 ℃ show no observed difference with that of dry pellet,but XRD result indicate increasing Fe3O4 peak intensity.The gap between the mineral powder particles increases and strength of pellets dramastically decreases.Roasting temperature of 1 000 ℃ generates main phase of pellet composing of Fe2TiO4 and reduced iron,and causes pellets shrinkage and thus strength increase.
参考文献
[1] | 付自碧.钒钛磁铁矿提钒工艺发展历程及趋势[J].中国有色冶金,2011(06):29-33. |
[2] | 杨绍利;马兰;吴恩辉.钒钛磁铁矿非高炉冶炼技术[M].北京:冶金工业出版社,2012:1-3. |
[3] | 胡兵,黄柱成,姜涛,彭虎.微波场中氧化球团升温性能及结构变化[J].中南大学学报(自然科学版),2011(11):3238-3244. |
[4] | 刘云龙,郭培民,庞建明,赵沛.钛铁矿磁化焙烧分离的热力学分析[J].钢铁钒钛,2013(03):8-12. |
[5] | 李彩霞,任瑞晨,廖明义.辽西某膨润土作铁矿球团粘结剂的研究[J].非金属矿,2009(03):42-43,46. |
[6] | 张福顺,赵增武,冯乃祥,常宏涛,李晓刚.内配碳铁铌共生矿冷固结球团强度实验研究[J].稀有金属与硬质合金,2012(02):60-63. |
[7] | 朱德庆,王志远,潘建,李建,徐小锋.巴西某镜铁精粉的烧结特性及强化工艺[J].中南大学学报(自然科学版),2006(05):878-883. |
[8] | 朱德庆,沈文俊,潘建,春铁军.碱度和内配燃料对赤铁矿球团强度的影响[J].金属矿山,2011(06):104-108. |
[9] | 曹明明,张建良,薛逊,邢相栋,王春龙,王喆.钒钛磁铁矿冷压含碳球团的粘结剂选择[J].矿冶工程,2012(05):67-71. |
[10] | 张建良,邢相栋,王春龙,曹明明,任山,焦克新.钒钛磁铁矿金属化球团固结机理研究[J].烧结球团,2012(03):26-30. |
[11] | 张旭,张建良,郭豪,刘征建,柏凌.含碳球团生产工艺参数优化及固结机理研究[J].过程工程学报,2009(z1):25-30. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%