主要研究了不同种类阻燃剂对涂层用环氧树脂的阻燃效率的影响.该环氧树脂由双酚A的二环氧丙醚经胺类固化剂固化而得,用氮气氛下的热重分析(TGA)和锥形量热研究了其热稳定性和阻燃性.本研究中,所用的阻燃剂都是商业化应用的阻燃添加剂,包括卤素、磷、无机物、三聚氰胺衍生物和膨胀型添加剂.研究所选用的阻燃环氧体系都具有较高的商业化应用价值.研究发现,固化剂的种类对环氧树脂的阻燃性有较大影响,在阻燃和抑烟方面,溴系阻燃剂比氯系阻燃剂更有效.亚磷酸盐对于环氧树脂具有很好的阻燃作用.氢氧化镁、硼酸锌比氢氧化铝的阻燃效率高.三聚氰胺化合物能够赋予环氧树脂较好的阻燃和抑烟性,此外膨胀型添加剂也是一种有效的阻燃剂.
参考文献
| [1] | Varma I K;Gupta V B.Polymer Matrix Composites[A].Amsterdam:Elsevier Science,2000:1-56. |
| [2] | Preeti Jain;Veena Choudhary;I. K. Varma .Flame retarding epoxies with phosphorus[J].Journal of macromolecular science.Polymer reviews,2002(2):139-183. |
| [3] | Sergei V Levchik;Edward D Weil .Thermal decomposition,combustion and flame-retardancy of epoxy resins - a review of the recent literature[J].Polymer international,2004(12):1901-1929. |
| [4] | EDWARD D. WEIL;SERGEI LEVCHIK .A Review of Current Flame Retardant Systems for Epoxy Resins[J].Journal of fire sciences,2004(1):25-40. |
| [5] | Sergei V. Levchik;Edward D. Weil .A Review of Recent Progress in Phosphorus-based Flame Retardants[J].Journal of fire sciences,2006(5):345-364. |
| [6] | Rakotomalala M;Wagner S;Doring M .Recent Developments in Halogen Free Flame Retardants for Epoxy Resins for Electrical and Electronic Applications[J].Materials,2010,3(08):4300-4327. |
| [7] | Gerard C;Fontaine G;Bourbigot S .New Trends in Reaction and Resistance to Fire of Fire-Retardant Epoxies[J].Materials,2010,3(08):4476-4499. |
| [8] | Song L;Wu K;Wang Y;Wang ZZ;Hu Y .Flammability and Thermo-Oxidative Decomposition of Epoxy Resin Containing Ammonium Polyphosphate and Metallic Oxide[J].Journal of Macromolecular Science. Pure and Applied Chemistry,2009(3):290-295. |
| [9] | Wang JS;Wang DY;Liu Y;Ge XG;Wang YZ .Polyamide-enhanced flame retardancy of ammonium polyphosphate on epoxy resin[J].Journal of Applied Polymer Science,2008(4):2644-2653. |
| [10] | Chen W Y;Wang Y Z;Chang F C .Thermal and Flame Retardation Properties of Melamine Phosphate-Modified Epoxy Resins[J].Journal of Polymer Research,2004,11(02):109-117. |
| [11] | Zerda AS.;Lesser AJ. .Organophosphorous additive for fortification, processibility, and flame retardance of epoxy resins[J].Journal of Applied Polymer Science,2002(2):302-309. |
| [12] | Y. -I. Liu;E. M. Pearce;E. D. Weil .Flame Retardancy of Dicyandiamide-Crosslinked Epoxy Resins containing Phenolphthalein Structures And/or a Phosphorus- Containing Additive[J].Journal of fire sciences,1999(3):240-258. |
| [13] | Katsoulis C;Kandare E;Kandola B K.Thermal and Fire Performance of Flame-Retarded Epoxy Resin:Investigating Interaction Between Resorcinol Bis (Diphenyl Phosphate) and Epoxy Nanocomposites[A].Condon:Royal Society of Chemistry Publishers,2009:184-205. |
| [14] | De Fenzo, A;Formicola, C;Antonucci, V;Zarrelli, M;Giordano, M .Effects of zinc-based flame retardants on the degradation behaviour of an aerospace epoxy matrix[J].Polymer Degradation and Stability,2009(9):1354-1363. |
| [15] | Kim J.;Yoo S.;Bae JY.;Yun HC.;Hwang J.;Kong BS. .Thermal stabilities and mechanical properties of epoxy molding compounds (EMC) containing encapsulated red phosphorous[J].Polymer Degradation and Stability,2003(2):207-213. |
| [16] | Levchik, S;Piotrowski, A;Weil, E;Yao, Q .New developments in flame retardancy of epoxy resins[J].Polymer Degradation and Stability,2005(1):57-62. |
| [17] | Ciesielski M;Diederichs J;D(o)ring M.Advanced FlameRetardant Epoxy Resins for Composite Materials[A].Washington D C:American Chemical Society Publications,2009:174-190. |
| [18] | Polka M .The Influence of Flame Retardant Additives on Fire Properties of Epoxy Materials[J].Journal of Civil Engineering and Management,2008,14(01):45-48. |
| [19] | Ishii T;Kokaku H;Nagai A;Nishita T;Kakimoto M .Calcium borate flame retardation system for epoxy molding compounds[J].Polymer engineering and science,2006(6):799-806. |
| [20] | Xiao W;He P;Hu G et al.Study on the Flame-Retardance and Thermal Stability of the Acid Anhydride-Cured Epoxy Resin Flame-Retarded by Triphenyl Phosphate and Hydrated Alumina[J].Journal of Fire Sciences,2001,19(05):369-377. |
| [21] | A.D. La Rosa;A. Recca;J.T. Carter;P.T. McGrail .An oxygen index evaluation of flammability on modified epoxy/polyester systems[J].Polymer: The International Journal for the Science and Technology of Polymers,1999(14):4093-4098. |
| [22] | Hussain M.;Varley RJ.;Zenka M.;Simon GP. .Synthesis, thermal behavior, and cone calorimetry of organophosphorus epoxy materials[J].Journal of Applied Polymer Science,2003(13):3696-3707. |
| [23] | Chun Shan Wang;Ching Hsuan Liu .Synthesis and Properties of Phosphorus-Containing Epoxy Resins by Novel Method[J].Journal of Polymer Science, Part A. Polymer Chemistry,1999(21):3903-3909. |
| [24] | Chin-Lung Chiang;Shu-Wei Hsu .Synthesis, characterization and thermal properties of novel epoxy/expandable graphite composites[J].Polymer international,2010(1):119-126. |
| [25] | Gao, M.;Wo, Y.;Wu, W. .Microencapsulation of intumescent flame-retardant agent and application to epoxy resins[J].Journal of Applied Polymer Science,2011(4):2025-2030. |
| [26] | Ming Gao;Shousheng Yang .A Novel Intumescent Flame-Retardant Epoxy Resins System[J].Journal of Applied Polymer Science,2010(4):2346-2351. |
| [27] | Chen GH;Yang B;Wang YZ .A novel flame retardant of spirocyclic pentaerythritol bisphosphorate for epoxy resins[J].Journal of Applied Polymer Science,2006(5):4978-4982. |
| [28] | Joseph Green .Mechanisms for Flame Retardancy and Smoke Suppression-A Review[J].Journal of fire sciences,1996(6):426-442. |
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