欢迎登录材料期刊网

材料期刊网

高级检索

研究了通过压坯烧结制备的8YbSZ(8 mol%Yb2O3掺杂的ZrZO2)致密固体电解质的电导率.初始粉体的较高活性、各组分分布的均匀性以及Al2O3的加入,使得陶瓷的烧结在1 400℃时几乎达到完全致密.随着烧结温度的进一步升高,离子电导率的变化不大,并且当烧结温度在1 450℃和1 550℃之间时达到最佳.8YbSZ烧结体具有较高的离子电导率,可以用作中温燃料电池的固体电解质材料.文中还对8YbSZ的老化进行了讨论.

参考文献

[1] Minfang Han;Xiuling Tang;Huiyan Yin et al.Fabrication,Microstructure and Properties of a YSZ Electrolyte for SOFCs[J].Journal of Power Sources,2007,165:757-763.
[2] T. S. Zhang;J. Ma;H. T. Huang;P. Hing;Z. T. Xia;S. H. Chan;J. A. Kilner .Effects of dopant concentration and aging on the electrical properties of Y-doped ceria electrolytes[J].Solid state sciences,2003(11/12):1505-1511.
[3] Yamamoto O.;Takeda Y.;Imanishi N.;Mizutani Y.;Kawai M. Nakamura Y.;Arati Y. .ELECTRICAL CONDUCTIVITY OF STABILIZED ZIRCONIA WITH YTTERBIA AND SCANDIA[J].Solid state ionics,1995(0):137-142.
[4] Yang SY;Lee JH;Kim JJ;Lee JS .Sintering behavior of Y-doped ZrO2 ceramics: the effect of Al2O3 and Nb2O5 addition[J].Solid state ionics,2004(1/4):413-416.
[5] S. Tekeli .The solid solubility limit of Al_2O_3 and its effect on densification and micro structural evolution in cubic-zirconia used as an electrolyte for solid oxide fuel cell[J].Materials & Design,2007(1):713-716.
[6] S. TEKELI .Influence of alumina addition on grain growth and room temperature mechanical properties of 8YSCZ/Al_2O_3 composites[J].Composites science and technology,2005(6):967-972.
[7] Zhengang L V;Ruisong Guo;Pei Yao et al.Effects of Al2O3 and/or CaO on Properties of Yttria Stabilized Zirconia Electrolyte Doped with Multi-Elements[J].Materials & Design,2007,28:1399-1403.
[8] Drennan J.The Influence of Interface Structures on the Conducting Properties of Zirconia(ZrO2)-Based Solid Electrolytes[J].Journal of Materials Synthesis and Processing,1998(06):181-189.
[9] Xin Guo;Zaoli Zhang .Grain size dependent grain boundary defect structure: case of doped zirconia[J].Acta materialia,2003(9):2539-2547.
[10] Xin Guo;Rainer Waser .Electrical properties of the grain boundaries of oxygen ion conductors: Acceptor-doped zirconia and ceria[J].Progress in materials science,2006(2):151-210.
[11] Carter R E;Roth W L.[A].Columbus OH:Am Ceram Soc Press,1968:125.
[12] Butz B;Kruse P;Stormer H;Gerthsen D;Muller A;Weber A;Ivers-Tiffee E .Correlation between microstructure and degradation in conductivity for cubic Y2O3-doped ZrO2[J].Solid state ionics,2006(37/38):3275-3284.
[13] Yanmei Kan;Guojun Zhang;Peiling Wang .Yb_2O_3 and Y_2O_3 co-doped zirconia ceramics[J].Journal of the European Ceramic Society,2006(16):3607-3612.
[14] Taylor M A;Argirusis Chr;Kilo M et al.Correlation between Ionic Radius and Cation Diffusion in Stabilised Zirconia[J].Solid State Ionics,2004,173:51-56.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%