炭黑表面的纳米结构与色散自由能之间的关系研究

材料科学与工程学报, 2006, 24(3): 337-340. doi: 10.3969/j.issn.1673-2812.2006.03.004

炭黑表面的纳米结构与色散自由能之间的关系研究

张尚勇 ^1, , 魏良明 ^2, , 古宏晨 ^3, , 朱永宁 ^4,

1.上海交通大学微纳科学与技术研究院,上海,200030

2.上海交通大学微纳科学与技术研究院,上海,200030

3.上海交通大学微纳科学与技术研究院,上海,200030

4.中国苏州宝化炭黑有限公司,江苏,苏州,215151

关键词：炭黑 , 纳米结构 , 反气相色谱(IGC) , 拉曼光谱

Relationship Research between Nano-structure of Carbon Black Surface and Dispersive Free Energy of Carbon Black

利用反气相色谱法(IGC)对炭黑的色散自由能rds进行了研究,利用激光拉曼光谱法对炭黑表面纳米尺寸的晶体结构进行了分析,并从两种方法的综合分析中推导出了炭黑的色散自由能与炭黑表面纳米晶体的特征尺寸(La)成反比的经验关系,并对此进行了理论分析.

参考文献

[1]	Wang M J;Wolff S .Filler-elastomer interactions.Part Ⅲ.Carbonblack-surface energies and interactions with elastomer analogs[J].Rubber Chemistry and Technology,1991,64:714-736.
[2]	Wang M J;Wolff S;Donnet J B .Filler-elastomer interactions.Part Ⅰ:Silica surface energies and interactions with model compounds[J].Rubber Chemistry and Technology,1991,64:559-576.
[3]	H. Darmstadt;N. -Z. Cao;D. M. Pantea;C. Roy;L. Summchen;U. Roland;J. -B. Donnet;T. K. Wang;C. H. Peng;P. J. Donnelly .Surface activity and chemistry of thermal carbon blacks[J].Rubber Chemistry and Technology,2000(2):293-309.
[4]	Weizhong Zhu;Donald E.Miser;W.Geoffrey Chan;Mohammad R.Hajaligol .HRTEM investigation of some commercially available furnace carbon blacks[J].Carbon: An International Journal Sponsored by the American Carbon Society,2004(8/9):1841-1845.
[5]	T. JAWHARI;A. ROID;J. CASADO .RAMAN SPECTROSCOPIC CHARACTERIZATION OF SOME COMMERCIALLY AVAILABLE CARBON BLACK MATERIALS[J].Carbon: An International Journal Sponsored by the American Carbon Society,1995(11):1561-1565.
[6]	Tuinstra F;Koenig JL .Raman Spectrum of Graphite[J].Journal of Chemical Physics,1970,53(03):1126-1130.
[7]	Castellano M.;Falqui L.;Costa G.;Turturro A.;Valenti B.;Castello G. .Investigation on elastomer-silica interactions by inverse gas chromatography and image analysis aided transmission electron microscopy[J].Journal of Macromolecular Science. Physics,2002(3):451-471.
[8]	Papirer Eugene;Brandle Eric;Ozil Fabien;Balard Henri .Comparison of the surface properties of graphite, carbon black and fullerene samples, measured by inverse gas chromatography[J].Carbon: An International Journal Sponsored by the American Carbon Society,1999(8):1265-1274.
[9]	Meng-Jiao Wang;Hairuo Tu;Lawrence;J. Murphy;Khaled Mahmud .Carbon-silica dual phase filler, a new generation reinforcing agent for rubber: part VIII. surface characterization by IGC[J].Rubber Chemistry and Technology,2000(4):666-677.
[10]	Tamas Ungar;Jeno Gubicza;Gabor Ribarik;Cristian Pantea;T.Waldek Zerda .Microstructure of carbon blacks determined by X-ray diffraction profile analysis[J].Carbon: An International Journal Sponsored by the American Carbon Society,2002(6):929-937.

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