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利用二氧化钛溶胶进行光催化含氯的有机物.二氯甲烷溶液在二氧化钛溶胶和紫外光的作用下,分解并使得溶液的电导率增加.二氧化钛溶胶的浓度和二氯甲烷的浓度对光催化的电导率的变化有一定的联系.当二氧化钛的浓度过高时,光照所产生的自由基和氧空穴对由于复合、浓度减低,导致二氯甲烷的降解反应速度变缓,反映在电导率的变化上,电导率的增加速度变缓.选择合适的二氧化钛的浓度,将有利于二氯甲烷的光催化分解.

参考文献

[1] Sidebottom H.;Franklin J. .THE ATMOSPHERIC FATE AND IMPACT OF HYDROCHLOROFLUOROCARBONS AND CHLORINATED SOLVENTS[J].Pure and Applied Chemistry,1996(9):1757-1769.
[2] Van Den Brink .Catalytic Oxidation of Dichloromethane on γ-Al2 O3 :A Combined Flow and Infrared Spectroscopic Study[J].Journal of Catalysis,1998,180:153-160.
[3] B Chen .Gold/cobalt oxide catalysts for oxidative destruction of dichloromethane[J].Catalysis Today,1996,30:15-20.
[4] L J Heraty etc.Isotopic fractionation of carbon and chlorine by microbial degradation of dichloromethane[J].Organic Geochemistry,1999,30:793-799.
[5] Gutierrez-Ortiz JI.;Lopez-Fonseca R.;Aurrekoetxea U.;Gonzalez-Velasco JR. .Low-temperature deep oxidation of dichloromethane and trichloroethylene by H-ZSM-5-supported manganese oxide catalysts[J].Journal of Catalysis,2003(1):148-154.
[6] A Fujishima;K. Honda .Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238:37-38.
[7] T Tsuru et al.A photocatalytic membrane reactor for gas-phase reactions using porous titanium oxide membranes[J].Catalysis Today,2003,82:41-48.
[8] Y-M Gao et al.Preparation and photocatalytic properties of titanium (Ⅳ) oxide films[J].Materials Research Bulletin,1992,27(09):1023-1030.
[9] Wonyong Choi et al.Kinetics and Mechanism of CCl4 Photoreductive Degradation on TiO2: The Role of Trichloromethyl Radical and Dichlorocarbene[J].Journal of Physical Chemistry,1996,100:2161-2169.
[10] 邱健斌,曹亚安,马颖,管自生,姚建年.担载材料对TiO2薄膜光催化活性的影响[J].物理化学学报,2000(01):1-4.
[11] Istvan Ilisz et al.Photocatalytic water treatment with different Tio2 nanoparticles and Hydrohilic/hydrophobic layer silicate adsorbents[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2004,230:89-97.
[12] S. Kataoka.Microwave-assisted heterogeneous photocatalytic oxidation[A].Orlando, FL.American Ceramic Society,2000
[13] Catherine B;Almquist;Pratim Biswas .The Photo-oxidation of cyclohexane on titanium dioxide: an investigation of competitive adsorption and is effects on product formation and selectivity[J].Applied Catalysis A:General,2001,214:259-271.
[14] Michael R. Hoffmann;Scot T. Martin;Wonyong Choi;Detlef W. Bahnemann .Environmental Applications of Semiconductor Photocatalysis[J].Chemical Reviews,1995(1):69-96.
[15] Amy L. Linsebigler;Guangquan Lu;John T. Yates Jr. .Photocatalysis on TiO_2 Surfaces: Principles, Mechanisms, and Selected Results[J].Chemical Reviews,1995(3):735-758.
[16] C S Turchi;D F Ollis .Photocatalytic degradation of organic water contaminants:mechanisms involving hydroxyl radical attack[J].Journal of Catalysis,1990,122:178-192.
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