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文献[4]等研究表明在活性气氛下裂解聚碳硅烷制备陶瓷,可以明显降低陶瓷中碳的含量,利用这一研究结果,结合物质扩散机制,提出了聚碳硅烷活性气氛下(NH3)制备梯度陶瓷的设想.模拟计算的结果表明,该方法的是可行的,工艺上可控的;通过工艺控制,可以制备两种不同电导率类型--沿厚度方向的电导率逐渐变化或者跃进式变化的功能陶瓷材料.

参考文献

[1] S Suresh;[瑞士]A Mortensen;李守新.功能梯度材料基础-制备及热机械行为[M].北京:国防工业出版社,2000
[2] 王顺兴;刘勇.实用热处理模拟技术[M].北京:机械工业出版社,2002:1.
[3] Douglas M Bates;[加]Donald G Watts;韦博成,万方焕.非线性回归分析及其应用[M].北京:中国统计出版社,1997:11.
[4] Gary T;Burns;Grish Chandra .Pyrolysis of preceramic Polymers In Ammonia:Preparation of Silicon Nitride Powders[J].Communication of the American Ceramic Society,1989,2:333-337.
[5] J Rabe;D Bujalski .Process for Preparing Ceramic materials with Reduced Carbon Levels[P].European Pat Application 200326,1986.
[6] Anthony G;Evans;Frank W Zok;Robert M,Mcmecking,Zheng Z Du .Models of High-Temperature,Environmentally Assisted Embrittlement in Ceramic-Matrix Composites[J].Journal of the American Ceramic Society,1996,79:2345-52.
[7] Jens Cordelair;Peter Greil .Electrical conductivity measurement as a microprobe for structure transition in polysiloxane derived Si-O-C ceramics[J].Journal of the European Ceramic Society,2000,20:1947-1857.
[8] Paolo Colombo;Tatiana Gambaryan-Roisman;Michael Scheffler;Peter Buhler;Peter Greil .Conductive Ceramic Foams from Preceramic Polymers[J].Journal of the American Ceramic Society,2001(10):2265-2268.
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