Ca0.6Mg0.4Zr4P6O24属于NZP结构族化合物,NZP陶瓷材料是一类新发现的低膨胀材料,其典型组成是NaZr2P2O12.本研究采用化学计量的ZrO(OH)2沉淀与Ca2+、Mg2+离子的酸式磷酸盐溶液混合,在80℃烘干.经900℃/16小时煅烧,合成出Ca0.6Mg0.4zr4P相粉体.利用DTA、TG和XRD研究了沉淀一溶液混合法合成Ca0.6Mg0.4Zr4P6O24相的温度和机理.
参考文献
[1] | Lhagman;Rkierkegaard.The Crystal Structure of NaMe2(PO43 ;Me=GeTiZr[J].Acta Chemica Scandinavica,1968:1822-32. |
[2] | HYHong .[J].Materials Research Bulletin,1976,11(01):73. |
[3] | JGoodenough;H Y-Hong;J A Kafalas .Fast Na+-ion Transport in Skeleton Structures[J].Materials Research Bulletin,1976,11(02):203-20. |
[4] | Rroy ERVanceand;James Alamo .[NZP], Anew Radiophase for Ceramic Nuclear Waste Forms[J].Materials Research Bulletin,1982,17(05):585-89. |
[5] | RRoy;Liji Yang;James Alamo;E R Vance.in Proceedings of Scientific Basis for Nuclear Waste Management VI edited by DGBrookins[M].Elsevier,New York,1983:15. |
[6] | DKAgrawal .Synthesis and Sintering of Ca0 5Zr2P3O12-a Low Thermal Expansion Material[J].Materials Research Bulletin,1985,20:99-106. |
[7] | ToshitakaOta;Ping Jin;lwao Yamai .Loe Thermal Expansion and Low Thermal Expansion Anisotropy Ceramic of Sr0 5Zr2[J].PO4,3 System,"J Mater Sci,1989,24:4239-4245. |
[8] | SYLimaye D;K Agrawal and H A Mckinstry .Synthesis and Thermal Expansion of MZr4P6O24(M=Mg,Ca,Sr,Ba[J].Journal of the American Ceramic Society,1987,70(10):232-c-236. |
[9] | SYLimaye;D K Agrawal;R Roy .Synthesis,Sintering and Thermal Expansion of Cal-xSrxZr,4P6O24-an ultra-Low Thermal Expansion Cerami cS istem[J].MateSci,1991,26:93-98. |
[10] | GELemain;H A Mckinstry;S Y Limaye;A Wood ward .Low Thermal Expansion of AlkaliZirconium Phosphates[J].Materials Research Bulletin,1984,19(10):1451-56. |
[11] | AClearfield;P Jirustithipong;R N Cotman;S P Pack .[J].Materials Research Bulletin,1980,15:106. |
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