采用溶胶-凝胶法制备的掺杂Co纳米TiO2粉体(Co/TiO2),在紫外光照射下光催化降解水中五氯苯酚(PCP).研究了光照反应时间、催化剂加入量、PCP溶液初始浓度等因素对纳米Co/TiO2光催化降解五氯苯酚的影响.在溶液中五氯苯酚初始浓度为0.01 mg/mL,pH=9~10,纳米Co/TiO2加入量达到0.25 mg/mL,光照时间为150 min时,溶液中的PCP降解率达到了97%;纳米Co/TiO2粉末与纳米TiO2相比,在紫外光和可见光下对水中PCP的降解效果均有一定提高.
参考文献
[1] | Hayes W J;Laws E R.Handbook of Pesticide Toxicology Classes of Pesticides[M].New York:Academic Press,Inc,1991:1206-1216. |
[2] | Chen Yingxu;Chen Hualin;Xu Yuntai .Irreversible sorption of pentachlorophenol to sediments:experimental observations[J].Environmental International,2004,30(01):31-37. |
[3] | Grady C P L Jr .Biodegradation of toxic organics:status and potential[J].Journal of Environmental Engineering,1990,116:805-828. |
[4] | 王宏,杨霓云,沈英娃,王波,王鲁昕.海河流域几种典型有机污染物环境安全性评价[J].环境科学研究,2003(06):35-36,52. |
[5] | 张兵,郑明辉,刘芃岩,包志成,徐晓白.五氯酚在洞庭湖环境介质中的分布[J].中国环境科学,2001(02):165-167. |
[6] | 罗进飞,于洪锋,李洪,李鑫钢.五氯苯酚光催化降解的影响因素分析[J].化工进展,2009(05):899-903. |
[7] | Jarnuzi Gunlazuardi;Winarti Andayani Lindu .Photocatalytic degradation of pentachlorophenol in aqueous solution employing immobilized TiO_2 supported on titanium metal[J].Journal of Photochemistry and Photobiology, A. Chemistry,2005(1):51-55. |
[8] | Zhou L;Zhang SY;Cheng JC;Zhang LD;Zeng Z;NANJING UNIV LAB MODERN ACOUST NANJING 210093 PEOPLES R CHINA.;ACAD SINICA INST SOLID STATE PHYS HEFEI 230031 PEOPLES R CHINA. .Optical absorptions of nanoscaled CoTiO3 and NiTiO3[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,1997(2):117-122. |
[9] | Iwasaki M.;Kawada H.;Tada H.;Ito S.;Hara M. .Cobalt ion-doped TiO2 photocatalyst response to visible light[J].Journal of Colloid and Interface Science,2000(1):202-204. |
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