全钒氧化还原液流电池(VRFB)具有储能效率高、循环寿命长、安全可靠、低成本等优点,在大规模储能中具有良好的应用前景.而作为VRFB的核心部件,离子交换膜应具有钒离子透过率低、电导率高、化学稳定性好等性能.总结了近年来国内外相关的研究进展,对比了不同合成方法的优缺点,并提出了开发适用于VRFB的高性能离子交换膜的建议.
参考文献
[1] | Thaller L H .Electrically rechargeable redox flow cells[P].US Pat:3996064,1974. |
[2] | Thaller L H;Nice A W .Fluid battery promise economical storage[J].Power EngJ,1981,85(02):56-58. |
[3] | Sum E;Rychcik M;Skyllas-Kazacos M .Investigation of the V(Ⅱ)/V(Ⅲ) system for use in the positive halfcell of a redox battery[J].Journal of Power Sources,1985,16:85-95. |
[4] | Sum E;Skyllas-Kazacos M .A study of the V(Ⅱ)/V(Ⅲ) redox couple for redox flow cell applications[J].Journal of Power Sources,1985,15:179-190. |
[5] | Mohammadi T;Skyllas-kazacos M .Evaluation of the chemical stability of some membranes in vanadium solution[J].Journal of Applied Electrochemistry,1997,27(02):153-160. |
[6] | Gab-Jin Hwang;H. Ohya .Preparation of cation exchange membrane as a separator for the all-vanadium redox flow battery[J].Journal of Membrane Science,1996(1):55-67. |
[7] | Ke-Long Huang;Xiao-gang Li;Su-qin Liu;Ning Tan;Li-quan Chen .Research progress of vanadium redox flow battery for energy storage in China[J].Renewable energy,2008(2):186-192. |
[8] | 石瑞成.全钒液流氧化还原电池中隔膜的研究[J].膜科学与技术,2009(03):72-75. |
[9] | Ping Zhao;Huamin Zhang;Hantao Zhou .Characteristics and performance of 10 kW class all-vanadium redox-flow battery stack[J].Journal of Power Sources,2006(2):1416-1420. |
[10] | T. Mohammadi;M. Skyllas-Kazacos .Preparation of sulfonated composite membrane for vanadium redox flow battery applications[J].Journal of Membrane Science,1995(1/2):35-45. |
[11] | T. Mohammadi;M. Skyllas-Kazacos .Use of polyelectrolyte for incorporation of ion-exchange groups in composite membranes for vanadium redox flow battery applications[J].Journal of Power Sources,1995(1):91-96. |
[12] | Mohammadi T.;Skyllaskazacos M. .CHARACTERISATION OF NOVEL COMPOSITE MEMBRANE FOR REDOX FLOW BATTERY APPLICATIONS[J].Journal of Membrane Science,1995(1/2):77-87. |
[13] | B. Tian;C.W. Yan;F.H. Wang .Proton conducting composite membrane from Daramic/Nafion for vanadium redox flow battery[J].Journal of Membrane Science,2004(1/2):51-54. |
[14] | Chang Houn Rhee;Hae Kyung Kim;Hyuk Chang;Jae Sung Lee .Nafion/Sulfonated Montmorillonite Composite:A New Concept Electrolyte Membrane for Direct Methanol Fuel Cells[J].Chemistry of Materials,2005(7):1691-1697. |
[15] | 滕祥国,赵永涛,席靖宇,武增华,邱新平,陈立泉.全钒氧化还原液流电池用Nafion/有机硅复合膜[J].化学学报,2009(06):471-476. |
[16] | Yoon S R;Hwang G H;Cho W I et al.Modification of polymer electrolyte membranes for DMFCs using Pd films formed by sputtering[J].Journal of Power Sources,2002,106(1-2):215-223. |
[17] | Jiang SP;Liu ZC;Tian ZQ .Layer-by-layer self-assembly of composite polyelectrolyte-nafion membranes for direct methanol fuel cells[J].Advanced Materials,2006(8):1068-1072. |
[18] | Bo Yang;Arumugam Manthiram .Multilayered membranes with suppressed fuel crossover for direct methanol fuel cells[J].Electrochemistry communications,2004(3):231-236. |
[19] | Mauritz K A;Warren R M .Microstructure evolution of a silicon oxide phase in a perfluorosulfonic acid ionomer by an in situ sol-gel reaction.(1) Infrared spectroscopic studies[J].Macromolecules,1989,22:1730. |
[20] | Mauritz K A;Stefanithis I D .Microstructure evolution of a silicon oxide phase in a perfluorosulfonic acid ionomer by an in situ sol-gel reaction.(2) Dielectric relaxation studies[J].Macromolecules,1990,23 |
[21] | Xi J Y;Wu Z H;Qiu X P et al.Nafion/SiO2 hybrid membrane for vanadium redox flow battery[J].Journal of Power Sources,2007,166(02):531-536. |
[22] | Xi JY;Wu ZH;Teng XG;Zhao YT;Chen LQ;Qiu XP .Self-assembled polyelectrolyte multilayer modified Nafion membrane with suppressed vanadium ion crossover for vanadium redox flow batteries[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2008(11):1232-1238. |
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