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采用自制的硅橡胶-沸石杂化优先透乙醇渗透汽化复合膜,利用响应曲面法研究原料液温度和循环流速两个参数对乙醇质量分数为4.05%的乙醇-水体系渗透汽化分离过程的影响.试验表明,温度对膜的通量和分离因子都有显著的影响,温度升高通量增加,而在50℃以下分离因子随温度升高而增加,此后分离因子随温度升高而下降.循环流速的增加会导致通量和分离因子的下降.综合考虑分离因子和通量这两个响应值,利用回归方程求得本试验所采用的渗透汽化复合膜在乙醇一水体系中最优操作条件是:温度59.8℃,循环流速30 L/h,此时总通量和乙醇分离因子分别达到242.8 g/(m2·h)和20.6.

参考文献

[1] Shao P;Huang RYM .Polymeric membrane pervaporation[J].Journal of Membrane Science,2007(2):162-179.
[2] 陈翠仙.渗透汽化和蒸汽渗透[M].北京:化学工业出版社,2005:116-125.
[3] Xiangli FJ;Wei W;Chen YW;Jin WQ;Xu NP .Optimization of preparation conditions for polydimethylsiloxane (PDMS)/ceramic composite pervaporation membranes using response surface methodology[J].Journal of Membrane Science,2008(1/2):23-33.
[4] Jenny Olsson;Gun Tragardh .Pervaporation of volatile organic compounds from water I influence of permeate pressure on selectivity[J].Journal of Membrane Science,2001(1/2):23-37.
[5] Bakhshi A;Mohammadi T;Aroujalian A .Pervaporation separation of binary and ternary mixtures with polydimethylsiloxane membranes[J].Journal of Applied Polymer Science,2008(3):1777-1782.
[6] M. Sivakumar;G. Annadurai;D. Mohan .Studieso n Box-Behnken design experiments: cellulose acetate-polyurethane ultrafiltration membranes for BSA separation[J].Bioprocess Engineering,1999(1):65-68.
[7] Malaisamy R.;Mohan D.;Annadurai G. .Performance optimization of polysulfone ultrafiltration membranes for riboflavin separation using design experiments[J].Bioprocess Engineering,2000(3):227-232.
[8] Idris A.;Ismail AF.;Noordin MY.;Shilton SJ. .Optimization of cellulose acetate hollow fiber reverse osmosis membrane production using Taguchi method[J].Journal of Membrane Science,2002(1/2):223-237.
[9] A.F.Ismail;P.Y.Lai .Development of defect-free asymmetric polysulfone membranes for gas separation using response surface methodology[J].Separation and Purification Technology,2004(2):191-207.
[10] Ani Idris;Farida Kormin;M.Y.Noordin .Application of response surface methodology in describing the performance of thin film composite membrane[J].Separation and Purification Technology,2006(3):271-280.
[11] Khayet M;Cojocaru C;Garcia-Payo C .Application of response surface methodology and experimental design in direct contact membrane distillation[J].Industrial & Engineering Chemistry Research,2007(17):5673-5685.
[12] Corneliu Cojocaru;Grazyna Zakrzewska-Trznadel .Response surface modeling and optimization of copper removal from aqua solutions using polymer assisted ultrafiltration[J].Journal of Membrane Science,2007(1/2):56-70.
[13] M. Khayet;C. Cojocaru;G. Zakrzewska-Trznadel .Studies on pervaporation separation of acetone, acetonitrile and ethanol from aqueous solutions[J].Separation and Purification Technology,2008(2):303-310.
[14] Lazic Z R.Design of experiments in chemical engineering:A practical guide[M].WILEY-VCH,Federal Republic of Germany,2004
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