介绍了近年来热致相分离(TIPS)法聚合物多孔膜研究的新进展.从热力学角度总结了TIPS的成膜机理,相图是理解TIPS机理的重要工具;液滴生长和晶粒生长是研究制膜体系TIPS动力学的两个方面.膜形貌由热力学、动力学共同控制,聚合物分子量、稀释剂种类、溶液固含量、冷却速率、成核剂是控制膜结构的五个重要方面.
参考文献
[1] | Jae-Jin Kim;Jeong Rim Hwang;Un Young Kim;Sung Soo Kim .Operation parameters of melt spinning of polypropylene hollow fiber membranes[J].Journal of Membrane Science,1995(1/2):25-36. |
[2] | Hideto Matsuyama;Hajime Okafuji;Taisuke Maki;Masaaki Teramoto;Noboru Kubota .Preparation of polyethylene hollow fiber membrane via thermally induced phase separation[J].Journal of Membrane Science,2003(1/2):119-126. |
[3] | Ruei-Liang Luo;Tai-Horng Young;Yi-Ming Sun .Structure formation and characterization of EVAL membranes with cosolvent of isopropanol and water[J].Polymer: The International Journal for the Science and Technology of Polymers,2003(1):157-166. |
[4] | Mehta RH.;Kalika DS. .CHARACTERISTICS OF POLY(ETHER ETHER KETONE) MICROPOROUS MEMBRANES PREPARED VIA THERMALLY INDUCED PHASE SEPARATION (TIPS)[J].Journal of Applied Polymer Science,1997(12):2347-2355. |
[5] | Senthilkumar Ramaswamy;Alan R. Greenberg;William B. Krantz .Fabrication of poly (ECTFE) membranes via thermally induced phase separation[J].Journal of Membrane Science,2002(1):175-180. |
[6] | Kessler E;Batzilla T;Wechs F et al.Method for producing an integrally asymmetrical polyolefin membrane[P].US 6375876B1,2002-04-23. |
[7] | Kopp C V;Streeton R J W;Khoo P .Extrusion of hollow fibre membranes[P].WO 90/05006,1990-05-17. |
[8] | Radovanovic P D;Perez M A;Thomas S D .Microporous meaerial resistant to capillary collapse[P].US 6461724B1,2002-10-08. |
[9] | Lopatin G;Yen L Y;Rogers R .Microporous membranes from polypropylene[P].US 4874567,1989-10-17. |
[10] | 郭行蓬,柳波,葛昌杰,杜强国,杨玉良.热致相分离法制备微孔EVAL中空纤维膜的探索[J].功能高分子学报,2001(01):23-26. |
[11] | 侯文贵,李凭力,张翠兰,王世昌.热致相分离制备聚丙烯微孔膜微观结构的研究[J].膜科学与技术,2003(02):27-31. |
[12] | P. van de Witte;P.J. Dijkstra;J.W.A. van den Berg;J. Feijen .Phase separation processes in polymer solutions in relation to membrane formation[J].Journal of Membrane Science,1996(1/2):1-31. |
[13] | Vadalia H C;Lee H K;Levon K et al.Thermally induced phase separation in ternary crystallizable polymer solutions[J].Journal of Membrane Science,1994,89:37-50. |
[14] | Kim S S;Lloyd D R .Microporous membrane formation via thermally-induced phase separation (Ⅲ)[J].Journal of Membrane Science,1991,64:13-29. |
[15] | Hua F J;Park T G;Lee D S .A facile preparation of highly interconnected microporous poly (D,L-latic acid-co-glycolic acid) (PLGA) scaffolds by liquid-liquid phase separation of a PLGA-dioxane-water ternary system[J].Polymer,2003,44:1911-1920. |
[16] | Kenneth S M;Laxminarayan A;Lloyd D R .Kinetics of droplet growth in liquid-liquid phase separation of polymer-diluent system:experimental[J].Polymer,1995,36:4951-4960. |
[17] | Kim WK.;Kim CK.;Char K. .Control of droplet size of polymer-diluent blends through thermally induced phase separation[J].Journal of Polymer Science, Part B. Polymer Physics,2000(23):3042-3052. |
[18] | Hideto Matsuyama;Masaaki Teramoto;Shunsuke kudari;Yoshiro Kitamura .Effect of Diluents on Membrane Formation via Thermally Induced Phase Separation[J].Journal of Applied Polymer Science,2001(1):169-177. |
[19] | Matsuyama H.;Maki T.;Teramoto M.;Asano K. .Effect of polypropylene molecular weight on porous membrane formation by thermally induced phase separation[J].Journal of Membrane Science,2002(1/2):323-328. |
[20] | Shang MX.;Matsuyama H.;Maki T.;Teramoto M.;Lloyd DR. .Effect of crystallization and liquid-liquid phase separation on phase-separation kinetics in poly (ethylene-co-vinyl alcohol)/glycerol solution[J].Journal of Polymer Science, Part B. Polymer Physics,2003(2):194-201. |
[21] | 李凭力 .热致相分离聚丙烯中空纤维膜及其萃取特性的研究[D].天津大学,2002. |
[22] | Laxminarayan A;Mcguire K S;Lloyd D R et al.Effect of initial composition,phase separation temperature and polymer crystallization on the formation of microcellular structures via thermally induced phase separation[J].Polymer,1994,35:3060-3068. |
[23] | Lee H K;Myerson A S;Levon K .Nonequilibrium liquid -liquid phase separation in crystallizable polymer solutions[J].Macromolecules,1992,25:4002-4010. |
[24] | Mcguire K S;Lloyd D R;Lim B A .Microporous membrane formation via thermally-induced phase separation (Ⅶ)[J].Journal of Membrane Science,1993,79:27-34. |
[25] | Lloyd D R;Kim S S;Kinzer K E .Microporous membrane formation via thermally-induced phase separation (Ⅱ)[J].Journal of Membrane Science,1991,64:1-11. |
[26] | Castro A J .Method for making microporous[P].US 4247498,1981-01-27. |
[27] | Lim G B A;Kim S S;Lloyd D R et al.Microporous membrane formation via thermally-induced phase separation[J].Journal of Membrane Science,1991,64:31-40. |
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