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简述了质子交换膜燃料电池中质子交换膜的质子传导机理;讨论了目前质子交换膜存在的甲醇渗透、耐温性等共性问题,就如何解决这些问题进行了评述.同时,论述了质子交换膜的研究开发现状及其发展前景.

参考文献

[1] 衣宝廉 .燃料电池现状与未来[J].电源技术,1998,22(05):216.
[2] Rieke P C;Vanderborgh N E .Polymer electrolyte fuel cell model[J].Journal of Membrane Science,1987,32:313.
[3] Pourcelly G;Oikonomou A;Gavach C .Influence of the water content on the kinetics of counter- ion transport in perfluorosulphonic membranes[J].Journal of Electroanalytical Chemistry,1990,287:43-59.
[4] Springer T E;Zawodzinski T A;Gottesfeld S .Temperature dependence of water content and proton conductivity in polyperfluorosulfonic acid membranes[J].Journal of the Electrochemical Society,1991,138:2363.
[5] 曾蓉;庞志成;朱鹤孙 .质子交换膜中的离子传递[J].膜科学与技术,1999,19(06):38-41.
[6] 電氣學會·燃料電池發電次世代システム技術調查專門委員會.燃料電池の技術[M].東京:オ一ム社,2002:58-70.
[7] 黄倬;屠海令;张冀强.质子交换膜燃料电池的研究开发与应用[M].北京:冶金工业出版社,2000
[8] 于景荣,邢丹敏,刘富强,刘建国,衣宝廉.燃料电池用质子交换膜的研究进展[J].电化学,2001(04):385-395.
[9] Ehrenberg S G;Serpico J M;Wnek G E et al.Fuel cell incorporating novel ion- conducting membrane[P].U S Pat:5468574,1995-11-21.
[10] Linkous C A;Anderson H R;Kopitzke R W et al.Development of new proton exchange membrane electrolytes for water electrolysis at higher temperatures[J].International Journal of Hydrogen Energy,1998,23:525.
[11] Jones D J;Roziere J .Recent advances in the functionalisation of polybenzinidazole and polyetherketones for fuel cell applications[J].Journal of Membrane Science,2001,185:41-58.
[12] Lufrano F.;Staiti P.;Antonucci V.;Passalacqua E.;Gatto I. .Sulfonated polysulfone ionomer membranes for fuel cells[J].Solid state ionics,2001(1/4):47-51.
[13] B. Xing;O. Savadogo .Hydrogen/oxygen polymer electrolyte membrane fuel cells (PEMFCs) based on alkaline-doped polybenzimidazole (PBI)[J].Electrochemistry communications,2000(10):697-702.
[14] Wang J T;Savinell R F;Wainright J et al.A H2/O2 fuel cell using acid doped polybenzimidazole as polymer electrolyte[J].Electrochimica Acta,1996,41(02):193-197.
[15] Vargas M A;Vargas R A;Mellander B E .New proton conducting membranes based on PVAL/H3PO2/H2O[J].Electrochimica Acta,1999,44:4227-4232.
[16] Stefan Haufe;Ulrich Stimming .Proton conducting membranes based on electrolyte filled microporous matrices[J].Journal of Membrane Science,2001(1):95-103.
[17] 吴庆银 .固体高质子导体钨钒锗酸的制备及导电性能研究[J].辽宁大学学报(自然科学版),1998,25(01):12-16.
[18] Malhotra S;Datta R .Membrane- supported nonvolatile acidic electrolytes allow higher temperature operation of proton - exchange membrane fuel cells[J].Journal of the Electrochemical Society,1997,144:L23-L26.
[19] Felix N B;Bhuvanesh G;Otto H et al.Study of radiation- grafted FEP - g - polystyrene membranes as polymer electrolytes in fuel cells[J].Electrochimica Acta,1995,40(03):345-353.
[20] Lehtinen T.;Holmberg S.;Sundholm F.;Bjornbom P.;Bursell M.;Sundholm G. .Electrochemical characterization of PVDF-based proton conducting membranes for fuel cells[J].Electrochimica Acta,1998(12/13):1881-1890.
[21] Baradie B;Dodelet J P;Guay D .Hybrid Nafion - inorganic membrane with potential applications for polyer electrolyte fuel cells[J].Journal of Electroanalytical Chemistry,2000,489:101-105.
[22] Antonucci P.L.;Creti P.;Ramunni E.;Antonucci V.;Arico A.S. .Investigation of a direct methanol fuel cell based on a composite Nafion-silica electrolyte for high temperature operation[J].Solid state ionics,1999(1/4):431-437.
[23] Watanabe M;Uchida H;Emori M .Polymer electrolyte membranes incorporated with nanometer - size particles of Pt and/or metal - oxides:Experimental analysis of the self - humidification and suppression of gas- crossover in fuel cells[J].Journal of Physical Chemistry B,1998,102:3129-3137.
[24] Chisholm CRI.;Haile SM. .Superprotonic behavior of Cs-2(HSO4)(H2PO4) - a new solid acid in the CsHSO4-CsH2PO4 system[J].Solid state ionics,2000(Special Issue SI):229-241.
[25] Sossina M H;Dane A B;Calum R I et al.Solid acids as fuel cell electrolytes[J].Nature,2001,410(19):910-913.
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