以甲烷为碳源,在865℃～930℃温度条件下,通过化学气相沉积法,在铁基催化剂上生长出纳米石墨棒.对产物进行X射线衍射分析,确认其为石墨结构,晶粒径估算为16.3nm,长度为200nm～800nm.用透射电子显微镜和激光拉曼光谱仪作进一步的分析,结果表明:产物为纯度较高的纳米石墨棒.
参考文献
| [1] | Iijima S .Helical microtubules of graphitic carbon[J].Nature,1991,354:56-58. |
| [2] | A. C. Dillon;K. M. Jones;T. A. Bekkedahl;C. H. Kiang;D. S. Bethune;M. J. Heben .STORAGE OF HYDROGEN IN SINGLE-WALLED CARBON NANOTUBES[J].Nature,1997(6623):377-379. |
| [3] | Liu C;Fan Y Y;Liu M et al.Hydrogen storage in single-walled carbon nanotubes at room temperature[J].Science,1999,286:1127-1129. |
| [4] | Zhu H W;Xu C L;Wu D H et al.Direct synthesis of long single-walled carbon nanotube strands[J].Science,2002,296(5569):884-886. |
| [5] | 赵宗彬,邱介山,王同华,李永峰,周颖.以煤为碳源直流电弧法制备单壁纳米碳管绳[J].新型炭材料,2006(01):19-23. |
| [6] | 姚明光,刘冰冰,邹永刚,李冬妹,艾晓雷,王霖,于世丹,邹广田,B Sundqvist.Ho/Ni作为催化剂合成单壁碳纳米管[J].新型炭材料,2006(01):70-74. |
| [7] | 王志,巴德纯,蔺增,曹培江,刘飞,梁吉.气体配比对硼掺杂碳纳米管生长特性的影响[J].新型炭材料,2005(04):350-354. |
| [8] | 梁新宇,王浩静,刘颖,晁兵,周立公.等离子体射流辅助双催化剂原位催化法合成碳纳米管[J].新型炭材料,2005(03):250-254. |
| [9] | 王野,拜晓东,梁吉.H2O2原位净化定向碳纳米管阵列的研究[J].新型炭材料,2005(02):103-107. |
| [10] | 王敏炜,李凤仪,彭年才.Ni-La-Mg上催化裂解甲烷生成碳纳米管的研究[J].新型炭材料,2005(01):28-32. |
| [11] | 卢怡,朱珍平,刘振宇.催化剂对爆炸法合成碳纳米管的影响[J].新型炭材料,2004(01):1-6. |
| [12] | Kuznetsov V L;Chuvilin A L;Butenko Y V.Onion-like carbon from ultra disperse diamon[J].Chemical Physics Letters,1994(222):343-348. |
| [13] | Ying Chen;John Fitz Gerald;Lewis T. Chadderton;Laurent Chaffron .Nanoporous carbon produced by ball milling[J].Applied physics letters,1999(19):2782-2784. |
| [14] | S. Orimo;G. Majer;T. Fukunaga;A. Zuttel;L. Schlapbach;H. Fujii .Hydrogen in the mechanically prepared nanostructured graphite[J].Applied physics letters,1999(20):3093-3095. |
| [15] | Kraetschmer W;Lamb L D;Fostiropoulos K.Solid C60:A new form ofcarbon[J].Nature,1990(347):354-357. |
| [16] | 李天保,许并社,韩培德,张艳,王晓敏,刘旭光,市野濑英喜.洋葱状富勒烯的CCVD法制备及其形貌特征[J].新型炭材料,2005(01):23-27. |
| [17] | 杨全红."纳米"-碳质材料研究的新视角--Carbon2004参会有感[J].新型炭材料,2004(03):161-165. |
| [18] | 文潮,刘晓新,李迅,孙德玉,关锦清,林英睿,唐仕英,周刚,林俊德,金志浩.纳米石墨颗粒粒度的测量与表征[J].分析测试学报,2004(01):1-4. |
| [19] | Backmann P K;Wiechert D V;Horton L L.Diamond and diamond-like films and coatings[M].New York:Institute of Physic Press,Plenum,1991:677. |
| [20] | Diane S Knight;William B White .Characterization of diamond films by Raman spectroscopy[J].Journal of Materials Research,1989,4:385-393. |
| [21] | Yunqi Liu;Wenping Hu;Xianbao Wang;Chengeng Long;Jibiao Zhang;Daoben Zhu;Dongsheng Tang;Sishen Xie .Carbon nanorods[J].Chemical Physics Letters,2000(1):31-34. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%