采用共沉淀方法,以ND_2O_3、Y_2O_3和Al(NO_3)_3·9H_2O为起始原料,尿素为沉淀剂,制备Nd:YAG纳米粉体,粉体经XRD、TG-DTA、FESEM以及激光散射等测试手段对其结构和形貌进行测试研究.XRD表明,前驱体在900℃煅烧3h出现了YAG相和YAM中间相,在1000℃及其以上煅烧3h后已完全转变成YAG相,且随着煅烧温度升高,衍射峰逐步增强,900℃～1200℃煅烧的Nd:YAG晶格常数值从1.2012 nm变化到1.1994 nm,颗粒度从31 nm变化到96 nm,激光粒度仪也给出了类似的变化趋势.TG-DTA结果表明当前驱体加热到1200℃时,粉体总重量损失约为43%.对前驱体进行了水洗和乙醇洗两种洗涤,比较发现乙醇洗涤更有利于Nd:YAG纳米粉体的分散,这些实验结果可为制备优良YAG透明陶瓷粉体提供参考.
Nd:YAG nanoscaled powders were prepared by the co-precipitation method with ND_2O_3, Y_2O_3 and Al(NO_3)_3·9H_2O as the starting materials and CO(NH_2)_2 as the precipitator. The structure and mor-phology of the powders were investigated by XRD, TG-DTA, FESEM and laser particle analyzer. XRD patterns show that YAG phase and intermediate phase YAM were detected in the sample from the precursor calcined at 900℃ for 3 hours, the precursor completely transformed to YAG phase when it was calcined at 1000℃ for 3 hours, and the intensity of YAG X-ray diffraction peaks increased with the increase of calcination temperature. Lattice parameters of Nd:YAG phase calcined at 900℃～ 1200℃ changed from 1.2012 nm t0 1.1994 nm, and the particle size ranged from 31～96 nm. The similar variation was given by a measure of laser particle analyzer. The TG-DTA results indicate that the mass loss value was about 43% when the precursor was heated up t0 1200℃. Suspension was washed with distilled water and alco-hol, respectively. The comparison results show that alcohol is more effective for the well-dispersion of the nano-sized Nd:YAG powders. The results provid references for preparing good powders of YAG transparent ceramics.
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