欢迎登录材料期刊网

材料期刊网

高级检索

采用传统的固相烧结法制备Ba(Zn1/3Nb2/3)O3(BZN)和(1-x)Ba(Zn1/3Nb2/3)O3-xSr(Zn1/3Nb2/3)O3(BSZN)陶瓷,研究MnCO3和BaZrO3添加剂对其烧结温度和介电性能的影响.研究表明二者均是很好的助熔剂,在烧结过程中形成液相促进原子扩散从而降低烧结温度,本研究中的最佳烧结温度为1260℃(5#样品).MnCO3和BaZrO3对于改善系统的介电性能均有较好的效果,合理调整添加剂的用量可以有效的改善介电性能.0.35BZN-0.65SZN-1%MnCO3样品的介电性能最佳且烧结温度低于1300℃.

参考文献

[1] Lee M K;Chung J H;Ryu K W.Microwave dielectric properties of Ba (Mg,Ta) O3-Ba (Co,Nb) O3 ceramics[J].Electrical Insulating Materials,1998(09):139-142.
[2] Renoult O;Boilot J P;Chaput F .Sol -Gel Processing and Microwave Characteristics of Ba(Mg1/3Ta2/3)O3 Dielectrics[J].Journal of the American Ceramic Society,1992,75(12):3337-3340.
[3] Smethurst E;Budworth D W .The Preparation of Transparent Magnesia Bodies I.By Hot-Pressing,Ⅱ By Sintering[J].Transactions and Journal of the British Ceramic Society,1972,71(02):45-50.
[4] Haussonne JM;Desgardiu G;Bajolet P H et al.Barium Tianate perovskite sintered with lithium fluoride[J].Journal of the American Ceramic Society,1983,66(11):801-807.
[5] Chen X M;Wu Y J .Dielectric characteristics of Ba(Mg1/3 Ta2/3) O3 ceramics sintered at low temperatures[J].J Mater Sci Mater Elec,1996,7(06):369-371.
[6] Tamura H;Konoike T;Sakabe Y et al.Improved high -Q dielectric resonator with complex perovskite structure[J].Commu Am Ceram Soc,1984,67(04):c-59-c-61.
[7] J. H. Lee .Low-firing and microwave dielectric properties of Ba[(Ni0.6Zn0.4)0.33Nb0.67]O3 ceramics doped with Sb2O5 and B2O3[J].Journal of Materials Science,1999(3):625-628.
[8] 栾伟玲,高濂,郭景坤.超细BaTiO3陶瓷晶粒尺寸对介电性能的影响[J].硅酸盐学报,1999(01):84-88.
[9] 徐廷献;沈继跃;薄占满.电子陶瓷材料[M].天津:天津大学出版社,1993
[10] 郭秀芬 .陶瓷介质在微波技术中的应用[J].压电与声光,1990,12(06):40-47.
[11] Onoda M;Jun K;Kumiko K et al.Ba(Zn1/3Nb2/3)O3-Sr(Zn1/3Nb2/3)O3 solid solution ceramics with temperature -stable high dielectric constant and low microwave loss[J].Japanese Journal of Applied Physics,1982,21(12):1707-1710.
[12] Colla E L;Reany I M;Setter N .Effect of structural changes in complex perevskites on the temperature coefficient of the relative permittivity[J].Journal of Applied Physics,1993,74(05):3414-3425.
[13] Hong K S;Kim I T;Kim C D .Order-Disorder Phase Formation in the Complex Perovskite compounds Ba (Ni1/3Nb2/3)O3 and Ba(Zn1/3Nb2/3)O3[J].Journal of the American Ceramic Society,1996,79(12):3218-3224.
[14] Kim IT.;Yoon SJ.;Hong KS. .EFFECTS OF NON-STOICHIOMETRY AND CHEMICAL INHOMOGENEITY ON THE ORDER-DISORDER PHASE FORMATION IN THE COMPLEX PEROVSKITE COMPOUNDS, BA(NI1/3NB2/3)O-3 AND BA(ZN1/3NB2/3)O-3[J].Journal of Materials Science,1995(2):514-521.
[15] Powder Dffraction File.Card NO.21-81 International Center for Diffraction Data[M].Newtowne Square,PA
[16] Yoon K H;Kim D P;Kim E S .Effect of BaWO4 on the Dielectric Properties of Ba(Mg1/3 Ta2/3) O3 Ceramics[J].Journal of the American Ceramic Society,1994,77(04):1062-1066.
[17] Chai L;Akbas M A;Davies P K et al.Cation ordering transformations in Ba(Mg1/3Ta2/3)O3-BaZrO3 perovskite solid solutions[J].Materials Research Bulletin,1997,32(09):1261-1269.
[18] Park JK.;Kim DY. .EFFECT OF GRAIN SIZE ON DIFFUSION-INDUCED GRAIN-BOUNDARY MIGRATION IN BA(ZN1/3NB2/3)O-3 CERAMICS[J].Journal of the American Ceramic Society,1996(5):1405-1408.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%