欢迎登录材料期刊网

材料期刊网

高级检索

本文采用外加磁场诱导自蔓延高温合成钡铁氧体,试验用的电磁场强度最高可达1.3T,对无磁场和不同磁场强度下合成的铁氧体的形貌、相组成和磁性能分别进行了表征.研究结果表明:外加磁场对燃烧温度有影响,燃烧温度影响产物转换,燃烧温度较低时,产物为BaFe2O4与BaFe12O19相共存;本试验条件下,磁场强度为0.86T时,合成为M型的钡铁氧体(BaFe12O19),产物结晶完整,有六角片状的钡铁氧体,且性能达到了最佳,矫顽力达到1083(4π)-1·kA·m-1,比剩余磁化强度为16.16 A·m2/kg,比不加磁场条件下分别提高50%和提高32%,说明适当的磁场强度诱导自蔓延高温合成可以改善BaFe12O19的磁性能.

参考文献

[1] 兰银辉,高学绪,乔袆,高静,包小倩.自蔓延高温合成钡铁氧体的研究[J].材料导报,2007(z1):333-335.
[2] 肖奇,邱冠周,张清岑,黄苏萍.M-型超微钡铁氧体粉末制备技术的最新进展[J].中国粉体技术,1999(02):25-28.
[3] Yao Li;Jiupeng Zhao;Jiecai Han .Self-propagating high temperature synthesis of Ni_(0.35)Zn_(0.65)Fe_2O_4 ferrite powders[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2002(3):583-592.
[4] Warren B Cross;Louise Affleck;Maxim VKuznetsov et al.Self-propagating high-temperature synthesis of ferrite MFe2O4 (M= Mg,Ba,Co,Ni,Cu,Zn);reactions in an external magnetic field[J].Journal of Materials Chemistry,1999,9(10):2545-2552.
[5] Jun wang;Yejun wu;Yuejin Zhu .Cation distribution of MnFe2O4 Nanoparticles synthesized under an indeced magnetic field[J].International Journal of Modern Physics B,2007,21(05):723-729.
[6] Luis Fernámdez-Barquin;Maxim V Kuznetsova;Yuri G Morozov et al.Combustion synthesis of Chromium-substi-tuted Litjium ferrites Lio.s Fe2.5-xCr1xO4 (x 《2.0):Rietveld analysis and magnetic measurements[J].International Journal of Inorganic Materials,1999,1(05):311-316.
[7] Maxim V. Kuznetsov;Yury G. Morozov;Sergey M. Busurin .Phase composition and magnetism of combustion products in Ba-Fe-O compounds synthesized under applied DC electric field[J].Journal of Magnetism and Magnetic Materials,2007(1):202-206.
[8] Aguas MD.;Parkin IP.;Kuznetsov MV.;Steer WA.;Pankhurst QA. Barquin LF.;Affleck L. .The effect of large magnetic fields on solid state combustion reactions: novel microstructure, lattice contraction and reduced coercivity in barium hexaferrite[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2000(2):235-237.
[9] 钟世安,胡启明,古映莹.磁场对水热法制备锰锌铁氧体锰价态的影响[J].电子元件与材料,2006(04):44-46.
[10] 钟云波,李志华,任忠鸣,邓康,徐匡迪.磁场对纳米MnZn铁氧体前驱体形貌的影响[J].稀有金属材料与工程,2006(08):1263-1267.
[11] Affleck L.;Parkin IP.;Pankhurst QA.;Kuznetsov MV.;Aguas MD. .Microstructural aspects of the self-propagating high temperature synthesis of hexagonal barium ferrites in an external magnetic field[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2000(8):1925-1932.
[12] 李垚;韩杰才;杜善义 .铁氧体的自蔓延高温合成方法[J].功能材料,1999,30(06):598-600.
[13] 谢丹阳,高发明.M型钡铁氧体的制备与表征[J].兵器材料科学与工程,2004(01):6-9.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%