采用一种简单的物理技术-聚合物溶液或熔体浸润多孔阳极氧化铝(AAO)模板的方法,在孔径仅为200 nm的AAO模板中制备聚苯乙烯(PS)纳米管阵列.SEM和TEM测试结果表明:熔体法制备的纳米管壁厚约为110 nm;5.0 wt%和10.0 wt%的PS溶液制备的纳米管壁厚分别为70 nm和80 nm.并初步探索了模板法制备聚合物纳米管的多次浸润机理.
参考文献
[1] | Martin C R .Nanomaterials: A membrane -based synthetic approach[J].Science,1994,266(23):1961-1966. |
[2] | Steinhart M;Wendorff J H;Greiner A .Polymer nanotubes by wetting of ordered porous template[J].Science,2002,296(14):1997-1997. |
[3] | Zhiming Zhang;Meixiang Wan .Composite films of nanostructured polyaniline with poly(vinyl alcohol)[J].Synthetic Metals,2002(1):83-89. |
[4] | Long YZ.;Zhang LJ.;Ma XJ.;Chen ZJ.;Wang NL.;Zhang Z.;Wan MX. .Electrical conductivity of an individual polyaniline nanotube synthesized by a self-assembly method[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2003(16):938-942. |
[5] | Huang K.;Wan MX. .Self-assembled polyaniline nanostructures with photoisomerization function[J].Chemistry of Materials,2002(8):3486-3492. |
[6] | Kim K K;Jin L L .Preparation of PPV nanotubes and nanorods and carbonized products derived therefrom[J].Nano Letters,2001,1(11):631-636. |
[7] | Steinhart M.;Senz S.;Wehrspohn RB.;Gosele U.;Wendorff JH. .Curvature-directed crystallization of poly(vinylidene difluoride) in nanotube walls[J].Macromolecules,2003(10):3646-3651. |
[8] | Joo J.;Park KT.;Kim BH.;Kim MS.;Lee SY.;Jeong CK.;Lee JK.;Park DH. Yi WK.;Lee SH.;Ryu KS. .Conducting polymer nanotube and nanowire synthesized by using nanoporous template: Synthesis, characteristics, and applications[J].Synthetic Metals,2003(1/3):7-9. |
[9] | Yang YS.;Wan MX. .Chiral nanotubes of polyaniline synthesized by a template-free method[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2002(4):897-901. |
[10] | Zhang JX.;Chen FE.;Fu MX.;Shi GQ. .Aligned polythiophene coated gold nanowires[J].Synthetic Metals,2003(1/3):217-218. |
[11] | Cepak V M;Martin C R .Preparation of polymeric micro -and nanostructures using a template - based deposition method[J].CHEMISTRY OF MATERIALS,1999,11:1363-1367. |
[12] | Sufen Ai;Gang Lu;Qiang He;Junbai Li .Highly Flexible Polyelectrolyte Nanotubes[J].Journal of the American Chemical Society,2003(37):11140-11141. |
[13] | Huaqiang Cao;Zheng Xu;Hai Sang;Dong Sheng;Chenyang Tie .Template Synthesis and Magnetic Behavior of an Array of Cobalt Nanowires Encapsulated in Polyaniline Nanotubules[J].Advanced Materials,2001(2):121-123. |
[14] | Moon S I;McCarthy T J .Template synthesis and selfassembly of nanoscopic polymer "pencils"[J].Macromolecules,2003,36(12):4253-4255. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%