通过引入描述纳米微粒形状效应的形状因子,建立了金属纳米微粒尺寸形状效应的结合能函数与熔化温度函数.并根据上述函数得出了金属晶体纳米微粒存在的最小临界尺寸表达式与最低熔化温度表达式.利用上述关系式对金属纳米微粒进行了理论预测,并将预测结果与实验值进行了比较.
参考文献
[1] | 张立德;牟季美.纳米材料和纳米结构[M].北京:科学出版社,2001 |
[2] | 严东生;冯端.材料新星--纳米材料科学[M].长沙:湖南科学技术出版社,1998 |
[3] | Qi W H;Wang M P;Xu G Y .[J].Journal of Materials Science Letters,2003,1333 |
[4] | Hill T L.Themodynamics of Small Systems[M].New York and Amsterdam: W A Benjamin. INC,1963:6. |
[5] | Qi WH.;Wang MP.;Xu GY. .The particle size dependence of cohesive energy of metallic nanoparticles[J].Chemical Physics Letters,2003(5-6):632-634. |
[6] | Xie D;Qi W H;Wang M P.[J].Physical Review B |
[7] | Qi W H;Wang M P .[J].Journal of Materials Science Letters,2002,21:1743. |
[8] | Li CH.;Hoe JL.;Wu P. .Empirical correlation between melting temperature and cohesive energy of binary Laves phases[J].The journal of physics and chemistry of solids,2003(2):201-212. |
[9] | Mott N F .[J].Proceedings of the Royal Society of London,1934,146A:465. |
[10] | 蒋青;南胜辉;周明 .[J].金属学报,1998,34:870. |
[11] | Jiang Q;Zhang Z;Wang Y W .[J].Materials Science and Engineering,2000,286A:139. |
[12] | Jiang Q;Shi H X;Zhao M .[J].Journal of Chemical Physics,1999,111:2176. |
[13] | 谢丹;齐卫宏;汪明朴.[J].金属学报 |
[14] | Xie D;Qi W H;Wang M P.[J].Journal of Materials Science Letters |
[15] | Kim HK.;Huh SH.;Park JW.;Jeong JW.;Lee GH. .The cluster size dependence of thermal stabilities of both molybdenum and tungsten nanoclusters[J].Chemical Physics Letters,2002(1/2):165-172. |
[16] | Zhao M;Zhou X H;Jiang Q .[J].Journal of Materials Research,2001,3304 |
[17] | Jiang Q;Yang C C;Li J C .[J].Materials Letters,2002,56:1019. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%