综述了近几年La-Mg-Ni系贮氢合金的研究进展,阐述了为了提高电极合金综合性能所采取的手段,包括元素替代、制备复合贮氢材料、表面处理及制取工艺等.总结了La-Mg-Ni系贮氢合金目前存在的问题,并提出了今后应用研究的方向.
参考文献
| [1] | 大角泰章.金属氢化物的性质与应用[M].北京:化学工业出版社,1999:335. |
| [2] | J. K. Lomness;M. D. Hampton;L. A. Giannuzzi .Hydrogen uptake characteristics of mechanically alloyed mixtures of Ti-Mg-Ni[J].International journal of hydrogen energy,2002(9):915-920. |
| [3] | Kadir K;sakai T;Uehara 1 .Synthesis and structure determination of a new series of hydrogen storage alloys; RMg2Ni9 ( R = La, Ce, Pr,Nd,Sm and Gd) built from MgNi2 Laves-type layers alternating with AB5 layers[J].Journal of Alloys and Compounds,1997,257:115-121. |
| [4] | K.Kadir;N.Kuriyama .Structural investigation and hydrogen capacity of CaMg2Ni9: a new phase in the AB2C9 system isostructural with LaMg2Ni9[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(1/2):145-154. |
| [5] | Kadir K et al.Structural investigation and hydrogen capacity of YMg2Ni9 and (Y0. 5Ca0.5) (MgCa) Ni9: new phase in the AB2C9 system isostructural with LaMg2Ni9[J].Journal of Alloys and Compounds,1999,287:264-270. |
| [6] | Kadir K et al.Sructural investigation and hydrogen capacity of LaMg2Ni9 and (La0.65Ca0.35) ( Mg1.32Ca0.68 ) Ni9 of the AB2C9 type structure[J].Journal of Alloys and Compounds,2000,302:112-117. |
| [7] | J. Chen;N. Kuriyama;H. T. Takeshita;H. Tanaka;T. Sakai;M. Haruta .Hydrogen Storage Alloys with PuNi_3-Type Structure as Metal Hydride Electrodes[J].Electrochemical and solid-state letters,2000(6):249-252. |
| [8] | 刘永锋,潘洪革,高明霞,朱云峰,葛红卫,李寿权,雷永泉.稀土镁基贮氢电极合金的结构与电化学性能研究[J].金属学报,2003(06):666-672. |
| [9] | Kohon T et al.Hydrogen storage properties of new ternary system alloys: La2MgNi9、 La5Mg2Ni23、 La3MgNi14[J].Journal of Alloys and Compounds,2000,311:L5-L7. |
| [10] | 胡子龙.贮氢材料[M].北京:化学工业出版社,2002 |
| [11] | J.Chen;H.T.Takeshita .Hydriding properties of LaNi_3 and CaNi_3 and their substitutes with PuNi_3-type structure[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):304-313. |
| [12] | Chen Yun et al.Electrochemical properties of the ball-milled La1. 8 Ca0.2Mg14Ni3 + xwt % Ni composites (x = 0, 50,100, 200 )[J].Journal of Alloys and Compounds,2003,354:120-123. |
| [13] | Terzieva M.;Peshev P.;Khrussanova M. .Hydriding and dehydriding characteristics of Mg-LaNi5 composite materials prepared by mechanical alloying[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):235-239. |
| [14] | Akiba E et al.Phase components of the sintered Mg-xwt% LaNi5 (x = 20 ～ 50 ) composites and their hydrogen properties[J].Acta Materialia,2000,48:2363-2372. |
| [15] | Wei Wang;Changpin Chen;Lixin Chen .Change in structure and hydrogen storage properties of La_2Mg_(16)Ni alloy after modification by mechanical grinding in tetrahydrofuran[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2002(1/2):175-179. |
| [16] | Yongfeng Liu;Hongge Pan;Mingxia Gao .Hydrogen storage and electrochemical properties of the La_(0.7)Mg_(0.3)Ni_(3.825-x)Co_(0.675)Mn_x hydrogen storage electrode alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2004(1/2):246-252. |
| [17] | Chi Hong Zhong et al.Hydriling properties of La2Mg16Ni alloy prepared by mechanical milling in benzene[J].Journal of Alloys and Compounds,2003,360:312-315. |
| [18] | Pan Hongge et al.An investigation on the structural and electrochemical properties of La0.7Mg0.3 (Ni0.85Co0.15) (x = 3.15 - 3.80)hydrogen storage electrode alloys[J].Journal of Alloys and Compounds,2003,351:228-234. |
| [19] | B. Liao;Y. Q. Lei;G. L. Lu .The electrochemical properties of La_xMg_(3-x)Ni_9 (x= 1.0-2.0) hydrogen storage alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2003(0):746-749. |
| [20] | Liang G.;Huot J.;Van Neste A.;Schulz R.;Boily S. .Hydrogen absorption properties of a mechanically milled Mg-50wt%LaNi5 composite[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):302-307. |
| [21] | Kazuhide Tanaka;Yoshisada Kanda .Improvement of hydrogen storage properties of melt- spun Mg-Ni-RE alloys by nanocrystallization[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(0):521-525. |
| [22] | 刘永锋,潘洪革,高明霞,朱云峰,雷永泉.Influences of heat treatment on electrochemical characteristics of La0.75 Mg0.25 Ni2.8 Co0.5 hydrogen storage electrode alloy[J].中国有色金属学会会刊(英文版),2003(01):25-28. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%