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AB5型贮氢合金的性能主要取决于其成分、结构和显微组织.本文从ABs型贮氢合金的晶体结构出发,详细讨论了AB5型贮氢合金在诸多方面的优化措施:(1)化学成分上,向多元合金化发展,降低合金的成本,改善合金性能;(2)结构上,偏离AB5结构,发展非化学计量比合金;(3)显微组织上,从主相向"主相+辅相”发展;(4)工艺上,开发新的合金制备、热处理和表面改性等工艺方法;(5)改善合金使用环境;(6)研究方法上理论化、系统化.通过这些途径,可以对AB5型贮氢合金进行深入研究,进一步提高合金的性能.

参考文献

[1] 田莳.功能材料[M].北京:北京航空航天大学出版社,1995:210-223.
[2] 廖翠萍 .[J].新能源,1999,21(02):6-11.
[3] Ito H.;Yamamoto T.;Yamawaki M.;Yamaguchi K. .Hydrogen absorption properties of U6Mn and U6Ni[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(0):629-631.
[4] 茅益明.[J].国外金属材料,1992(05):15-21.
[5] 大角泰章.金属氢化物的性质及应用[M].北京:化学工业出版社,1990
[6] 陈长聘.金属氢化物基础、特性与应用[A].北京:航空工业出版社,1994:160-218.
[7] 周熠;雷永泉;罗永春 .气体雾化贮氢电极合金Ml(Ni,Co,Mn,Al)5的活化性能[J].金属学报,1996,32(08):857-861.
[8] 侯万良,常新春,王建强,郝云彦,张海峰,尹君,胡壮麒.双相MlNi3.7Al0.4Cu0.4微晶贮氢合金的结构及活化性能[J].材料研究学报,2000(z1):32-35.
[9] 陈磊,诸德威,张翠芬.贮氢合金物理活化的研究[J].电源技术,1999(Z1):64.
[10] Jae W O .[J].Journal of Alloys and Compounds,1998,278:270-276.
[11] 林勤 .[J].金属学报,1996,32(06):624628.
[12] 康龙,罗永春.贮氢合金动力学测试方法的研究[J].甘肃工业大学学报,1995(02):15.
[13] 江建军 .[J].功能材料,1998,29(01):33-37.
[14] 靳红梅,李国勋,张昭良,王超群,王瑞坤,孙丽虹.La1-xNdx(NiCoMnAl)5贮氢合金性能研究[J].中国稀土学报,1998(01):22-25.
[15] 江建军 .稀土成分对Re(NiCoMnTi)5贮氢合金电化学性能的影响[J].金属学报,1995,31(08):B379-B383.
[16] 王超群 .[J].电源技术,1998,22(01):5-7.
[17] 张文鹏,吴建民,王峰松,魏丹.稀土含量对MmNi5基储氢合金性能的影响[J].金属功能材料,1998(04):176.
[18] Joubert JM.;Percheron-Guegan A.;Bouree-Vigneron F.;Latroche M. .Thermodynamic and structural comparison between two potential metal-hydride battery materials LaNi3.55Mn0.4Al0.3Co0.75 and CeNi3.55Mn0.4Al0.3Co0.75[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(0):118-122.
[19] 靳红梅,李国勋,周传华,郑青军.La1-x-y-zCexPryNdzB5电极材料组成的优化与设计[J].中国稀土学报,1998(04):348-352.
[20] WillemsJ J G .[J].Philips Journal of Research,1984(39):1-9.
[21] Boonstra A H .[J].Journal of the Less-Common Metals,1990,159:327-336.
[22] Makamura H .[J].Journal of Alloys and Compounds,1998,281:81-91.
[23] 吕建国 .MlαMm1αNi5贮氢合金结构与组织研究[D].西安:西安理工大学材料学院,2000.
[24] Adzic GD.;Reilly JJ.;Mcbreen J.;Mukerjee S.;Kumar MPS. Zhang W.;Srinivasan S.;Johnson JR. .CERIUM CONTENT AND CYCLE LIFE OF MULTICOMPONENT AB(5) HYDRIDE ELECTRODES[J].Journal of the Electrochemical Society,1995(10):3429-3433.
[25] 王超群 .[J].电源技术,1998,22(03):107-110.
[26] Cossianteli J M .[J].Journal of Alloys and Compounds,1997,253-254:642-647.
[27] 沈剑韵 .[J].电源技术,1995,19(04):9-11.
[28] Nakamura Y.;Fujitani S.;Nishio K.;Oguro K.;Uehara I.;Sato K. .Lattice expanding behaviour and degradation of LaNi5-based alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):205-210.
[29] Chartouni D .[J].Journal of Alloys and Compounds,1996,241:160-166.
[30] Hu WK.;Kim DM.;Jeon SW.;Lee JY.;Lee H. .Electrochemical behaviors of low-Co Mm-based alloys as MH electrodes[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):261-265.
[31] 葛副鼎,李伟健,王新林,朱静.MmNi3.8Mn0.55C0.6Ti0.05储氢合金的微观结构研究[J].金属功能材料,1997(05):216.
[32] Suzuki K .[J].Journal of Alloys and Compounds,1993,192:173-175.
[33] 盖迎新.MmNis5基储氢电极材料电化学性能的研究[A].北京:化学工业出版社,1995:425-427.
[34] 张昭良 .[J].物理化学学报,1998,14:954-956.
[35] 郭靖洪,燕萍,庞柳萍,唐丽新,张建海,夏春明,段秋生,刘国忠.贮氢合金Ml(Ni Co Mn Al)s中Ce和Nd对MH-Ni电池性能的影响[J].电源技术,2000(05):265-266,287.
[36] 王超群 .[J].电源技术,1998,22(04):158-160.
[37] Notten P H L .[J].Advanced Materials,1991,3:343.
[38] LI Z P .[J].Electrochimica Acta,1995,40:467-471.
[39] WANG Xin-hua .[J].Journal of Alloys and Compounds,1996,232:192-196.
[40] 王新华.Ca对MI1-xCaxNi5系氢化物稳定性的影响[A].北京:化学工业出版社,1995:363-366.
[41] 江建军 .[J].电源技术,1998,22(02):61-64.
[42] 康龙,罗永春.LaNi5-xAlx贮氢合金的研究[J].稀土,1997(02):6.
[43] 周志刚 .[J].电源技术,1997,21(04):153-155,157.
[44] 江建军.[J].材料导报,1993(06):16-18.
[45] Srivastava S.;Srivastava ON. .Investigations on synthesis, characterization and hydrogenation behaviour the spin- and thermal-melted versions of LaNi5-xSix (x = 0.1, 0.3, 0.5)[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):240-245.
[46] Sakai T .[J].SJ Less-common Met,1990,161:193-202.
[47] 程菊.镍氢电池及储氢合金的进展[J].金属功能材料,1996(03):86.
[48] 谢中伟 .[J].电池,1996,26(03):144-146.
[49] Hu WK.;Jang KJ.;Lee JY.;Kim DM. .Studies on Co-free rare-earth-based hydrogen storage alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):254-258.
[50] Hu Wei-Kang .[J].Journal of Alloys and Compounds,1998,279:295-300.
[51] 赵爽,林勤,朱大建,陈宁,袁永文.Sn对稀土系贮氢合金性能的影响[J].中国有色金属学报,2000(01):73-76.
[52] Balasubramaniam R .[J].Journal of Alloys and Compounds,1993,196:63-70.
[53] 陈立新 .[J].中国有色金属学报,1999,9(01):61-64.
[54] 赵东江,马松艳.影响贮氢电极性能因素的研究Ⅲ金属氧化物掺杂的影响[J].电源技术,2000(04):197-199.
[55] 靳红梅 .[J].电源技术,1997,21(04):170-173.
[56] 陈卫祥 .[J].金属学报,1998,4(02):184-188.
[57] Notten P H L .[J].Journal of the Electrochemical Society,1991,138(07):1877-1885.
[58] Mishima R .[J].Journal of Alloys and Compounds,1993,192:176-178.
[59] Chuan-jian Li .[J].Journal of Alloys and Compounds,1998,266:300-306.
[60] 李传健 .[J].电源技术,1998,22(02):68-71.
[61] Lei Yong-quan .[J].Journal of Alloys and Compounds,1997,253-254:590.
[62] 罗永春 .[J].电源技术,1997,21(04):147-152.
[63] Takeya K .[J].Journal of Alloys and Compounds,1993,192:167-169.
[64] Adachi G .[J].Journal of the Less-Common Metals,1981,83:345.
[65] Sakai T .[J].Z Phys Chem(Munich),1989,164:1539-1544.
[66] Wei-kang Hu .[J].Materials Chemistry and Physics,1995,41:141-145.
[67] Chuan-Jian Li .[J].Journal of Alloys and Compounds,1998,274:278-283.
[68] Sakai T .[J].Journal of Alloys and Compounds,1993,192:155-157.
[69] 郑青军,周传华,李国勋.稀土镍系贮氢合金的放电电压平台研究[J].电源技术,1999(06):298.
[70] Yang QM.;Ryan DH.;Strom-Olsen JO.;Ciureanu M. .Composite hydride electrode materials[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):266-273.
[71] Sakal T.[J].Journal of less-common Matels,1991:1175-1184.
[72] ZHANG Yun-shi .[J].Journal of Alloys and Compounds,1993,192:L37-L38.
[73] 孙俊才 .[J].材料科学与工艺,1995,3(01):49-52.
[74] Ikeya T .[J].Journal of the Electrochemical Society,1993,140:3082-3086.
[75] Wada M .[J].Journal of Alloys and Compounds,1993,192:164-166.
[76] 尹鸽平,夏保佳,程新群,史鹏飞.贮氢合金表面处理及其对氧化物含量的影响[J].电源技术,2000(03):144-145,188.
[77] Matsuoka M .[J].Electrochimica Acta,1993,38:659-662.
[78] Hisa H .[J].Journal of Alloys and Compounds,1997,253-254:525-528.
[79] 周震.用HAc-NaAc缓冲溶液对AB5型储氢合金表面改性的研究[J].稀土,1998(04):30.
[80] Zuttle A .[J].Journal of Alloys and Compounds,1994,209:99-105.
[81] Gao L .[J].Electrochimica Acta,1994(39):1681-1693.
[82] 崔舜.热处理对贮氢合金电化学性能的影响[J].稀有金属,1999(03):201-204.
[83] 李传键,王新林.Mm(NiMnTiCo)5贮氢合金的制备工艺、 电化学性能及相结构研究[J].中国稀土学报,1998(04):343-347.
[84] 靳红梅 .[J].电源技术,1997,21(02):58-60,76.
[85] Hu Wei Kang .[J].Journal of Alloys and Compounds,1998,270:255-264.
[86] 桑革,涂铭旌,李全安,闫康平,陈云贵,李宁,唐定骧.LaNi4.7Al0.3和MlNi4.5Al0.5合金在H2-CO系统中贮氢性能下降的研究[J].中国有色金属学报,2000(01):69-72.
[87] Stephanie Corre .[J].Journal of Alloys and Compounds,1998,275-277:99-104.
[88] 赵爽 .[J].金属学报,1999,35(01):65-69.
[89] LIU J .[J].Journal of the Less-Common Metals,1983,90:11-20.
[90] GuoJin .[J].Journal of the Electrochemical Society,1997,144(07):2276-2278.
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