利用WD-01分散剂辅助球磨分散法和涂布技术,制备多壁碳纳米管(MWNT)/改性聚醚酮(PEK-C)复合薄膜,考察树脂浓度、球磨时间、涂布液放置时间及MWNT含量等因素对薄膜导电性能的影响,研究MWNT含量及残留溶剂对薄膜储能模量及玻璃化转变温度(Tg)的影响.结果表明,由WD-01分散剂辅助球磨分散法可以剪短并有效分散MWNT;涂布液黏度增大能有效抑制MWNT的再团聚;在MWNT含量在8% ~33.3%的范围内,薄膜电导率随MWNT含量的增加呈线性升高,在MWNT含量为33.3%时,薄膜电导率达7.2S/cm;碳纳米管吸附溶剂使薄膜的玻璃化转变温度降低.
参考文献
[1] | J.K.W.Sandler;J.E.Kirk;I.A.Kinloch;M.S.P.Shaffer;A.H.Windle .Ultra-low electrical percolation threshold in carbon-nanotube-epoxy composites[J].Polymer: The International Journal for the Science and Technology of Polymers,2003(19):5893-5899. |
[2] | Alig I;Lellinger D;Dudkin SM;Potschke P .Conductivity spectroscopy on melt processed polypropylene-multiwalled carbon nanotube composites: Recovery after shear and crystallization[J].Polymer: The International Journal for the Science and Technology of Polymers,2007(4):1020-1029. |
[3] | Vincenza Antonucci;Gabriella Faiella;Michele Giordano;Luigi Nicolais;Gianpiero Pepe .Electrical Properties of Single Walled Carbon Nanotube Reinforced Polystyrene Composites[J].Macromolecular symposia,2007(0):172-181. |
[4] | Potschke P;Abdel-Goad M;Alig I;Dudkin S;Lellinger D .Rheological and dielectrical characterization of melt mixed polycarbonate-multiwalled carbon nanotube composites[J].Polymer: The International Journal for the Science and Technology of Polymers,2004(26):8863-8870. |
[5] | BAUHOFER W;KOVACS J Z .A review and analysis of electrical percolation in carbon nanotube polymer composites[J].Composites Science and Technology,2009,69(11):1486-1498. |
[6] | Ki Hong Kim;Won Ho Jo .A strategy for enhancement of mechanical and electrical properties of polycarbonate/multi-walled carbon nanotube composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(4):1126-1134. |
[7] | CHENG Q F;WANG J P;WHEN J J et al.Carbon nanotubes/epoxy composites fabricated by resin transfer molding[J].CARBON,2010,48(01):260-266. |
[8] | Qing-Ping Feng;Jiao-Ping Yang;Shao-Yun Fu .Synthesis of carbon nanotube/epoxy composite films with a high nanotube loading by a mixed-curing-agent assisted layer-by-layer method and their electrical conductivity[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(7):2057-2062. |
[9] | 张宝艳,李萍,陈祥宝.新型改性双马来酰亚胺树脂体系[J].高分子材料科学与工程,2000(02):67-69. |
[10] | 王汝敏,杨利,郑水蓉,蓝立文.热塑性树脂增韧MBMI/DABPA复合材料效果研究[J].固体火箭技术,2001(04):62-65. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%