利用磁场辅助硫化工艺,制备了含有排列的微米铁粉的硅橡胶复合材料,测量了体系的压阻特性.结果表明,该复合材料显示丰富的压阻特性,初始电阻大于1010Ω的体系显示负压阻特性,而小于1010Ω的体系显示正压阻特性;填充了10%,20%,50%(质量分数)铁粉的硅橡胶在加载压力0.2MPa前后出现正压阻渗流转变,电阻变化达103~105//Ω个量级,然而,质量分数ψ=50%,磁感应强度B=0.2T体系显示线性正压阻特性.初步研究认为,体系压阻行为的复杂性与磁场在基胶中诱导的导电路径构象的多样性有关.
参考文献
[1] | R. Strumpler;J. Glatz-Reichenbach .Conducting polymer composites[J].Journal of electroceramics,1999(4):329-346. |
[2] | 耿新玲,刘君,任玉柱,苏正涛,王景鹤.导电硅橡胶研究进展[J].航空材料学报,2006(03):283-288. |
[3] | CHUNG D D L .Self-monitoring structural materials[J].Materials Science and Technology,1998,R22:57-78. |
[4] | N. Muto;Y. Arai;S.G. Shin .Hybrid composites with self-diagnosing function for preventing fatal fracture[J].Composites science and technology,2001(6):875-883. |
[5] | Wu ZS;Yang CQ;Harada T;Ye LP .Self-diagnosis of structures strengthened with hybrid carbon-fiber-reinforced polymer sheets[J].Smart Materials & Structures,2005(3):S39-S51. |
[6] | Wang Luheng;Ding Tianhuai;Wang Peng .Effects of conductive phase content on critical pressure of carbon black filled silicone rubber composite[J].Sensors and Actuators, A. Physical,2007(2):587-592. |
[7] | LALLI J H;CLAUS R O;HILL A B et al.Commercial applications of metal rubber[J].Proceedings of Spie,2005,5762(01):1-6. |
[8] | 谢泉,刘让苏,徐仲榆,彭平.白炭黑和炭黑含量对导电硅橡胶拉敏特性影响的研究[J].高分子材料科学与工程,1998(01):94-97. |
[9] | 宋义虎,郑强,潘颐,益小苏.单轴压力对高密度聚乙烯/碳黑导电复合材料电阻特性的影响[J].高等学校化学学报,2000(03):475-479. |
[10] | Lu JR;Weng WG;Chen XF;Wu DJ;Wu CL;Chen GH .Piezoresistive materials from directed shear-induced assembly of graphite nanosheets in polyethylene[J].Advanced functional materials,2005(8):1358-1363. |
[11] | MAMUNYA Ye P;ZOIS H;APEKIS L et al.Influence of pressure on the electrical conductivity of metal powders used as fillers in polymer composites[J].Powder Technology,2004,140:49-55. |
[12] | Manwar Hussain;Yong-Ho Choa;Koichi Niihara .Fabrication process and electrical behavior of novel pressure-sensitive composites[J].Composites, Part A. Applied science and manufacturing,2001(12):1689-1696. |
[13] | Beruto DT;Capurro M;Marro G .Piezoresistance behavior of silicone-graphite composites in the proximity of the electric percolation threshold[J].Sensors and Actuators, A. Physical,2005(2):301-308. |
[14] | Bangwen Zhang;Changsheng Xie;Junhui Hu .Novel 1-3 metal nanoparticle/polymer composites induced by hybrid external fields[J].Composites science and technology,2006(11/12):1558-1563. |
[15] | 张邦文,谢长生,胡军辉,王辉虎,桂阳海.金属纳米粒子在聚合物中的磁致排列--实验及分子动力学模拟[J].高等学校化学学报,2005(11):2131-2134. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%