钢铁表面热镀Al3Ni耐蚀合金镀层工艺涉及Al3Ni合金由液态冷凝固化成镀层的过程.冷凝速度对微结构的影响是工艺中关键问题之一.本文采用F-S多体势对液态合金Al3Ni在不同冷却速度下的微观结构及其转变机制进行了分子动力学模拟,得到了不同冷速下各温度的双体分布函数;采用HA键型指数法对其结构进行了分析,结果表明,Al3Ni在两种冷速下均以非晶的形式出现,只是慢冷时体系的有序度略有升高,这为最终确定工艺参数提供了理论依据.
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