用表面增强拉曼光谱技术(SERS)对在0.5mol/LH2SO4溶液中苯并三氮唑BTAH及其衍生物4CBTAH(4羧基苯并三唑)对铜的缓蚀作用机理进行了研究,发现4CBTAH对铜的作用与BTAH的作用机理相似,在较正电位下两者都是通过三唑环与铜形成配合物覆盖在铜表面,随着电位负移在铜电极表面吸附的聚合物膜逐渐转化为分子形式吸附,4CBTAH中的-COOH基团只是起到空间位阻的作用,没有参与电极表面的吸附.
参考文献
| [1] | Zhou Guoding;Ma Zhichuan;Tong Ruting et al.Corrosion inhibition of copper with benzotriazole and tolyltriazole in a 3% NaCl solution[J].Bulletin of Electrochemistry,1991,7(02):60-63. |
| [2] | Zhou Guoding;Shao Hua;Loo B H .A study of the copper electrode behaviour in borax buffer solutions containing chloride ionsand benzotriazole-type inhibitors by voltammetry and photocurrent response method[J].Journal of Electroanalytical Chemistry,1997,421:129-135. |
| [3] | Zhou Guoding;Cai Shengmin;Song Liqun et al.A comparative study of the inhibition effects of benzotriazole and 6-aniline-1,3,5-triazine-2,4-dithiol monosodium salt on the corrosion of copper by potentiodynamic polarization,AC impedance and surface-enhanced Raman spectroscopic techniques[J].Applied Surface Science,1991,52:227-234. |
| [4] | Xu Qunjie;Zhou Guoding;Lu Zhu et al.Comparative investigation of several corrosion inhibitors of copper by using AC impedance spectroscopy[J].Journal of East China University of Science and Technology,1998,24(03):324-328. |
| [5] | Xu Qunjie;Zhou Guoding;Lu Zhu et al.Comparative investigation of several corrosion inhibitors of copper at different pH values using ac impedance spectroscopy[J].腐蚀与防护,1999,20(04):160-161. |
| [6] | 徐群杰,周国定,陆柱,姚念,张红伟.苯并三氮唑和4-羧基苯并三氮唑对铜缓蚀作用的光电化学比较[J].华东理工大学学报（自然科学版）,2000(02):172-176. |
| [7] | Tian Zhongqun;Ren Bing;She Chunxing et al.Applications and prospectus of electrochemical in-situ Raman spectroscopy[J].ELECTROCHEMISTRY,1999,5(01):1-13. |
| [8] | Lin Zhonghua;Wang Fengchun;Tian Zhongqun .Inhibition mechanism of 2-aminopyrimidine for copper corrosion[J].Journal of Physical Chemistry,1992,8:87-89. |
| [9] | Xu Haibo;Yu Jiakang;Dong Junhua et al.SERS and electrochemical studies of adsorption of thiourea and urea at silver electrode[J].腐蚀科学与防护技术,1997,9(04):302-307. |
| [10] | Xu Qunjie;Zhou Guoding;Lu Zhu et al.SERS studies of corrosion inhibition of BTA and 4CBTA on copper electrode in 3% aCl solution[J].The Chinese Journal of Nonferrous Metals,2001,11(01):135. |
| [11] | Kester J J;Furtak T E;Bevolo A J .Surface-enhanced Raman scattering in corrosion science: Benzotriazole on copper[J].Journal of the Electrochemical Society,1982,129:1716-1719. |
| [12] | Fleishmann M;Mengoli G;Musiani M M et al.An Electrochemical and Raman spectroscopic investigation of synergetic effects in the corrosion inhibition of copper[J].Electrochimica Acta,1985,30:1591-1602. |
| [13] | J C Rubim;J H Kim;E Henderson et al.Surface-enhanced Raman scattering and atomic force microscopy of brass electrodes in sulfuric acid solution containing benzotriazole and chloride ion[J].Applied Spectroscopy,1993,47:80. |
| [14] | ARAMAKI K;Kiuchi T;Sumiyoshi T et al.Surface enhanced Raman scattering and impedance studies on the inhibition of copper orrosion in sulphate solutions by 5-substituted benzotriazoles[J].Corrosion Science,1991,32:87-96. |
| [15] | Hope G A;Schweinsberg D P;Fredericks P M .Application of FT-Raman Spectroscopy to the study of the benzotriazole inhi ition of acid copper corrosion[J].Spectrochimica Acta,1994,50(11):2019-2026. |
| [16] | Schweinsberg D P;Bottle S E;Otieno-Alego V et al.A near-infrared FT-Raman (SERS) and electrochemical study of the synergistic effect of 1-[(1',2'- dicarboxy)ethyl]-benzotriazole and KI on the dissolution of copper in aerated sulfuric acid[J].Journal of Applied Electrochemistry,1997,27:161-168. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%