研究了不同水热碱性条件下(糖)醇对Cu2+的还原,通过控制不同水热条件及添加不同种类和质量的(糖)醇,借助XRD和SEM分析,得到了不同的产物及形貌.当不加任何(糖)醇时,产物为CuO,其形貌随[OH-]/[Cu2+]增大而由薄带和球形颗粒向薄片转变;当在不同[OH-]/[Cu2+]的体系中分别添加不同种类和质量的(糖)醇时,可以得到具有多种形貌的Gu2O和线状、棒状、立方六角状、颗粒状等形貌的金属铜.本研究可得结论是,水热条件下,[OH-]/[Cu2+]值可以决定还原产物形貌,(糖)醇的加入可以与Cu2+或其络合物发生氧化还原反应,而且加入的质量和种类可以决定产物的形貌.研究结果为新型金属和金属氧化物材料的制备提供了新思路.
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