采用交流微弧氧化法于Na2SiO3-KOH-(NaPO3)6溶液中在Ti6Al4V表面形成了氧化物陶瓷膜.利用扫描电镜、电子探针及X射线衍射研究了陶瓷膜的组织形貌、元素的分布和相组成.研究表明:在恒定的微弧氧化电参数(U+=500V,U_=100V和f=600Hz)下,随氧化时间延长,电流密度逐渐降低,膜层厚度不断增加;相对致密均匀的膜分为3层:过渡层、致密层与疏松层.膜层主要由TiO2(锐钛矿和金红石)相组成,延长处理时间,锐钛矿相及金红石相的相对含量发生变化,金红石相TiO2逐渐增多,而锐钛矿相TiO2减小.膜层相的形成过程可分为两个阶段.
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