评述了Pt-Rh、Pt-Pd-Rh和Pt-Pd-Rh-RE合金催化网的应用性能、结构再造和失活方面的问题.在Pt-Rh合金中添加Pd组元或在Pt-Pd-Rh合金中增大Pd的浓度或添加微量RE元素,可使氨转化率在原合金基础上再提高1.0～1.5%,并可一定程度降低铂耗率和氨耗率,减轻了催化网的腐蚀和表面结构再造的程度.分析了铂合金催化网的表面化学状态和结构再造及其机制,讨论了铂合金催化网的瞬态高热反应与失活效应.
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