用厚膜、薄膜和叠片工艺制作的氧传感器,降低了总阻抗,从而降低了工作温度和缩短了响应时间.通过测量电离或催化反应得到的氧,极限电流型气体传感器的测量范延伸到H2O、CO2、H2、CO和HCs.采用离子-电子混合导体膜作为扩散控制层改善了电流测量型传感器的性能.与掺杂Y2O3稳定的ZrO2相比,采用掺杂In2O3、Y2O3稳定的ZrO2可抑制老化时电导率的降低.用高能球磨技术可以制备3价阳离子稳定的氧化锆.
参考文献
| [1] | A. Rivera;J. Santamaria;C. Leon .Electrical conductivity relaxation in thin-film yttria-stabilized zirconia[J].Applied physics letters,2001(5):610-612. |
| [2] | Luo J.;Almond P. .Ionic mobilities and association energies from an analysis of electrical impedance of ZrO_2-Y_2O_3 alloys[J].Journal of the American Ceramic Society,2000(7):1703-1708. |
| [3] | Zuoyan Peng;Meilin Liu;Ed. Balko .A new type of amperometric oxygen sensor based on a mixed-conducting composite membrane[J].Sensors and Actuators, B. Chemical,2001(1):35-40. |
| [4] | Bae J.W.;Park J.Y. .Characterization of yttria-Stabilized Zirconia Thin Films Prepared by Radio Frequency Magnetron Sputtering for a Combustion Control Oxygen Senso[J].Journal of the Electrochemical Society,2000(6):2380-2384. |
| [5] | Cao W;Tan O K;Zhu W et al.An amorphous-like x α-Fe2O3-(1-x )ZrO2 solid solution system for low temperature resistive-type oxygen sensing[J].Sensors and Actuators B:Chemical,2001,77(1-2):421-426. |
| [6] | Weller M.;Damson B. .Mechanical loss of cubic zirconia[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):47-53. |
| [7] | ROBERTSON N L;Michaels J N .Double layer capacitance of porous platinum electrodes in zirconia electrochemical cells[J].Journal of the Electrochemical Society,1991,138(05):1494-1499. |
| [8] | Yoshiharu U;Kazushi T;Tsutomu I et al.Reaction in vapor-phase electrolytic deposition for preparing yttria-stabilized zirconia thin films[J].Journal of the American Ceramic,2000,83(01):77-81. |
| [9] | JONG-HEUN L;Mori T;Ji-Guang L et al.Improvement of grain-boundary conductivity of 8 mol% yttria-stabilized zirconia by precursor scavenging of siliceous phase[J].Journal of the Electrochemical Society,2000,147(07):2822-2829. |
| [10] | JONG-HEUN L;Toshiyuli M;Ji-Guang L et al.Precursor scavenging of resistive grain-boundary phase in 8 mol% ytterbia-stabilized zirconia[J].Journal of the Electrochemical Society,2002,149(03):J35-J40. |
| [11] | ROBERTSON N L;Michaels J N .Oxygen exchange on platinum electrodes in zirconia cells: Location of electrochemical reaction sites[J].Journal of the Electrochemical Society,1990,137(01):129-135. |
| [12] | Makovos E B;Liu C C .Development of a solid electrolyte sensor for oxygen in hot gases[J].Sensors and Actuators B-Chemical,1991,3(01):15-22. |
| [13] | Kohno K;Takeda Y;Imanishi N et al.Preparation and characterization of platinum-ceramic composite powders and thin films[J].Journal of the American Ceramic Society,1993,76(01):192-196. |
| [14] | Chu W F;Leonhard V;Erdmann H et al.Thick-film chemical sensors[J].Sensors and Actuators B-Chemical,1991,4(3-4):321-324. |
| [15] | Sridhar K R;Blanchard J A .Electronic condition in low oxygen partial pressure measurements using an amperometric zirconia oxygen sensor[J].Sensors and Actuators B-Chemical,1999,59(01):60-67. |
| [16] | Vasylkiv O.;Sakka Y. .Noniosthermal Synthesis of Yttria-Stabilized Zirconia Nanopowder through Oxalate processing: I, Characteristics of Y-Zr Oxalate Synthesis and Its Decomposition[J].Journal of the American Ceramic Society,2000(9):2196-2202. |
| [17] | Yu Shougeng;Zhang Xiaomin;Liu Enuo.Thick film platinum resistance paste characterized by TCR 3850[A].Naples, Florida,1991:283-287. |
| [18] | Komachiya M;Suzuki S;Fujita T et al.Limiting-current type air-fuel sensor using porous zirconia layer without inner gas chambers: proposal for a quick-startup sensor[J].Sensors and Actuators B-Chemical,2001,73(01):40-48. |
| [19] | Takeuchi T;Watanabe S;Hatano Y et al.Current-voltage characteristic of various metal electrodes in limiting-current-type zirconia cells[J].Journal of the Electrochemical Society,2001,148(09):H132-H138. |
| [20] | Kei Mochizuki;Ryoji Sorita;Hiromasa Takashima;Kenichi Nakamura;Geyu Lu .Sensing characteristics of a zirconia-based CO sensor made by thick-film lamination[J].Sensors and Actuators, B. Chemical,2001(1/2):190-195. |
| [21] | Junya Kondoh;Hirohisa Shiota;Shiomi Kikuchi .Changes in Aging Behavior and Defect Structure of Y_2O_3 Fully Stabilized ZrO_2 by In_2O_3 Doping[J].Journal of the Electrochemical Society,2002(8):J59-J72. |
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