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评述了近年来ICP-MS测定地质品样中金的预处理方法,包括火试金法、氯化法、酸溶法及熔融等.火试金是经典的方法,但其具有操作繁琐、劳动强度大等缺点;氯化处理法有局限性,对样品中有抗氯化作用的非金属部分不溶解;熔融法一般用于处理不溶的残渣,更适用于难溶矿样的处理;酸溶法现在应用比较广泛,但一般需结合富集的方法.

参考文献

[1] 蔡树型;黄超.贵金属分析[M].北京:冶金工业出版社,1984
[2] 杨丙雨 .化学发光法测定金的进展[J].黄金,1993,14(08):52-57.
[3] 冯玉怀;石星明 .1995年中国金分析测定的进展[J].地质实验室,1996,12(05):314-320.
[4] 杨丙雨;冯玉怀;石星明 .90年代前5年中国金分析测定的成就[J].冶金分析,1996,16(06):29-32.
[5] 吕文广 .微珠析出比色法在黄金开发中的应用[J].黄金,1996,17(12):45-48.
[6] 朱利亚,吴瑞林,杨晓云.金银滴定分析方法一览[J].贵金属,1996(04):45-50.
[7] 冯玉怀;石星明;杨丙雨 .1996年中国金分析测定的进展[J].地质实验室,1997,13(04):269-275.
[8] 石星明;冯玉怀;杨丙雨 .1997年中国金分析测定的进展[J].地质实验室,1998,14(04):242-248.
[9] 杨丙雨.中国金分析50年[J].黄金,2000(01):50.
[10] 薛光 .金测定方法的最新进展(待续)[J].黄金,1999,20(06):50-51.
[11] 薛光 .金测定方法的最新进展(续一)[J].黄金,1999,20(07):46-50.
[12] 薛光 .金测定方法的最新进展(续二)[J].黄金,1999,20(08):48-53.
[13] 薛光 .金测定方法的最新进展(续三)[J].黄金,1999,20(09):48-51.
[14] 薛光 .金测定方法的最新进展(续完)[J].黄金,1999,20(10):48-50.
[15] B.J. Perry;R.R. Barefoot;J.C. Van Loon .Inductively coupled plasma mass spectrometry for the determination of platinum group elements and gold[J].TrAC: Trends in Analytical Chemistry,1995(8):388-397.
[16] 薛光.加氯化钠焙烧提高含铜金精矿中金、银、铜浸出率的试验研究[J].黄金,2002(12):32-35.
[17] 薛光.金的分析化学[M].北京:宇航出版社,1990:60-65.
[18] 吴瑞林,李茂书,吴立生.贵金属试金分析方法评论[J].贵金属,1997(01):44-48.
[19] HALL G E M;Pelchat J C .Analysis of geological material for gold,platinum and palladium at low ppb levels by fire assay-ICP mass[J].Chemical Geology,1994,115(1-2):61-72.
[20] Paukert T .Determination of noble metals in rocks,waters and plants by inductively coupled plasma mass spectrometry[J].Chemicke Listy,1993,87(01):8-15.
[21] Kiwamu Oguri;Gen Shimoda;Yoshiyuki Tatsumi .Quantitative determination of gold and the platinum-group elements in geological samples using improved NiS fire-assay and tellurium coprecipitation with inductively coupled plasma-mass spectrometry (ICP-MS)[J].Chemical geology,1999(3-4):189-197.
[22] Gros M.;Lorand JP.;Luguet A. .Analysis of platinum group elements and gold in geological materials using NiS fire assay and Te coprecipitation; the NiS dissolution step revisited[J].Chemical geology,2002(3-4):179-190.
[23] 刘小荣,董守安.铂族元素和金的硫化镍试金预富集在现代仪器分析方法中的应用[J].贵金属,2002(01):45-52.
[24] Sun M;Jain J;Zhou M F et al.A procedual modification for enhanced recovery of precious metals(Au,PGE) following nickel sulfide fire assay and tellurium co-precipitation:applications for analysis of geological samples by inductively coupled plasma mass spectrometry .Canadian[J].Applied Spectroscopy,1993,38(04):103-108.
[25] JARVIS K E;Williams J G;Parry S J et al.Quantitative determination of the platinum-group using NiS fire assay with laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS)[J].Chemical Geology,1995,124(1-2):37-46.
[26] Frimpong A;Fryer B J;Longerich H P et al.Recovery of problems at nanogram per gram concentrations[J].Analyst,1995,120:1675-1680.
[27] JUVONEN R;Kallo E;Lakomaa T .Determination of precious metals in rocks by inductively coupled plasma mass spectrometry using nickel sulfide concentration,comparison with other pre-treatment methods[J].Analyst,1994,119:617-621.
[28] Jackson S E;Fryer B J;Goss W et al.Determination of the precious metals in geological material by inductively coupled plasma-mass spectrometry(ICP-MS) with nickel sulfide fire-assay collection and tellurium coprecipitation[J].Chemical Geology,1990,83(1-2):119-132.
[29] Paukert T;Rubeska I .Effects of fusion charge composition on the determination of platinum group elements using collection into a minimized nickel sulphide button[J].Analytical Biochemistry,1993,278(1-2):125-136.
[30] Boisvert R;Bergeron M;Turcotte J .Re-examination of the determination of palladium,platinum and rhodium in rocks by nickel sulphide fire assay followed by graphite furnace atomic absorption measurements[J].Analytical Biochemistry,1991,246(02):365-373.
[31] Mcdonald I;Hart R J;Tredoux M .Determination of the platinum-group elements in South African kimberlites by nickel sulphide fire-assay and neutron activation analysis[J].Analytical Biochemistry,1994,289(02):237-247.
[32] Bruce J Perry;Jon C Van Loon .Dry-chlorination inductively coupled plasma mass spectrometric method for the determination of platinum group elements in rocks[J].Journal of Analytical Atomic Spectrometry,1992,7:883-888.
[33] PERRY B J;Speller D V;Barefoot R R et al.A large sample,dry chlorination,ICP-MS analytical method for the determination of platinum group elements and gold in rocks[J].Canadian Journal of Applied Spectroscopy,1993,38(05):131-136.
[34] PERRY B J;Barefoot R R;Van Loon J C.Application of Plasma Source Mass Spectrometry II[M].Cambridge,UK:The Royal Society of Chemistry,1993
[35] PERRY B J;Speller O V .Determination of noble metal depletion in layered mafic intrusions:a potential acid to exploration for platinum-group element deposits[J].Chemical Geology,1995,124(1-2):47-53.
[36] Reddi G S;Ganesh S;Rao C R M et al.Determination of gold in geological materials by atomic absorption spectrometry after bromine and hydrochloric acid extraction at room temperature[J].Analytical Biochemistry,1992,260:131-134.
[37] 黄珍玉,张勤,胡克,吴健玲.等离子体质谱法直接测定地球化学样品中金铂钯[J].岩矿测试,2001(01):15-19.
[38] 张丰利;蔡传生 .地质样品中痕量金分析及展望[J].成都理工学院学报,1995,22(02):114-122.
[39] 李汝雄,王建基,邝生鲁.用4种溶液对金、银和铂进行溶解的研究[J].黄金,2002(07):41-43.
[40] 来雅文,段太成,甘树才,曹淑琴,郭锦勇,李静.C-410树脂分离富集-电感耦合等离子体质谱法测定地质样品中的金、铂、钯[J].分析化学,2002(11):1363-1366.
[41] Totland M M;Jarvis I;Jarvis K E .Microwave digestion and alkali fusion procedures for the determination of the platinum-group elements and gold in geological materials by ICP-MS[J].Chemical Geology,1995,124(1-2):21-36.
[42] 漆亮,胡静.等离子体质谱法快速测定地质样品中的痕量铂族元素和金[J].岩矿测试,1999(04):267-270.
[43] 靳新娣,朱和平.电感耦合等离子体质谱法测定地质样品中铂、钯、钌、铑、铱和金[J].分析化学,2001(06):653-656.
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