欢迎登录材料期刊网

材料期刊网

高级检索

本文从制备方法、微观结构、光催化活性研究等方面介绍了本课题组近几年从事的具有纳米结构的氧化钛、被修饰在介孔材料中的氧化钛以及沉积了贵金属的纳米结构氧化钛的研究成果,并总结了纳米氧化钛的结构特点和对应的光催化性质的规律.纳米氧化钛因颗粒尺寸下降而具有与微米氧化钛不同的特殊性质,有着广泛的应用前景,是具有光催化性质的氧化钛的研究热点.

参考文献

[1] Kasuga T;Hiramatsu M;Hirano M et al.Preparation of TiO2-based powders with high photocatalytic activities[J].Journal of Materials Research,1997,12(03):607-609.
[2] Fujishima A;Honda K .Electrochemical photocatalysis of water at a semiconductor electrode[J].Nature,1972,238(5358):37-38.
[3] Malato S;Blanco J;Richter C et al.Enhancement of rate of solar photocatalytic mineralization of organic pollutants by inorganic oxidizing species[J].Applied Catalysis B:Environmental,1998,17(04):347-356.
[4] Shul'pin G B;Bochkova M M;Nizova G V et al.Aerobic photodegradation of phenols in aqueous solutions promoted metal compounds[J].Applied Catalysis B:Environmental,1997,12(01):1-19.
[5] Zhang Q;Gao L;Guo J .Effects of calcination on the photocatalytic properties of nanosized TiO2 powders prepared by TiCl4 hydrolysis[J].Applied Catalysis B:Environmental,2000,26(03):207-215.
[6] 张青红,高濂,郭景坤.四氯化钛水解法制备二氧化钛纳米晶的影响因素[J].无机材料学报,2000(06):992-998.
[7] Lian Gao;Qinghong Zhang .EFFECTS OF AMORPHOUS CONTENTS AND PARTICLE SIZE ON THE PHOTOCATALYTIC PROPERTIES OF TiO_2 NANOPARTICLES[J].Scripta materialia,2001(8-9):1195-1198.
[8] 张青红,高濂,郑珊.金红石相二氧化钛纳米晶的光催化活性[J].化学学报,2001(11):1909-1913.
[9] Gao L;Zhang Q .The promoting effect of sulfate ions on the nucleation of TiO2(Anatase)nanocrystals[J].Materials Transactions,2001,42(08):1676-1680.
[10] Bard A J .Spin trapping and electron spin resonance detection of radical intermediates in the photodecomposition of water at TiO2 particulate system[J].Journal of Physical Chemistry,1979,83(24):3146-3150.
[11] Fox M A;Dulay M T.Heterogeneous photocatalysis[J].Chemical Reviews,1993:93.
[12] 郑珊,高濂,郭景坤.TiO2在MCM-41内表面单层及双层分散的结构表征[J].无机材料学报,2001(01):98-102.
[13] Zheng S.;Zhang QH.;Guo JK.;Gao LA. .Synthesis, characterization and photocatalytic properties of titania-modified mesoporous silicate MCM-41[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2000(3):723-727.
[14] Zheng S.;Zhang QH.;Zhang WP.;Guo JK.;Gao L. .Preparation, characterization and photocatalytic properties of singly and doubly titania-modified mesoporous silicate MCM-41 by varying titanium precursors[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2001(2):578-583.
[15] 郑珊,高濂,张青红,郭景坤.TiO2修饰的介孔分子筛MCM-41的合成、表征及光催化性研究[J].化学学报,2000(11):1403-1408.
[16] 郑珊,高濂,张青红,郭景坤.TiO2修饰MCM-41的结构表征及光催化苯酚降解活性[J].催化学报,2001(02):206-208.
[17] Zhang Q;Gao L;Zheng S.Preparation of mesoporous TiO2 photocatalyst by selective dissolving of titania-silica binary oxides[J].Chemistry Letters,2001(11):1124-1125.
[18] 高濂;郑珊;张青红.纳米氧化钛光催化材料及应用[M].北京:化学工业出版社,2002:254.
[19] Rothenberger C;Moser J;Gratzel M et al.Charge carrier trapping and recombination dynamics in small semiconductor particles[J].Journal of the American Chemical Society,1985(107):8054-8059.
[20] Zheng S;Gao L .Synthesis characterization of Pt,Au or Pd clusters deposited titania-modified mesoporous silicate MCM-41[J].Materials Chemistry and Physics,2002,78(02):512-517.
[21] Zheng S;Gao L;Zhang Q .Synthesis,characterization and photoactivity of nanosized palladium clusters deposited titania-modified mesoporous MCM-41[J].Journal of Solid State Chemistry,2001,162(01):138-141.
[22] 郑珊,高濂,郭景坤.光沉积法合成纳米金属Pd负载的MCM-TiO2及其光催化性质研究[J].高等学校化学学报,2002(06):1126-1130.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%