在碱性氰化液提金工艺中,溶剂萃取具有诱人的应用前景.反萃取是溶剂萃取的重要组成部分,但是目前金的反萃技术还没有比较满意的解决方法,这也是Au(Ⅰ)溶剂萃取未能工业化应用的一个主要原因.本文对从碱性氰化液萃金有机相的各种反萃方法进行了总结,主要方法有NaOH反萃法、降低离子强度反萃法、电沉积法、配体交换反萃法、阴离子交换反萃法等.
参考文献
| [1] | Mooiman M B;Miller J D.The solvent extraction of gold fiom aurecyanide solution[A].,1983:530. |
| [2] | Mooiman M B;Miller J D .The chemistry of gold slovent extraction from cyanide solution using modified amines[J].HYDROMETALLURGY,1986,16:245-261. |
| [3] | Mooiman M B;Miller J D .The chemistry of gold slovent extraction from cyanide solution by extratants[J].Hydrometallurgy,1991,27:29-46. |
| [4] | Chen Jing;Huang Kun.Research and development on solvent extraction of gold from alkaline cyanide solutions[A].Kunming,China,1998:3-11. |
| [5] | 张丽霞.从氰化物溶液中溶剂萃取金[J].湿法冶金,1997(04):11. |
| [6] | MA Gang;Yan Wenfei;CHEN Jing et al.Progress in gold solvent extraction[J].自然科学进展(英文版),2000,10(12):881-886. |
| [7] | Miller J D;Meoiman M B .A review of new developments in amine solvent extraction systems for hydrometallurgy[J].Separation Science and Technology,1984(19):895-909. |
| [8] | Aluacil F J;Hemandez A;Luis A .Study of the KAu(CN)2-amine amberlite LA-2 extraction equilibrium system[J].Hydrometallurgy,1990(24):157-166. |
| [9] | Caravaca C;Aluacil F J .Gold(Ⅰ) extraction equilibrium in the system KAn(CN)2-primene JMT sulphate-xylene[J].Hydrometallurgy,1992(31):257-263. |
| [10] | Caravaca C;Aluacil F J .Extraction of gold from cyanide aqueous-media by primene-JMT[J].Hydrometallurgy,1994,35:67-68. |
| [11] | Caravaca C;Aluacil F J;Sastre A et al.Exuacfion of gold ( Ⅰ )cyanide by the primary amine tridecylamine[J].Hydrometallurgy,1996(40):89-97. |
| [12] | Caravaca C;Aluaeil F J .The use of primary amines in Gold(Ⅰ) extraction from cyanide solutions[J].Hydrometallurgy,1996(36):369-384. |
| [13] | Caravaea C .Gold ( Ⅰ )extraction equilibrium in cyanide media by the synergie mixture Primene81R-Cyanex923[J].Hydrometallurgy,1994(35):27-40. |
| [14] | 马恒励,金品利.二烷基亚砜-胺二元系从氰化物溶液中萃取金[J].贵金属,1992(04):8-14. |
| [15] | 余建民,李奇伟,陈景.多烷基支链仲胺从碱性氰化液中萃取金[J].应用化学,2001(04):276-280. |
| [16] | Kordosky G A;Sieraoski J M .Gold extraction from typical cyanide leach solutions[J].Hydrometallurgy,1992,30:291-305. |
| [17] | Yu Jianmin;Li Qiwei;CHEN Jing .Solvent extraction of aurocyanide from alkaline cyanide solution by Lix7825[J].Chemical Journal on Internet,2001,3:21. |
| [18] | Aluacil F J;Caravaca C et al.The extraction of gold(I) from cyanide solutions by the phosphine oxide cyanex 921[J].Hydrometallurgy,1993(35):41-52. |
| [19] | Aluacil F J;Caravaca C .The phosphine oxides Cyanex923 and Cyanex925 as extractants for gold ( Ⅰ )cyanide aqueous so lutions[J].Hydrometallurgy,1994(36):369-384. |
| [20] | Wan R Y;Miller J D.Research and development activities for the recovery of gold from alkaline cyanide solutions[J].Mineral Processing and Extractive Metallurgy Review,1990(06):143-190. |
| [21] | Wan R Y;Miller J D .Solvation extraction and electrodeposition of gold from cyanide solutions[J].Journal of Metals,1986,38(12):35-40. |
| [22] | Miller J D;Wan R Y .Direct gold electrolysis from a leaded organic phase[P].US:4657642 |
| [23] | Groenewald T.A modified dilution for the solvent extavaction of gold ( Ⅰ )cyanide from alkaline solution[M].London,1974:2715-2732. |
| [24] | Chen Jing;Zhu Liya;Jing Yaqiu.Solvent extraction of gold cyanide with tri - butyl - phosphate and additive added in aqueous phase[A].Ontario,Canada,1998:65-74. |
| [25] | 潘学军,陈景.碱性氰化液中加表面活性剂用TBP萃取金的研究[J].稀有金属,2000(02):90-95. |
| [26] | 黄昆,陈景,吴瑾光,高宏成,崔宁,余建民.CTMAB萃取Au（CN）-2体系中几种改性剂的对比[J].中国有色金属学报,2001(02):307-311. |
| [27] | MA Gang,YAN Wenfei,CHEN Jing,YAN Chunhua,GAO Hongcheng,ZHOU Weijin,SHI Nai,WU Jinguang,XU Guangxian,HUANG Kun,YU Jianmin,CUI Ning.Mechanism of gold solvent extraction from aurocyanide solution by quaternary amines: models of extracting species based on hydrogen bonding[J].中国科学B辑（英文版）,2000(02):169-177. |
| [28] | MA Gang;Yan Wenfei;Hu Tiandou.FTIR and EXAFS investigation of microstructures of gold solvent extraction:hydrogen bonding betweenmodifierandAu(CN)-2[J].Physical Chemical Physics,1999(01):5215-5221. |
| [29] | 闫文飞,马刚,周维金,高宏成,施鼐,吴瑾光,徐光宪,陈景.氰化金浸取液萃取机理研究[J].无机化学学报,2000(02):261-266. |
| [30] | FlemingCA;CrombergeC .The elution of aurocyanide from strong and weak - base resins[J].Journal of the South African Institute of Mining and Metallurgy,84(09):1884,269-280. |
| [31] | 周展云,傅建顺,吴志泉.从季铵盐负载有机相中反萃金银铜[J].贵金属,1991(02):11-18. |
| [32] | Riveros F J .Studies on the solvent extraction of gold from cyanide media, hydrometallurgy[J].,1990,24:135-156. |
| [33] | 朱声逾,戴桂贞.硫脲反萃金的研究[J].贵金属,1989(04):51-53. |
| [34] | 张天喜,黄保贵,陈景,周维金,高宏成,吴瑾光.季铵盐体系金的萃取与反萃[J].过程工程学报,2001(04):351-355. |
| [35] | MA Gang;Yan Weifei;CHEN Jing et al.Stripping of gold from quaternary amine extraction system[J].Solvent Extraction and Ion Exchange,2000,18(06):1179-1187. |
| [36] | 黄昆;陈景 .表面活性剂从碱性氰化液中萃取金理论及应用研究[D].昆明贵金属研究所,1998. |
| [37] | Demopoulos G P .溶剂萃取中的加压氢反萃取[J].Journal of Metals,1985,37(07):46-52. |
| [38] | Zhang Tianxi;Li Wenjun;Wu Jingguang et al.Extraction and separation of gold( Ⅰ )cyanide in polyethylene glycol based aqueous biphasie systems[J].Hydrometallurgy,2001(62):41-46. |
| [39] | 张天喜,李文钧,周维金,高宏成,陈景,吴瑾光.基于双水相体系的KAu（CN）2分配行为[J].北京大学学报(自然科学版),2001(02):197-199. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%