用二茂铁甲酰腙与稀土金属(Ⅲ)氯化物反应,合成了一系列配合物,进行了元素分析、IR、1HNMR、质谱、电化学性质分析、摩尔电导率及荧光光谱表征,确定了配合物的组成[Ln(HL)3Cl3*nH2O]和可能的配位方式.分析表明配合物中配体以酮式与稀土金属离子配位;电导率测定结果说明配合物为非电解质;电化学性质分析表明配合物中三个单取代的二茂铁基所处的化学环境相同;荧光光谱测定结果表明配合物中没有稀土金属离子f-f轨道间跃迁的特征光谱.
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