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采用10%氢氧化钠、20%硫酸、甲苯分别对Ca(OH)2和Al(OH)3为填料的不饱和树脂聚合物浸泡,浸泡期分别为15、30、60天,测定其抗弯强度并进行力学性能分析.结果表明,随着腐蚀液浸泡时间的延长,其抗弯强度和抗压强度迅速下降.由显微镜对人造石浸泡后的观察表明.腐蚀主要是针对不饱和树脂聚合物发生,使聚合物与填料之间的粘接力降低.甲苯对不饱和树脂聚合物的腐蚀作用较大,氢氧化钠的腐蚀作用次之,而硫酸的腐蚀作用相对较小.

Unsaturated polyester resin artificial marble with the fillers of Ca(OH)2 and AI(OH)3 were soaked by 10% NaOH, 20% H2SO4 and toluene by 15, 30, 60 days. The flexural strength was mensurated and the mechanical properties was analyzed. The results showed that flexural strength was reduced rapidly with prolonging of the soaking time in corrosion solutions. The artificial marble soaked into corrosion solutions was observed by microscope. The observations showed that corrosion was dead against the polymer of unsaturated polyester resin, and the cohesive force between the polymer and fillers was reduced. The results of corrosive tests showed that toluene as organic solvent had a corrosion strong effect on polymer of unsaturated polyester resin, sodium hydroxide was relative strong, and sulfuric acid was relative weak.

参考文献

[1] 邢帮元,陈文利.聚酯型透明人造大理石[J].化工时刊,2004(04):39-40.
[2] 王建都;陈学年;宋连卿 等.无机人造大理石的原料、工艺及性能[J].建筑技术,1994,23(09):531-532.
[3] 孙国忠,唐万侠,周永强,刘海涛,李青山.废玻璃、粉煤灰人造大理石的研制[J].化工时刊,2003(10):45-46.
[4] GB2567-1995,树脂浇铸体力学性能试验方法总则[S].
[5] GB/T 2570.GB/T 2570.树脂浇铸体弯曲试验方法[S].北京,国家质检总局,1995.
[6] GB3857.GB3857,玻璃纤维增强热固性塑料耐化学药品性能试验方法[S].北京,国家质检总局,2005.
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