以甲苯二异氰酸酯(TDI-80)、聚醚二元醇(N220)、环氧树脂(E20)和甲基丙烯酸甲酯(MMA)等为原料,通过原位聚合,制备了水性聚氨酯-环氧树脂-丙烯酸(WPUEA)复合分散液.研究了体系NCO/OH总摩尔比和TMP、E20、DMPA及MMA用量对WPUEA分散液及其胶膜性能的影响.结果表明,当NCO/OH总摩尔比为1.2~1.5,TMP用量为2%~3%,E20用量为4%~6%,DMPA用量为6%~9%,MMA用量为20%~30%时,分散液储存期超过10个月,冻融循环大于5,其涂膜硬度大于0.70,拉伸强度大于10 MPa,耐水性、耐酸碱性、耐溶剂性等较水性聚氨酯(WPU)有明显改善.
参考文献
[1] | Sundar Saimani,Kannan Tharanikkarasu,Ganga Radhakrishnan.Aqueous dispersion of polyurethane polyacrylic acid multiblock copolymers through living radical[J].Journal of applied Polymer Science,2003,87:1109. |
[2] | Urska Ebenik,Matjaz Krajnc.Properties of acrylic-polyurethane hybrid emulsions synthesized by the semibatch emulsion copolymerization of acrylates using different polyurethane particles[J].Journal of Polymer Science:Part A:Polymer Chemistry,2005,43:4050. |
[3] | Jian-Zei Lai,Pao-Jan Chen,Jen-Taut Yeh,et al.A cross shelfcuring system for an aqueous-based PU hybrid[J].Journal of applied Polymer Science,2005,97:550. |
[4] | Chaaroen Chinwanitcharoen,Shigeyoshi Kanoh,Toshiro Yamada et al.Preparation and shelf-life stability of aqueous polyurethane dispersion.[J].Marcromol Symp,2004,216 (1):229. |
[5] | 瞿金清,李佩妍,陈焕钦.甲基丙烯酸甲酯与水性聚氨酯的共聚反应[J]华南理工大学学报(自然科学版),2004,32(8):54. |
[6] | Subiao Zhang,Hongtao Lv,Han Zhang,et al.Waterborne Polyurethanes:Spectroscopy and Stability of Emulsions[J].Journal of Applied Polymer Science,2006,101:597. |
[7] | 夏骏嵘,刘娇,潘肇琦,等.聚氨酯-丙烯酸酯杂化乳液结构与性能的影响[J].功能高分子学报,2005,18(3):399. |
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