石墨烯作为一种新型的二维纳米材料，具有优异的透光率和导电性。与传统的铟锡氧化物(ITO)相比，石墨烯具有更高的导电性、较好的柔韧性和丰富的资源，因此石墨烯在透明导电薄膜领域有着较好的应用前景。主要对国内外近3年来化学法制备石墨烯基透明导电薄膜的最新研究成果进行综述。并以成膜方法的不同为区分，重点介绍了真空抽滤法、旋涂法、自组装、Langmuir-Blodgett (LB)法、喷涂法制备石墨烯基透明导电薄膜的最新研究成果。同时，对薄膜的硝酸处理、掺杂进行了介绍。最后，就目前化学法制备石墨烯基透明导电薄膜所面临的问题进行了讨论，并对石墨烯透明导电薄膜的未来发展进行了展望。
Graphene as a new two-dimensional material,including excellent light transmittance and conductivity. Compared with the conventional indium tin oxide (ITO),graphene,transparent conductive film has a good ap-plication prospect,because of its higher electrical conductivity,good flexibility and rich resources.This paper focused on the research progress of graphene-based transparent conductive film using chemical method last three years.Depending on the different of the preparation method of film,the latest research progress of vacuum fil-tration method,spin-coating method,self-assembly,Langmuir-Blodgett (LB)and spraying prepared graphene-based transparent conductive films were introduced.Meanwhile,the transparent graphene thin films by acid, doping treatment were introduced as well.Finally,the unsolved problem of graphene-based transparent conduc-tive films was discussed and the future development of graphene-based transparent conductive films was pros-pected.
参考文献
| [1] | Lee Y B;Ahn J H .Graphene-based transparent conduc-tive films[J].Nano,2013,8(05):1330001. |
| [2] | Bolotin, KI;Sikes, KJ;Jiang, Z;Klima, M;Fudenberg, G;Hone, J;Kim, P;Stormer, HL .Ultrahigh electron mobility in suspended graphene[J].Solid State Communications,2008(9/10):351-355. |
| [3] | Novoselov KS;Jiang Z;Zhang Y;Morozov SV;Stormer HL;Zeitler U;Maan JC;Boebinger GS;Kim P;Geim AK .Room-temperature quantum Hall effect in graphene.[J].Science,2007(5817):1379-0. |
| [4] | Geim AK;Novoselov KS .The rise of graphene[J].Nature materials,2007(3):183-191. |
| [5] | Mao S;Pu H H;Chen J H .Graphene oxide and its re-duction:modeling and experimental progress[J].RSC Advances,2012,2:2643-2662. |
| [6] | Michael J.McAllister;Je-Luen Li;Douglas H.Adamson .Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(18):4396-4404. |
| [7] | Balandin AA;Ghosh S;Bao WZ;Calizo I;Teweldebrhan D;Miao F;Lau CN .Superior thermal conductivity of single-layer graphene[J].Nano letters,2008(3):902-907. |
| [8] | Han S T;Zhou Y;Wang C D et al.Flexible electronics:layer-by-layer assembled reduced graphene oxide/gold nanoparticle hybrid double-floating-gate structure for low-voltage flexible flash memory[J].Advanced Materials,2013,25(06):793. |
| [9] | Jiale Du;Yu Zhang;Shaozhi Deng.Correlation between topographic structures and local field emission characteristics of graphene-sheet films[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:507-514. |
| [10] | Geetika Khurana;Sujit K. Barik;Satyaprakash Sahoo .In Situ Raman Studies of Electrically Reduced Graphene Oxide and Its Field-Emission Properties[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2013(10):5485-5491. |
| [11] | Gregory Lui;Jin-Yun Liao;Aoshu Duan .Graphene-wrapped hierarchical TiO2 nanoflower composites with enhanced photocatalytic performance[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,2013(39):12255-12262. |
| [12] | S. Y. CAO;C. S. CHEN;X. T. NING.Preparation and Photocatalytic Property of Graphene/TiO_2 Composite Powder[J].Integrated Ferroelectrics,2013:40-45. |
| [13] | Cai, C.-J.;Xu, M.-W.;Bao, S.-J.;Ji, C.-C.;Lu, Z.-J.;Jia, D.-Z. .A green and facile route for constructing flower-shaped TiO_2 nanocrystals assembled on graphene oxide sheets for enhanced photocatalytic activity[J].Nanotechnology,2013(27):275602-1-275602-8. |
| [14] | Lingam Hima Kumar;Chitturi Venkateswara Rao;Balasubramanian Viswanathan .Catalytic effects of nitrogen-doped graphene and carbon nanotube additives on hydrogen storage properties of sodium alanate[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,2013(10):3355-3361. |
| [15] | Valentina Tozzini;Vittorio Pellegrini .Prospects for hydrogen storage in graphene[J].Physical chemistry chemical physics: PCCP,2013(1):80-89. |
| [16] | Kim, T.;Jung, G.;Yoo, S.;Suh, K.S.;Ruoff, R.S. .Activated graphene-based carbons as supercapacitor electrodes with macro- and mesopores[J].ACS nano,2013(8):6899-6905. |
| [17] | Yang Zhao;Jia Liu;Yue Hu;Huhu Cheng;Chuangang Hu;Changcheng Jiang;Lan Jiang;Anyuan Cao;Liangti Qu .Highly Compression-Tolerant Supercapacitor Based on Polypyrrole-mediated Graphene Foam Electrodes[J].Advanced Materials,2013(4):591-595. |
| [18] | Leng K;Zhang F;Zhang L et al.Graphene-based Li-ion hybrid supercapacitors with ultrahigh performance[J].Nano Research,2013,6(08):581-592. |
| [19] | Wu, Z.;Chen, X.;Zhu, S.;Zhou, Z.;Yao, Y.;Quan, W.;Liu, B..Enhanced sensitivity of ammonia sensor using graphene/polyaniline nanocomposite[J].Sensors and Actuators, B. Chemical,2013:485-493. |
| [20] | Akbari, E.;Ahmadi, M.T.;Kiani, M.J.;Karimi Feizabadi, H.;Rahmani, M.;Khalid, M. .Monolayer graphene based CO_2 gas sensor analytical model[J].Journal of computational and theoretical nanoscience,2013(6):1301-1304. |
| [21] | Bae, S.;Kim, H.;Lee, Y.;Xu, X.;Park, J.-S.;Zheng, Y.;Balakrishnan, J.;Lei, T.;Ri Kim, H.;Song, Y.I.;Kim, Y.-J.;Kim, K.S.;?zyilmaz, B.;Ahn, J.-H.;Hong, B.H.;Iijima, S. .Roll-to-roll production of 30-inch graphene films for transparent electrodes[J].Nature nanotechnology,2010(8):574-578. |
| [22] | Han, T.-H.;Lee, Y.;Choi, M.-R.;Woo, S.-H.;Bae, S.-H.;Hong, B.H.;Ahn, J.-H.;Lee, T.-W. .Extremely efficient flexible organic light-emitting diodes with modified graphene anode[J].Nature photonics,2012(2):105-110. |
| [23] | Shi S W;Sadhu V;Moubah R et al.Solution-proces-sable graphene oxide as an efficient hole inj ection layer for high luminance organic light-emitting diodes[J].J Mater Chem C,2013,1:1708-1712. |
| [24] | Zhang Q;Wan X J;Xing F et al.Solution-processable graphene mesh transparent electrodes for organic solar cells[J].Nano Research,2013,6(07):478-484. |
| [25] | Huang, J.-H.;Fang, J.-H.;Liu, C.-C.;Chu, C.-W. .Effective work function modulation of graphene/carbon nanotube composite films as transparent cathodes for organic optoelectronics[J].ACS nano,2011(8):6262-6271. |
| [26] | Sunho Jeong;Min-Wook Jung;Ji-Yoon Lee .Graphene electrodes transfer-printed with a surface energy-mediated wet PDMS stamp: impact of Au doped-graphene for high performance soluble oxide thin-film transistors[J].Journal of Materials Chemistry, C. materials for optical and electronic devices,2013(36):5632-5637. |
| [27] | Yong Un Jung;Se-in Oh;Sung-Hoon Choa;Han-Ki Kim;Seong Jun Kang .Electromechanical properties of graphene transparent conducting films for flexible electronics[J].Current applied physics: the official journal of the Korean Physical Society,2013(7):1331-1334. |
| [28] | Memon N K;Tse S D;Al-Sharab J F et al.Transpar-ent,flexible conducting graphene hybrid films with a subpercolating network of silver nanowires[J].CARBON,2011,49:5064-5070. |
| [29] | Yang Liu;Quanhong Chang;Lei Huang .Transparent, flexible conducting graphene hybrid films with a subpercolating network of silver nanowires[J].Journal of Materials Chemistry, C. materials for optical and electronic devices,2013(17):2970-2974. |
| [30] | Lee, W.H.;Suk, J.W.;Lee, J.;Hao, Y.;Park, J.;Yang, J.W.;Ha, H.-W.;Murali, S.;Chou, H.;Akinwande, D.;Kim, K.S.;Ruoff, R.S. .Simultaneous transfer and doping of CVD-grown graphene by fluoropolymer for transparent conductive films on plastic[J].ACS nano,2012(2):1284-1290. |
| [31] | Toshiyuki Kobayashi;Masashi Bando;Nozomi Kimura;Keisuke Shimizu;Koji Kadono;Nobuhiko Umezu;Kazuhiko Miyahara;Shinji Hayazaki;Sae Nagai;Yukiko Mizuguchi;Yosuke Murakami;Daisuke Hobara .Production of a 100-m-long high-quality graphene transparent conductive film by roll-to-roll chemical vapor deposition and transfer process[J].Applied physics letters,2013(2):023112-1-023112-4. |
| [32] | Rodrigo V. Salvatierra;Sergio H. Domingues;Marcela M. Oliveira.Tri-layer graphene films produced by mechanochemical exfoliation of graphite[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:410-415. |
| [33] | Kang M S;Kim K T;Leeb J U et al.Direct exfoliation of graphite using a non-ionic polymer surfactant for fab-rication of transparent and conductive graphene films[J].J Mater Chem C,2013,1:1870-1875. |
| [34] | Secor E B;Prabhumirashi P L;Puntambekar K et al.Inkj et printing of high conductivity,flexible graphene pat-terns secor[J].J Phys Chem Lett,2013,4:1347-1351. |
| [35] | Nair R R;Black P;Grigorenko A N et al.Graphene thickness determination using reflection and contract spectroscopy[J].SCIENCE,2008,320(5881):1308-1308. |
| [36] | Keun Soo Kim;Yue Zhao;Houk Jang;Sang Yoon Lee;Jong Min Kim;Kwang S. Kim;Jong-Hyun Ann;Philip Kim;Jae-Young Choi;Byung Hee Hong .Large-scale Pattern Growth Of Graphene Films For Stretchable Transparent Electrodes[J].Nature,2009(7230):706-710. |
| [37] | Eda G;Fanchini G;Chhowalla M .Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material[J].Nature nanotechnology,2008(5):270-274. |
| [38] | Lifang Shi;Junhe Yang;Zhendong Huang;Jing Li;Zhihong Tang;Ying Li;Qingbin Zheng .Fabrication of transparent, flexible conducing graphene thin films via soft transfer printing method[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2013(Jul.1):437-446. |
| [39] | Hsi-Wen Tien;Yuan-Li Huang;Shin-Yi Yang .The production of graphene nanosheets decorated with silver nanoparticles for use in transparent, conductive films[J].Carbon: An International Journal Sponsored by the American Carbon Society,2011(5):1550-1560. |
| [40] | Luowen Peng;Yiyu Feng;Peng Lv .Transparent, Conductive, and Flexible Multiwalled Carbon Nanotube/Graphene Hybrid Electrodes with Two Three-Dimensional Microstructures[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2012(8):4970-4978. |
| [41] | Shu Jun Wang;Yan Geng;Qingbin Zheng .Fabrication of highly conducting and transparent graphene films[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(6):1815-1823. |
| [42] | Jeong, S.Y.;Kim, S.H.;Han, J.T.;Jeong, H.J.;Yang, S.;Lee, G.-W. .High-performance transparent conductive films using rheologically derived reduced graphene oxide[J].ACS nano,2011(2):870-878. |
| [43] | Song Hun Kim;Yuan Yu;Yu Zhen Li .A hybrid reduction procedure for preparing flexible transparent graphene films with improved electrical properties[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2012(35):18306-18313. |
| [44] | 唐晶晶,第凤,徐潇,肖迎红,车剑飞.石墨烯透明导电薄膜[J].化学进展,2012(04):501-511. |
| [45] | He, Q.;Wu, S.;Gao, S.;Cao, X.;Yin, Z.;Li, H.;Chen, P.;Zhang, H. .Transparent, flexible, all-reduced graphene oxide thin film transistors[J].ACS nano,2011(6):5038-5044. |
| [46] | Yamaguchi, H.;Eda, G.;Mattevi, C.;Kim, H.;Chhowalla, M. .Highly uniform 300 mm wafer-scale deposition of single and multilayered chemically derived graphene thin films[J].ACS nano,2010(1):524-528. |
| [47] | Yamaguchi, H.;Eda, G.;Mattevi, C.;Kim, H.;Chhowalla, M. .Highly uniform 300 mm wafer-scale deposition of single and multilayered chemically derived graphene thin films[J].ACS nano,2010(1):524-528. |
| [48] | Shin, K.-H.;Jang, Y.;Kim, B.-S.;Jang, J.;Kim, S.H. .Highly conductive reduced graphene oxide produced via pressure-assisted reduction at mild temperature for flexible and transparent electrodes[J].Chemical communications,2013(43):4887-4889. |
| [49] | Becerril, H.A.;Mao, J.;Liu, Z.;Stoltenberg, R.M.;Bao, Z.;Chen, Y. .Evaluation of solution-processed reduced graphene oxide films as transparent conductors[J].ACS nano,2008(3):463-470. |
| [50] | Karthick, R.;Brindha, M.;Selvaraj, M.;Ramu, S..Stable colloidal dispersion of functionalized reduced graphene oxide in aqueous medium for transparent conductive film[J].Journal of Colloid and Interface Science,2013:69-74. |
| [51] | Bo-Tau Liu;Han-Lin Kuo.Graphene/silver nanowire sandwich structures for transparent conductive films[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:390-396. |
| [52] | Kholmanov, I.N.;Stoller, M.D.;Edgeworth, J.;Lee, W.H.;Li, H.;Lee, J.;Barnhart, C.;Potts, J.R.;Piner, R.;Akinwande, D.;Barrick, J.E.;Ruoff, R.S. .Nanostructured hybrid transparent conductive films with antibacterial properties[J].ACS nano,2012(6):5157-5163. |
| [53] | Zhu Y W;Cai W W;Richard D et al.Transparent self-assembled films of reduced graphene oxide platelets[J].Applied Physics Letters,2009,95:103-104. |
| [54] | Zhao, J.;Pei, S.;Ren, W.;Gao, L.;Cheng, H.-M. .Efficient preparation of large-area graphene oxide sheets for transparent conductive films[J].ACS nano,2010(9):5245-5252. |
| [55] | Hong, T.-K.;Lee, D.W.;Choi, H.J.;Shin, H.S.;Kim, B.-S. .Transparent, flexible conducting hybrid multilayer thin films of multiwalled carbon nanotubes with graphene nanosheets[J].ACS nano,2010(7):3861-3868. |
| [56] | Kezheng Gao;Ziqiang Shao;Xue Wu .Cellulose nanofibers/reduced graphene oxide flexible transparent conductive paper[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2013(1):243-251. |
| [57] | Yuan-Li Huang;Avinash Baji;Hsi-Wen Tien .Self-assembly of silver-graphene hybrid on electrospun polyurethane nanofibers as flexible transparent conductive thin films[J].Carbon: An International Journal Sponsored by the American Carbon Society,2012(10):3473-3481. |
| [58] | Zhou Y Z;Yang J;Cheng X N et al.Transparent and conductive reduced graphene oxide/silver nanoparticles multilayer film obtained by electrical self-assembly process with graphene oxide sheets and silver colloid[J].RSC Advances,2013,3:3391-3398. |
| [59] | 周亚洲,杨娟,孙磊,赵南,程晓农.石墨烯/银复合薄膜的制备及表征[J].无机化学学报,2012(01):137-142. |
| [60] | Hsi-Wen Tien;Sheng-Tsung Hsiao;Wei-Hao Liao.Using self-assembly to prepare a graphene-silver nanowire hybrid film that is transparent and electrically conductive[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:198-207. |
| [61] | Dong Wook Lee;Tae-Keun Hong;Dongwoo Kang .Highly controllable transparent and conducting thin films using layer-by-layer assembly of oppositely charged reduced graphene oxides[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2011(10):3438-3442. |
| [62] | Jiayi Zhu;Junhui He .Assembly and benign step-by-step post-treatment of oppositely charged reduced graphene oxides for transparent conductive thin films with multiple applications[J].Nanoscale,2012(11):3558-3566. |
| [63] | 郑庆彬,师丽芳,杨俊和.Langmuir-Blodgett自组装法制备超大尺寸氧化石墨烯透明导电薄膜[J].中国有色金属学报（英文版）,2012(10):2504-2511. |
| [64] | Zheng, Q.;Ip, W.H.;Lin, X.;Yousefi, N.;Yeung, K.K.;Li, Z.;Kim, J.-K. .Transparent conductive films consisting of ultralarge graphene sheets produced by Langmuir-Blodgett assembly[J].ACS nano,2011(7):6039-6051. |
| [65] | Qingbin Zheng;Biao Zhang;Xiuyi Lin .Highly transparent and conducting ultralarge graphene oxide/single-walled carbon nanotube hybrid films produced by Langmuir-Blodgett assembly[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2012(48):25072-25082. |
| [66] | Viet Hung Pham;Tran Viet Cuong;Seung Hyun Hur .Fast and simple fabrication of a large transparent chemically-converted graphene film by spray-coating[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(7):1945-1951. |
| [67] | Kholmanov, I.N.;Domingues, S.H.;Chou, H.;Wang, X.;Tan, C.;Kim, J.-Y.;Li, H.;Piner, R.;Zarbin, A.J.G.;Ruoff, R.S. .Reduced graphene oxide/copper nanowire hybrid films as high-performance transparent electrodes[J].ACS nano,2013(2):1811-1816. |
| [68] | De, S.;Coleman, J.N. .Are there fundamental limitations on the sheet resistance and transmittance of thin graphene films?[J].ACS nano,2010(5):2713-2720. |
| [69] | Lee J K;Slain D W;Makotchenko V Q;et a1 .One-step exfoliation synthesis of easily soluble graphite and trans-parent conducting Graphene sheets[J].Advanced Materials,2009,21:1-5. |
| [70] | Qing Bin Zheng;Mohsen Moazzami Gudarzi;Shu Jun Wang .Improved electrical and optical characteristics of transparent graphene thin films produced by acid and doping treatments[J].Carbon: An International Journal Sponsored by the American Carbon Society,2011(9):2905-2916. |
| [71] | A. Dideykin;A.E. Aleksenskiy;D. Kirilenko .Monolayer graphene from graphite oxide[J].Diamond and Related Materials,2011(2):105-108. |
| [72] | Zhou, XF;Liu, ZP .A scalable, solution-phase processing route to graphene oxide and graphene ultralarge sheets[J].Chemical communications,2010(15):2611-2613. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%