重金属离子广泛存在于冶金、电镀、制革等行业排放的废水,研究者们致力于重金属离子高效吸附材料的研制已有多年,基于国内外最新研究文献,系统论述了生物质吸附材料,基于生物质吸附材料的改性产品及新型高分子的吸附性能,比较了各种吸附剂的优缺点。指出将制革产生的废弃革屑处理后得到的胶原纤维经过化学改性提高其吸附性能,原材料来源广泛。将其应用于含重金属离子废水的处理中,可以达到以废治污的目的。
The heavy metal ion mainly existing in the waste water of metallurgy,electroplating and leather mak-ing industry.The researchers are focusing on high effective adsorption material.This paper based on the latest research paper,mainly discussed on the adsorption properties of biomass adsorption material,the modified product based on the biomass material and some novel macro molecular.The advantages and disadvantages of the adsorbent were compared.Collagen fibers have advantage of wide resource and it can be extracted from the abandoned waste leather shaving.After the chemical modification,the adsorption capacity of collagen fiber could be enhanced greatly.It will be of great use when used in the treatment of heavy metal ion contained waste water.
参考文献
[1] | Hsu L C;Wang S L;Lin Y C et al.Cr(Ⅵ)removal on fungal biomass of neurospora crassa:the importance of dissolved organic carbons derived from the biomass to Cr(Ⅵ)reduction[J].Environmental Science &Technology,2010,44:6202-6208. |
[2] | Akar T;Tunali S .Biosorption characteristics of Aspergillus flavus biomass for removal of Pb(II) and Cu(II) ions from an aqueous solution[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2006(15):1780-1787. |
[3] | Wu Xiuwen;Ma Hongwen;Zhang Yanrong .Adsorption of chromium(Ⅵ)from aqueous solution by a meso-porousaluminosilicate synthesized from microcline[J].Applied Clay Science,2010,48:538-541. |
[4] | Parinda Suksabye;Akira Nakajima;Paitip Thiravetyan;Yoshinari Baba;Woranan Nakbanpote .Mechanism Of Cr(Ⅵ) Adsorption By Coir Pith Studied By Esr And Adsorption Kinetic[J].Journal of hazardous materials,2009(2/3):1103-1108. |
[5] | H. Soner Altundogan .Cr(Ⅵ) removal from aqueous solution by iron (Ⅲ) hydroxide-loaded sugar beet pulp[J].Process biochemistry,2005(3/4):1443-1452. |
[6] | Yu Honghao;Li Xin;Xue Xiangxin .Preparation of me-soporous molecular sieve MCM-41 andits adsorption be-havior for chromium ion in water[J].Journal of Functional Materials,2013,44(09):1252-1256. |
[7] | 张继义,梁丽萍,蒲丽君,王利平.小麦秸秆对Cr(Ⅵ)的吸附特性及动力学、热力学分析[J].环境科学研究,2010(12):1546-1552. |
[8] | Wu Xiuwen;Ma Hongwen;Zhang Yanrong .Adsorption of chromium(Ⅵ)from aqueous solution by a mesoporousa-luminosilicate synthesized from microcline[J].Applied Clay Science,2010,48:538-541. |
[9] | N. Rajesh;Rohit Kumar Jalan;Pinky Hotwany .Solid phase extraction of chromium(Ⅵ) from aqueous solutions by adsorption of its diphenylcarbazide complex on an Amberlite XAD-4 resin column[J].Journal of hazardous materials,2008(3):723-727. |
[10] | Rao M;Parwate A V;Bhole A G .Removal of Cr6+ and Ni2+ from aqueous solution using bagasse and fly ash[J].Waste Manage,2002,22(07):821-830. |
[11] | Ibrahim Narin;Ayse Kars;Mustafa Soylak .A novel solid phase extraction procedure on Amberlite XAD-1180 for speciation of Cr(Ⅲ), Cr(Ⅵ) and total chromium in environmental and pharmaceutical samples[J].Journal of hazardous materials,2008(2):453-458. |
[12] | 李昱琢,李辉,逯翠梅,李贵,李志平,符再德.尼古丁印迹材料的制备表征及对烟气中尼古丁的吸附研究[J].功能材料,2013(09):1289-1293. |
[13] | 李新宝,谷巍,曹永.石墨烯复合材料对水中金属离子的吸附研究进展[J].功能材料,2013(z1):5-10,14. |
[14] | 赵永纲,沈昊宇,李勍,夏清华.氨基功能化纳米Fe3O4磁性高分子吸附剂对废水中Cr(Ⅵ)的吸附研究[J].化学学报,2009(13):1509-1514. |
[15] | N. Rajesh;Rohit Kumar Jalan;Pinky Hotwany .Solid phase extraction of chromium(Ⅵ) from aqueous solutions by adsorption of its diphenylcarbazide complex on an Amberlite XAD-4 resin column[J].Journal of hazardous materials,2008(3):723-727. |
[16] | Zang Yunbo .Adsorption of Cr(Ⅵ)and Cu(Ⅱ)on hydrotalcite-like compounds and bentonite[D].Ji’nan:Shandong University,2007. |
[17] | Deng Liping .Bioaccumulation and biosorption of nitro-gen,phosphorus and heavy metal ions Cu2+, Pb2+, Cd2+ and Cr6+[D].Beij ing:Graduate University of Chi-nese Academy of Sciences,2008. |
[18] | 陈学青,曹吉林,杜秀娟,常贵环.聚(丙烯酰胺-丙烯酸钠)复合膨润土制备及其对Pb2+的吸附[J].功能材料,2013(09):1309-1314. |
[19] | Wang Mingming;Qian Chunxiang .Study on heay metal ion Zn2+ mineralized by phosphate ore implication of bacteria[J].Journal of Functional Materials,2013,44(03):393-395. |
[20] | 段丽红,杨晋青,郭祀远.磁场对壳聚糖希夫碱吸附重金属铅离子的影响[J].功能材料,2012(02):235-239. |
[21] | 张军丽,李瑞玲,张燕,潘庆才.改性壳聚糖吸附剂的合成及对镉离子的吸附性能[J].环境科学与技术,2011(07):87-89,170. |
[22] | 王湖坤,贺倩,韩木先.粉煤灰/壳聚糖复合材料制备及处理含重金属工业废水的研究[J].离子交换与吸附,2010(04):362-369. |
[23] | Chanthateyanonth, R;Ruchirawat, S;Srisitthiratkul, C .Preparation of New Water-Soluble Chitosan Containing Hyperbranched-Vinylsulfonic Acid Sodium Salt and Their Antimicrobial Activities and Chelation with Metals[J].Journal of Applied Polymer Science,2010(4):2074-2082. |
[24] | 王雪源.改性壳聚糖重金属生物质吸附剂的制备及表征[J].环境科学与技术,2010(12):109-114,127. |
[25] | 程海明,王睿,王英梅,陈敏,廖隆理,李舟,段悟吾,李志强.猪皮酸松弛胶原纤维的制备及性能表征[J].四川大学学报(工程科学版),2007(03):78-82. |
[26] | Liao Xuepin .Preparation of adsorbents based on collagen fibers and investigation of their adsorption characteristics[D].Chengdu:Sichuan University,2004. |
[27] | 廖洋,何春光,赵仕林,廖学品.改性皮革胶原纤维对水体中Cd2+、Cr3+、Pb2+、Ni2+、Co2+等痕量重金属离子的富集与测定[J].分析试验室,2006(07):10-13. |
[28] | 孙霞,廖学品,石碧.胶原-单宁树脂对水体中Hg(Ⅱ)的吸附特性研究[J].高校化学工程学报,2010(04):562-568. |
[29] | 刘方,何春光,廖学品,赵仕林.胶原纤维固化黑荆树单宁对La3+的吸附特性研究[J].稀土,2008(02):35-38,75. |
[30] | 王碧,张凤金,覃松,廖学品.胶原纤维固化黑荆树单宁对钪吸附的研究[J].林产化学与工业,2008(01):33-38. |
[31] | 何春光,廖洋,廖学品,赵仕林.胶原纤维固化杨梅单宁对Pr3+,Nd3+的吸附特性[J].稀有金属材料与工程,2006(12):1928-1931. |
[32] | 王茹,廖学品,侯旭,石碧.胶原纤维固化杨梅单宁对Pb2+、Cd2+、Hg2+的吸附[J].林产化学与工业,2005(01):10-14. |
[33] | 廖学品,邓慧,陆忠兵,石碧.胶原纤维固化杨梅单宁对UO22+的吸附[J].离子交换与吸附,2003(05):407-415. |
[34] | Liu Guodong;Lin Yingying;Wu Hong et al.Voltam-metricdetection of Cr(Ⅵ)with disposable screen-printed electrode modified with gold nanoparticles[J].Environ-mental Science & Technology,2007,41:8129-8134. |
[35] | 王茹,廖学品,曾滔,彭娜,石碧.胶原纤维固化杨梅单宁对Mo(Ⅵ)的吸附[J].林产化学与工业,2008(02):21-26. |
[36] | Sun Xia;Liao Xuepin;Shi Bi .Adsorption of Pb(Ⅱ)from aqueous solution using collagen-tannin resin[J].Chemistry and Industry of Forest Products,2010,30(02):11-16. |
[37] | 马贺伟,廖学品,王茹,石碧.皮胶原纤维固化单宁膜的制备及其对水溶液中铅和汞的吸附[J].化工学报,2005(10):1907-1911. |
[38] | 焦利敏,廖学品,石碧.胶原纤维固载铁对电镀废水中Cr(Ⅵ)的吸附[J].工业水处理,2008(09):17-20. |
[39] | 廖学品,张米娜,王茹,石碧.制革固体废弃物的吸附特性[J].化工学报,2004(12):2051-2059. |
[40] | 李琛.农林废弃物对废水中铬去除的研究进展[J].电镀与精饰,2013(07):12-19,34. |
[41] | 梁鹏,许娄金,柏松,谢鸣.农林废弃物对废水中铜离子吸附过程的研究[J].西南民族大学学报(自然科学版),2012(02):263-268. |
[42] | 于明革,陈英旭.茶废弃物对溶液中重金属的生物吸附研究进展[J].应用生态学报,2010(02):505-513. |
[43] | 李荣华,张院民,张增强,孟昭福,唐次来.农业废弃物核桃壳粉对Cr(Ⅵ)的吸附特征研究[J].农业环境科学学报,2009(08):1693-1700. |
[44] | 李荣华,张增强,孟昭福,李红艳.玉米秸秆对Cr(Ⅵ)的生物吸附及热力学特征研究[J].环境科学学报,2009(07):1434-1441. |
[45] | 官章琴,金春姬,方迪.松果粉末对废水中Cr(Ⅵ)的吸附特性研究[J].河南科学,2010(03):281-284. |
[46] | Li Kebin;Wang Qinqin;Dang Yan et al.Characteristic and mechanism of Cr(Ⅵ)biosorption by buckwheat hull from aqueous solutions[J].Acta Chimica Sinica,2012,70(07):929-937. |
[47] | 周显宏,杨倩倩,余以刚,王励申,朱丹.豆皮对重金属离子Cr(Ⅵ)的吸附性能的研究[J].东莞理工学院学报,2010(05):69-73. |
[48] | 戚建华,梁宗锁,邓西平,姚增玉.板栗壳吸附Cu2+的平衡与动力学研究及工艺设计[J].环境科学学报,2009(10):2141-2147. |
[49] | Zhang Caifeng;Wang Jinlin;Bai yingqi .Study on ad-sorption performance of humicacid on Pb(Ⅱ),Ni(Ⅱ),Cr(Ⅵ)[D].Taiyuan:Taiyuan Normal University,2009. |
[50] | Zhang Jingyi;Liang Jing;Fang Hailan et al.Adsorp-tion-desorption Cu2+ by several amelioration materials[J].Journal of Agro-Environment Science,2013,32(02):274-281. |
[51] | 张峰,陈宇岳,张德锁,华琰蓉,赵兵.端氨基超支化聚合物及其季铵盐的制备与性能[J].高分子材料科学与工程,2009(08):141-144. |
[52] | 强涛涛,王学川,任龙芳.端氨基超支化聚合物的研究进展[J].皮革化工,2007(02):17-21,44. |
[53] | Kim Y H;Webster O W .Hyperbranched polypheny-lenes[J].Macromolecules,1992,25(21):5561-5572. |
[54] | Ishida Y.;Jikei M.;Kakimoto M.;Sun ACF. .Synthesis of hyperbranched aromatic polyamides starting from dendrons as AB(x) monomers: Effect of monomer multiplicity on the degree of branching[J].Macromolecules,2000(8):2832-2838. |
[55] | Liu CH;Gao C;Yan DY .Synergistic supramolecular encapsulation of amphiphilic hyperbranched polymer to dyes[J].Macromolecules,2006(23):8102-8111. |
[56] | Taotao Qiang;Min Luo;Qiaoqiao Bu.Adsorption of an acid dye on hyperbranched aminated collagen fibers[J].Chemical engineering journal,2012:343-349. |
[57] | 王学川,何林燕,强涛涛,袁绪政,李震.整代树状聚酰胺-胺的制备及在Cr(Ⅲ)处理中的应用[J].中国皮革,2009(23):28-32. |
[58] | Ma Fang;Qu Rongjun;Sun Changmei et al.Adsorp-tion behaviors of Hg(Ⅱ)on chitosan functionalized by amino-terminated hyperbranchedpolyamidoamine poly-mers[J].Journal of Hazardous Materials,2009,172(2-3):792-801. |
[59] | 李国平,罗运军,徐厚才,崔艳霞,谭惠民.银离子与聚酰胺-胺型树形高分子配位作用的研究[J].无机化学学报,2003(11):1212-1216. |
[60] | 李慧芝,翟殿棠,寿崇琦,赵淑英,魏琴.超支化聚合物吸附金、铂和钯及化学光谱行为的研究[J].光谱学与光谱分析,2006(09):1724-1727. |
[61] | Liu P;Zhang LX .Hyperbranched aliphatic polyester modified activated carbon particles with homogenized surface groups[J].Surface review and letters,2007(6):1025-1032. |
[62] | Feng Yuanchun;Huang Xin;Wang Yanping et al.Ad-sorptive removal of Cu2+ in aqueous solution using silica grafted with bayberry tannin[J].Leather Science and Engineering,2010,20(02):10-15. |
[63] | Peng Liu;Tingmei Wang .Adsorption properties of hyperbranched aliphatic polyester grafted attapulgite towards heavy metal ions[J].Journal of hazardous materials,2007(1):75-79. |
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