能源危机和环境污染不断加剧，开发绿色、高效的电化学储能器件迫在眉睫。由于锂具有很高的能量密度，锂系二次电池包括锂离子电池、锂硫电池和锂空电池等得到广泛研究和快速发展；而碳基材料是锂系二次电池重要的电极材料和关键组分。石墨烯是“至柔至薄”的碳基材料，良好的力学、热学、电学性能以及高比表面积和柔性片状的结构特征使其在锂系二次电池中展示出很大的应用潜力；作为其它 sp2杂化碳基材料的基本结构单元，石墨烯的出现也为构建高性能的新型碳电极材料提供了契机。评述了不同结构形貌的石墨烯基材料在锂系二次电池中的研究进展，并对目前存在的问题和下一步的工作方向进行了分析与展望。
Clean and efficient electrochemical energy storage and conversion devices are urgently required due to the aggravating energy and environmental problems.The lithium-based rechargeable batteries including lithi-um-ion,lithium-sulfur and lithium-air batteries have attracted much attention for lithium possessing the ex-tremely high energy density,while the carbonaceous materials play a vital role as carbon electrodes or key com-ponents for noncarbon electrodes in these batteries.With the unique structure of single-layer thickness with close-packed conj ugated hexagonal lattices,graphene possesses huge specific surface area,excellent mechanical, thermal and electrical properties,inherent flexibility and chemical stability.Meanwhile,some novel carbon based high performance electrode materials can be designed and assembled with graphenes which are used as the basic unit for various sp2 carbons.Therefore,graphene-based materials with well-controlled nanostructure show great potentials in lithium-based rechargeable batteries.The progresses of the related studies and applica-tions are summarized and the challenges and prospects are also commented and discussed.
参考文献
| [1] | Liu Chang;Li Feng;Ma Laipeng et al.Advanced mate-rials for energy storage[J].Advanced Energy Materials,2010,22:E28-E62. |
| [2] | 杨全红."梦想照进现实"--从富勒烯、碳纳米管到石墨烯[J].新型炭材料,2011(01):1-4. |
| [3] | Geim AK;Novoselov KS .The rise of graphene[J].Nature materials,2007(3):183-191. |
| [4] | Novoselov K S;Geim A K;Morozov S V et al.Electric field effect in atomically thin carbon films[J].Science,2004,306:666-669. |
| [5] | Novoselov K S;Falko V I;Colombo L et al.A roadmap for graphene[J].Nature,2012,490:192-200. |
| [6] | Kim Y A;Takuya H;Kim J H et al.Important roles of graphene edges in carbon-based energy storage devices[J].Journal of Energy Chemistry,2013,22:183-194. |
| [7] | Guoxiu Wang;Xiaoping Shen;Jane Yao .Graphene nanosheets for enhanced lithium storage in lithium ion batteries[J].Carbon,2009(8):2049-2053. |
| [8] | Takai K;Suzuki T;Enoki T et al.Structure and mag-netic properties of curved graphene networks and the effects of bromine and potassium adsorption[J].Physical Review B,2010,81:205420. |
| [9] | Peichao Lian;Xuefeng Zhu;Shuzhao Liang;Zhong Li;Weishen Yang;Haihui Wang .Large reversible capacity of high quality graphene sheets as an anode material for lithium-ion batteries[J].Electrochimica Acta,2010(12):3909-3914. |
| [10] | Lv, W.;Tang, D.-M.;He, Y.-B.;You, C.-H.;Shi, Z.-Q.;Chen, X.-C.;Chen, C.-M.;Hou, P.-X.;Liu, C.;Yang, Q.-H. .Low-temperature exfoliated graphenes: Vacuum-promoted exfoliation and electrochemical energy storage[J].ACS nano,2009(11):3730-3736. |
| [11] | Yoo E;Kim J;Hosono E;Zhou H;Kudo T;Honma I .Large reversible Li storage of graphene nanosheet families for use in rechargeable lithium ion batteries[J].Nano letters,2008(8):2277-2282. |
| [12] | Yin, S.;Niu, Z.;Chen, X. .Assembly of graphene sheets into 3D macroscopic structures[J].Small,2012(16):2458-2463. |
| [13] | Wei Lv;Zhangxun Xia;Sida Wu .Conductive graphene-based macroscopic membrane self-assembled at a liquid-air interface[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2011(10):3359-3364. |
| [14] | Chengmeng Chen;Quan-Hong Yang;Yonggang Yang;Wei Lv;Yuefang Wen;Peng-Xiang Hou;Maozhang Wang;Hui-Ming Cheng .Self-Assembled Free-Standing Graphite Oxide Membrane[J].Advanced Materials,2009(29):3007-3011. |
| [15] | Dan Li;Richard B. Kaner .Graphene-Based Materials[J].Science,2008(5880):1170-1171. |
| [16] | Li Shisheng;Luo Yanhong;Lv Wei et al.Vertically aligned carbon nanotubes grown on graphene paper as e-lectrodes in lithium-ion batteries and dye-sensitized solar cells[J].Advanced Energy Materials,2011,1:486-490. |
| [17] | Haiqun Chen;Marc B. Mueller;Kerry J. Gilmore;Gordon G. Wallace;Dan Li .Mechanically Strong, Electrically Conductive, and Biocompatible Graphene Paper[J].Advanced Materials,2008(18):3557-3561. |
| [18] | Li, N.;Chen, Z.;Ren, W.;Li, F.;Cheng, H.-M. .Flexible graphene-based lithium ion batteries with ultrafast charge and discharge rates[J].Proceedings of the National Academy of Sciences of the United States of America,2012(43):17360-17365. |
| [19] | Luo, B.;Liu, S.;Zhi, L. .Chemical approaches toward graphene-based nanomaterials and their applications in energy-related areas[J].Small,2012(5):630-646. |
| [20] | Minghui Liang;Linjie Zhi .Graphene-based electrode materials for rechargeable lithium batteries[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2009(33):5871-5878. |
| [21] | Chen, X.-C.;Wei, W.;Lv, W.;Su, F.-Y.;He, Y.-B.;Li, B.;Kang, F.;Yang, Q.-H. .A graphene-based nanostructure with expanded ion transport channels for high rate Li-ion batteries[J].Chemical communications,2012(47):5904-5906. |
| [22] | Yang Shubin;Zhi Linjie;Tang Kun et al.Efficient synthesis of heteroatom (N or S)-doped graphene based on ultrathin graphene oxide-porous silica sheets for oxy-gen reduction reactions[J].Advanced Functional Mate-rials,2012,22:3634-3640. |
| [23] | Wu, Z.-S.;Ren, W.;Xu, L.;Li, F.;Cheng, H.-M. .Doped graphene sheets as anode materials with superhigh rate and large capacity for lithium ion batteries[J].ACS nano,2011(7):5463-5471. |
| [24] | Yao, Y.;McDowell, M.T.;Ryu, I.;Wu, H.;Liu, N.;Hu, L.;Nix, W.D.;Cui, Y. .Interconnected silicon hollow nanospheres for lithium-ion battery anodes with long cycle life[J].Nano letters,2011(7):2949-2954. |
| [25] | Bin Luo;Bin Wang;Xianglong Li;Yuyingjia;Minghui Liang;Linjie Zhi .Graphene-Confined Sn Nanosheets with Enhanced Lithium Storage Capability[J].Advanced Materials,2012(26):3538-3543. |
| [26] | Wang, H.;Cui, L.-F.;Yang, Y.;Sanchez Casalongue, H.;Robinson, J.T.;Liang, Y.;Cui, Y.;Dai, H. .Mn_3O_4-graphene hybrid as a high-capacity anode material for lithium ion batteries[J].Journal of the American Chemical Society,2010(40):13978-13980. |
| [27] | Jie Fan;Tao Wang;Chengzhong Yu;Bo Tu;Zhiyu Jiang;Dongyuan Zhao .Ordered, Nanostructured Tin-Based Oxides/Carbon Composite as the Negative-Electrode Material for Lithium-Ion Batteries[J].Advanced Materials,2004(16):1432-1436. |
| [28] | Chen Zhongxue;Zhou Min;Cao Yuliang et al.In situ generation of few-layer graphene coatings on SnO2-SiC core-shell nanoparticles for high-performance lithium-ion storage[J].Advanced Energy Materials,2012,2:95-102. |
| [29] | Zhou Jisheng;Song Huaihe;Ma Lulu et al.Magnetite/graphene nanosheet composites:interfacial interaction and its impact on the durable high-rate performance in lithium-ion batteries[J].RSC Advances,2011,1:782-791. |
| [30] | Wu Zhongshuai;Zhou Guangmin;Yin Lichang et al.Graphene/metal oxide composite electrode materials for energy storage[J].Nano Energy,2012,1:107-131. |
| [31] | Liu, N.;Wu, H.;McDowell, M.T.;Yao, Y.;Wang, C.;Cui, Y. .A yolk-shell design for stabilized and scalable Li-ion battery alloy anodes[J].Nano letters,2012(6):3315-3321. |
| [32] | Bin Luo;Bin Wang;Minghui Liang;Jing Ning;Xianglong Li;Linjie Zhi .Reduced Graphene Oxide-Mediated Growth of Uniform Tin-Core/Carbon-Sheath Coaxial Nanocables with Enhanced Lithium Ion Storage Properties[J].Advanced Materials,2012(11):1405-1409. |
| [33] | Wei Lv;Ying Tao;Wang Ni .One-pot self-assembly of three-dimensional graphene macroassemblies with porous core and layered shell[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2011(33):12352-12357. |
| [34] | Goodenough, J.B.;Park, K.-S. .The Li-ion rechargeable battery: A perspective[J].Journal of the American Chemical Society,2013(4):1167-1176. |
| [35] | Yan-Bing He;Feng Ning;Baohua Li;Quan-Sheng Song;Wei Lv;Hongda Du;Dengyun Zhai;Fangyuan Su;Quan-Hong Yang;Feiyu Kang .Carbon coating to suppress the reduction decomposition of electrolyte on the Li_4Ti_5O_(12) electrode[J].JOURNAL OF POWER SOURCES,2012(Mar.15):253-261. |
| [36] | He Yanbing;Li Baohua;Liu Ming et al.Gassing in Li4 Ti5 O12-based batteries and its remedy[J].Scientific Reports,2012,2:1-9. |
| [37] | J.B. Goodenough;Youngsik Kim .Challenges for rechargeable batteries[J].Journal of Power Sources,2011(16):6688-6694. |
| [38] | Yan-Bing He;Feng Ning;Quan-Hong Yang;Quan-Sheng Song;Baohua Li;Fangyuan Su;Hongda Du;Zhi-Yuan Tang;Feiyu Kang .Structural and thermal stabilities of layered Li(Ni_(1/3)Co_(1/3)Mn_(1/3))O_2 materials in 18650 high power batteries[J].Journal of Power Sources,2011(23):10322-10327. |
| [39] | Zhang B;Yu Y;Liu Y et al.Percolation threshold of graphene nanosheets as conductive additives in Li4Ti5O12 anodes of Li-ion batteries[J].Nanoscale,2013,5:2100-2106. |
| [40] | Fang-Yuan Su;Conghui You;Yan-Bing He .Flexible and planar graphene conductive additives for lithium-ion batteries[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(43):9644-9650. |
| [41] | Wei Wei;Wei Lv;Ming-Bo Wu.The effect of graphene wrapping on the performance of LiFePO4 for a lithium ion battery[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:530-533. |
| [42] | J.I.Martinez;I.Cabria;M.J.Lopez .Adsorption of Lithium on Finite Graphitic Clusters[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(3):939-941. |
| [43] | Su, F.-Y.;He, Y.-B.;Li, B.;Chen, X.-C.;You, C.-H.;Wei, W.;Lv, W.;Yang, Q.-H.;Kang, F. .Could graphene construct an effective conducting network in a high-power lithium ion battery?[J].Nano Energy,2012(3):429-439. |
| [44] | Junghoon Kim;Dong-Ju Lee;Hun-Gi Jung;Yang-Kook Sun;Jusef Hassoun;Bruno Scrosati .An Advanced Lithium-Sulfur Battery[J].Advanced functional materials,2013(8):1076-1080. |
| [45] | Wei Shezhi;Li Weiyang;Cha Judy J et al.Sulphur-TiO2 yolk-shell nanoarchitecture with internal void space for long-cycle lithium-sulphur batteries[J].Nature Communications,2013,4:1331-1331. |
| [46] | Ji, L.;Rao, M.;Zheng, H.;Zhang, L.;Li, Y.;Duan, W.;Guo, J.;Cairns, E.J.;Zhang, Y. .Graphene oxide as a sulfur immobilizer in high performance lithium/sulfur cells[J].Journal of the American Chemical Society,2011(46):18522-18525. |
| [47] | Chaohe Xu;Binghui Xu;Yi Gu;Zhigang Xiong;Jing Sun;X. S. Zhao .Graphene-based electrodes for electrochemical energy storage[J].Energy & environmental science: EES,2013(5):1388-1414. |
| [48] | Zhou, G.;Yin, L.-C.;Wang, D.-W.;Li, L.;Pei, S.;Gentle, I.R.;Li, F.;Cheng, H.-M. .Fibrous hybrid of graphene and sulfur nanocrystals for high-performance lithium-sulfur batteries[J].ACS nano,2013(6):5367-5375. |
| [49] | Xin, S.;Gu, L.;Zhao, N.-H.;Yin, Y.-X.;Zhou, L.-J.;Guo, Y.-G.;Wan, L.-J. .Smaller sulfur molecules promise better lithium'sulfur batteries[J].Journal of the American Chemical Society,2012(45):18510-18513. |
| [50] | Shrikant C. Nagpure;R. Gregory Downing;Bharat Bhushan;S. S. Babu;Lei Cao .Neutron depth profiling technique for studying aging in Li-ion batteries[J].Electrochimica Acta,2011(13):4735-4743. |
| [51] | Xiao, J.;Mei, D.;Li, X.;Xu, W.;Wang, D.;Graff, G.L.;Bennett, W.D.;Nie, Z.;Saraf, L.V.;Aksay, I.A.;Liu, J.;Zhang, J.-G. .Hierarchically porous graphene as a lithium-air battery electrode[J].Nano letters,2011(11):5071-5078. |
| [52] | Yoo, E.;Zhou, H. .Li-air rechargeable battery based on metal-free graphene nanosheet catalysts[J].ACS nano,2011(4):3020-3026. |
| [53] | Li, Y.;Wang, J.;Li, X.;Geng, D.;Li, R.;Sun, X. .Superior energy capacity of graphene nanosheets for a nonaqueous lithium-oxygen battery[J].Chemical communications,2011(33):9438-9440. |
| [54] | Drew Higgins;Zhu Chen;Dong Un Lee .Activated and nitrogen-doped exfoliated graphene as air electrodes for metal-air battery applications[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,2013(7):2639-2645. |
| [55] | Yoo E;Nakamura J;Zhou Haoshen .N-doped graphene nanosheets for Li-air fuel cells under acidic conditions[J].Energy &Environmental Science,2012,5:6928-6932. |
| [56] | Yang Yin;Shi Min;Li Yuesheng et al.MnO2-gra-phene composite air electrode for rechargeable Li-air bat-teries[J].Journal of the Electrochemical Society,2012,159:A1917-A1921. |
| [57] | Hee-Dae Lim;Hyeokjo Gwon;Haegyeom Kim;Sung-Wook Kim;Taeho Yoon;Jang Wook Choi;Seung M. Oh;Kisuk Kang.Mechanism of Co_3O_4/graphene catalytic activity in Li-O_2 batteries using carbonate based electrolytes[J].Electrochimica Acta,2013:63-70. |
| [58] | Wang Long;Zhao Xin;Lu Yuhao et al.CoMn2 O4 spi-nel nanoparticles grown on graphene as bifunctional cata-lyst for lithium-air batteries[J].Journal of the Electro-chemical Society,2011,158:A1379-A1382. |
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