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阐述了两种真空法制备铜铟镓硒(CIGS)薄膜的工艺原理和工艺过程,比较和分析了两工艺的优缺点;介绍了溅射靶材的熔融铸造法和粉末冶金法,列举了靶材制备中所需的温度、压强、保温时间等参数.最后分析认为,用均匀细小的黄铜矿相CIGS粉末压制烧结成四元靶材,经溅射成膜后退火处理,可制备出优异的CIGS薄膜,具有更广阔的应用前景.

参考文献

[1] Repins I;Contreras MA;Egaas B;DeHart C;Scharf J;Perkins CL;To B;Noufi R .19.9%-efficient ZnO/CdS/CuInGaSe2 solar cell with 81.2% fill factor[J].Progress in photovoltaics,2008(3):235-239.
[2] Jackson P;Hariskos D;Lotter E et al.New world record efficiency for Cu(In,Ga)Se2 thin-film solar cells beyond 20 %[J].Progress in Photovoltaics:Research and Applications,2011,19:894897.
[3] M. Lammer;R. Kniese;M. Powalla .In-line deposited Cu(In,Ga)Se_2 solar cells: influence of deposition temperature and Na co-evaporation on carrier collection[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2004(3):175-178.
[4] Chang Jen Chuan;Chuang Chia-Chih;Guo Jhe-Wei et al.An investigation of CuInGaSe2 thin film solar cells by using CuInGa precursor[J].Nanoscience and Nanotechnology Letters,2011,3:200203.
[5] Bhattacharya, R.N.;Oh, M.-K.;Kim, Y..CIGS-based solar cells prepared from electrodeposited precursor films[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2012:198-202.
[6] Alexander R. Uhl;Yaroslav E. Romanyuk;Ayodhya N. Tiwari .Thin film Cu(In,Ga)Se_2 solar cells processed from solution pastes with polymethyl methacrylate binder[J].Thin Solid Films,2011(21):7259-7263.
[7] Seong Yeon KIM;JunHo KIM .Fabrication of CIGS Thin Films by Using Spray Pyrolysis and Post-selenization[J].Journal of the Korean Physical Society,2012(12):2018-2024.
[8] Kessler F;Herrmann D;Powalla M .Approaches to flexible CIGS thin-film solar cells[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2005(0):491-498.
[9] 张维佳,王天民,糜碧,洪轲.纳米ITO粉末及高密度ITO靶制备工艺的研究现状[J].稀有金属材料与工程,2004(05):449-453.
[10] Zhang Ning;Zhuang Da-Ming;Zhang Gong .An investigation on preparation of CIGS targets by sintering process[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2010(1):34-40.
[11] Gabor A M;Tuttle J R;Albin D S et al.High-efficiency CuInxGa1,Se2 solar cells made from (Inx,Ga1 x)2Se3 precursor films[J].Applied Physics Letters,1994,65(02):198-200.
[12] Seike, S.;Shiosaki, K.;Kuramoto, M.;Komaki, H.;Matsubara, K.;Shibata, H.;Ishizuka, S.;Yamada, A.;Niki, S. .Development of high-efficiency CIGS integrated submodules using in-line deposition technology[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2011(1):254-256.
[13] Shigeru N;Contreras M;Repins I et al.CIGS absorbers and process[J].Progress in Photovoltaics:Research and Applications,2010,18:453-466.
[14] Dhere, N.G. .Scale-up issues of CIGS thin film PV modules[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2011(1):277-280.
[15] Kushiya K;Tanaka Y;Hakuma H et al.Interface control to enhance the fill factor over 0.70 in a large-area CIGS-based thin-film PV technology[J].Thin Solid Films,2009,517:2108-2110.
[16] Romeo N;Bosio A;Mazzamuto S.CIGS thin films prepared by sputtering and selenization by using In2Se3,Ga2Se3 and Cu as sputtering targets[A].Hono lulu,2010:786788.
[17] Volobujeva, O;Altosaar, M;Raudoja, J;Mellikov, E;Grossberg, M;Kaupmees, L;Barvinschi, P .SEM analysis and selenization of Cu-In alloy films produced by co-sputtering of metals[J].Solar Energy Materials and Solar Cells,2009(1):11-14.
[18] 韩东麟,张弓,庄大明,沙晟春,元金石.氮气流量对CIGS薄膜结构和形貌的影响[J].功能材料,2008(03):446-448,452.
[19] Chen, G. S.;Yang, J. C.;Chan, Y. C.;Yang, L. C.;Huang, Welson .Another route to fabricate single-phase chalcogenides by post-selenization of Cu-In-Ga precursors sputter deposited from a single ternary target[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2009(8):1351-1355.
[20] Shi J H;Li Z Q;Zhang D W et al.Fabrication of Cu (In,Ga)Se2 thin films by sputtering from a single quaternary chalcogenide target[J].Progress in Photovoltaics:Research and Applications,2011,19:160-164.
[21] 栾和新,庄大明,曹明杰,刘江.磁控溅射法制备CIGS薄膜太阳能电池的工艺及性能研究[J].真空科学与技术学报,2012(08):661-668.
[22] Chia-Hsiang Chen;Wen Chieh Shih;Chih-Yu Chien et al.A promising sputtering route for one-step fabrication of chalcopyrite phase Cu (In,Ga) Se2 absorbers without extra Se supply[J].Solar Energy Materials and Solar Cells,2012,103:2529.
[23] J.A. Frantz;R.Y. Bekele;V.Q. Nguyen;J.S. Sanghera;A. Bruce;S.V. Frolov;M. Cyrus;I.D. Aggarwal .Cu(In,Ga)Se_2 thin films and devices sputtered from a single target without additional selenization[J].Thin Solid Films,2011(22):7763-7765.
[24] Rampino S;Bissoli F;Gilioli E et al.Growth of Cu(In,Ga)Se2 thin films by a novel single-stage route based on pulsed electron deposition[EB/OL].http://onlinelibrary.wiley.com/doi/10.1002/pip.1234/pdf,2011.
[25] 小田淳一 .Cu-In-Ga-Se四元合金溅镀靶的制造方法[P].日本:特开2008-163367,2008-07-17.
[26] 生泽正克;高见英生;田村友哉 .Cu-Ga系溅镀靶、该靶之制造方法、光吸收层及使用该光吸收层之太阳电池[P].台湾专利:TW201126003Al,2011-08-01.
[27] C. Suryanarayana;E. Ivanov;R. Noufi;M. A. Contreras;J. J. Moore .Synthesis and processing of a Cu-In-Ga-Se sputtering target[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1998(1/2):340-344.
[28] Tamura T;Takami H;Masaru S .Cu-In-Ga-Se quaternary alloy sputtering target[P].USP:0205242A1,2012-08-16.
[29] 王东生;黄开盛;龙 飞 等.太阳能电池铜铟镓硒薄膜关键靶材的制备方法[P].中国发明专利:CN101260513,2011-04-06.
[30] 付耀贤;黄文启;周邦彦 等.CIS系粉末的制作方法及其靶材的制作方法[P].中国发明专利:CN101519307A,2009-09-02.
[31] 周继承;巩小亮;黄迪辉 .一种CIGS粉末、靶材、薄膜及其制备方法[P].中国发明专利:CN101613091A,2009-12-30.
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