研究两种不同成分具有较大过冷液相区的四元合金Zr65Al7.5Ni10Cu17.5和Zr65Al10Ni10Cu15非晶和晶态薄带吸氢行为,结果表明两种薄带的吸氢量均随着温度的升高而增大,非晶薄带的吸氢量要小于同等条件下的晶态薄带的吸氢量且只有在673K吸氢后形成了氢化物,Zr65Al7.5Ni10Cu17.5非晶和晶态薄带吸氢后分别生成了Zr2NiH4.7和ZrH2;而Zr65Al10Ni10Cu15非晶和晶态两种薄带最后生成的氢化物同为ZrH2.
参考文献
| [1] | A Inoue;T.Zhang;Masumoto .Al-La-Cu Amorphous Alloys with A Wide Supercooled Liquid Region[J].Materials Transactions,1990,30:104-109. |
| [2] | A Inoue .Nanocrystalline Soft Magnetic Alloys with Zero Magnetostriction in Fe-Zr-Al and Fe-Zr-Si Base Systems[J].Materials Science Forum,1996,225:639-648. |
| [3] | A Inoue;T Zhang;T Masumoto .Reductilization of Embrittled La-Al-Ni Amorphous Alloys by Viscous Flow Deformation in A Supercooled Liquid Region[J].Journal of Non Crystalline,1993,156:598-602. |
| [4] | F Sommer;G Schluckebier .Hydrogen in Amorphous Metals[J].ACTA MATERIALIA,1982,30:1059-1068. |
| [5] | D Menzel;A Niklas;U Koster .Hydrogen in Titanium-based Metallic Glasses[J].Materials Science and Engineering,1991,133:312-315. |
| [6] | S Fujitani;H Nakamura;A Furukawa;K.Nasako, K.Satoh, T.Imoto, T.Saito, I.Yonezu .Development of Hydrogen-absorbing Rare Earth-Ni alloys for A -20 °C Refrigeration System[J].Journal of Alloys and Compounds,1993,192:170-172. |
| [7] | Li X.G.;Otahara T. .Hydrogen absorption and corresponding changes in structure and thermal stability of Zr_(60)Al_(10)Ni_(30) amorphous alloy[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):303-311. |
| [8] | Nam Hoo Goo;Kyung Sub Lee .The electrochemical hydriding properties of Mg-Ni-Zr amorphous alloy[J].International journal of hydrogen energy,2002(4):433-438. |
| [9] | T.Shoji;A.Inoue .Hydrogen absorption and desorption behavior of Zr- based amorphous alloys with a large structurally relaxed amorphous region[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(1/2):275-280. |
| [10] | Gebert A;Eckert J;Schultz L .Effect of Oxygen on Phase Formation and Thermal Stability of Slowly Cooled Zr65Al7.5 Cu17.5Ni10 Metalllic Glass[J].Acta Materialia,1998,46:5475-5482. |
| [11] | Eckert J;Mattern N;Zinkevitch M;Seidel M .Crystallization Behavior and Phase Frmation in Zr-Al-Cu-Ni Metallic Glass Containing Oxygen[J].Materials Transactions,1998,39:623-632. |
| [12] | Inoue A;Kawase D;Tsai A P;Zhang T, Masumoto T .Stability and Transformation to Crystalline Phases of Amorphous Zr-Al-Cu Alloys with Signification Supercooled Liquid Region[J].Materials Science and Engineering,178:255-263. |
| [13] | K Aoki;M.Kamachi;T.Masumoto .Practical Method for Decentralized V-Q Control[J].Journal of Non-Crystalline Solids,1984,679:61-62. |
| [14] | A J Maeland;L E Tanner;G G Libowitz .Hydrides of Metallic Glass Alloys[J].Journal of the Less-Common Metals,1980,74:279-285. |
| [15] | K Suzuki .Properties of Microcrystalline P Doped Si:H Films[J].Journal of Non-Crystalline Solids,1983,59:827-830. |
| [16] | R C Bowman .Density of Trapped Gas in Heavily-irradiated Lithium Hydride[J].Journal of Nuclear Materials,1988,154:318-331. |
| [17] | R Kirchheim .Solubility,Diffusivity and Trapping of Hydrogen in Dilute Alloys,Defformed and Amorphous Metals-2[J].Acta Metallurgy,1982,30:1069-1078. |
| [18] | F. Cuevas;M. Hirscher .Hydrogen solubility and diffusivity in amorphous La_(14)Ni_(86) films[J].Acta materialia,2003(3):701-712. |
| [19] | J Garaguly;A Lovas;K Tompa;J.Takacs, Varga.L.K .Hydrogen Uptake Monitored by Resistance Change in Amorphous Zr33Ni67 Alloy[J].Hydrogen Energy Progress,1996,21:1039-1040. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%