酚醛树脂是一种传统的合成树脂,在诸多行业有着广泛的应用.提高酚醛树脂的耐热性一直是业内研究的热点.系统介绍了国内外提高酚醛树脂耐热性所采取的改性方法,以及所取得的研究成果.提出了今后酚醛树脂耐热改性的主要研究方向是进一步提高PF在400~700℃时的结构热稳定性,并开发出良好的改性剂组合、优化热处理工艺,使酚醛树脂分别在低、中、高温区均具有较稳定的结构与性能.
参考文献
[1] | 薛斌,张兴林.酚醛树脂的现代应用及发展趋势[J].热固性树脂,2007(04):47-50. |
[2] | ZHANG Y;XU Y;GAO L et al.Preparation and microstruetural evolution of carbon/carbon composites[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,2006,430(1-2):9-14. |
[3] | Tzeng SS.;Chr YG. .Evolution of microstructure and properties of phenolic resin-based carbon/carbon composites during pyrolysis[J].Materials Chemistry and Physics,2002(2/3):162-169. |
[4] | 张亚妮,徐永东,高列义,张立同,成来飞.基于酚醛树脂的碳/碳复合材料在高温分解过程的微结构演变[J].复合材料学报,2006(01):37-43. |
[5] | H. J. Kim;Z. Brunovska;H. Ishida .Synthesis and thermal characterization of polybenzoxazines based on acetylene-functional monomers[J].Polymer: The International Journal for the Science and Technology of Polymers,1999(23):6565-6573. |
[6] | FITZER E .The future of carbon-carbon composites[J].CARBO,1987,25(02):163-190. |
[7] | KOOJ H;STRETZ H;BRAY A.Nanocomposite rocket ablative materials:processing,characterization,and performance[A].Long Beach:SAMPE,2003:1156-1170. |
[8] | GARDZIELLA A;SUREN J.Phenolic resins as impregnating agents for refractories-present state of development[A].New Orleans:American Ceramic Society,1997:975-998. |
[9] | C.P.Reghunadhan Nair .Advances in addition-cure phenolic resins[J].Progress in Polymer Science,2004(5):401-498. |
[10] | 张俊华,李锦文,魏化震,齐风杰,邹秀娥.高性能酚醛树脂基烧蚀复合材料的研究[J].纤维复合材料,2009(01):15-18,23. |
[11] | KOO J H;STRETZ H;BRAY A.Phenolic-clay nanocomposites for rocket propulsion system[A].Long Beach:SAMPE,2002:1085-1099. |
[12] | Wang, DC;Chang, GW;Chen, Y .Preparation and thermal stability of boron-containing phenolic resin/clay nanocomposites[J].Polymer Degradation and Stability,2008(1):125-133. |
[13] | Jigang Wang;Quangui Guo;Lang Liu;Jinren Song .The preparation and performance of high-temperature adhesives for graphite bonding[J].International Journal of Adhesion & Adhesives,2005(6):495-501. |
[14] | Jigang Wang;Haiyun Jiang;Quangui Guo .High-Temperature Joining of Carbon/Carbon Composites by an Organic Resin Adhesive[J].Journal of Adhesion Science and Technology: The International Journal of Theoredtical and Basic Aspects of Adhesion Science and Its Applications in All Areas of Technology,2009(1):115-123. |
[15] | 林荣会,郗英欣,邵艳霞,方亮.纳米铜改性酚醛树脂及其应用性能[J].复合材料学报,2004(06):114-118. |
[16] | U. S. Hong;S. L. Jung;K. H. Cho;M. H. Cho;S. J. Kim;H. Jang .Wear mechanism of multiphase friction materials with different phenolic resin matrices[J].Wear,2009(7/8):739-744. |
[17] | C.S. Tyberg;M. Sankarapandian;K. Bears;P. Shih .Tough, void-free, flame retardant phenolic matrix materials[J].Construction and Building Materials,1999(6):343-353. |
[18] | Tyberg CS.;Sankarapandian M.;Shih P.;Loos AC.;Dillard DA. McGrath JE.;Riffle JS.;Sorathia U.;Bergeron K. .Structure-property relationships of void-free phenolic-epoxy matrix materials[J].Polymer: The International Journal for the Science and Technology of Polymers,2000(13):5053-5062. |
[19] | Sugihara S.;Ohtsuka H.;Yamaki J.;Okada S. .EFFECTS OF THE SURFACE STATE OF PLASTICS ON ADHESIVE STRENGTH IN ELECTROLESS PLATING[J].Journal of Applied Polymer Science,1996(11):1751-1758. |
[20] | TAKAKAZU N;YUKIO M .Thermosetting resin composition[P].JP Patent:JP63289055,1988-11-25. |
[21] | 伊廷会.高性能酚醛树脂改性研究进展[J].化工进展,2001(09):13-16. |
[22] | Ikeda R.;Tanka H.;Uyama H.;Kobayashi S. .Synthesis and curing behaviors of a crosslinkable polymer from cashew nut shell liquid[J].Polymer: The International Journal for the Science and Technology of Polymers,2002(12):3475-3481. |
[23] | DIRLIKOV S K .Propargy-terminated resins,a hydrophobic substitute for epoxy resins[J].High Performance Polymers,1990,2(01):67-77. |
[24] | Tarek Agag;Tsutomu Takeichi .Novel Benzoxazine Monomers Containing p-Phenyl Propargyl Ether: Polymerization of Monomers and Properties of Polybenzoxazines[J].Macromolecules,2001(21):7257-7263. |
[25] | Nair CPR.;Bindu RL.;Ninan KN. .Addition curable phenolic resins based on ethynyl phenyl azo functional novolac[J].Polymer: The International Journal for the Science and Technology of Polymers,2002(9):2609-2617. |
[26] | C.P. Reghunadhan Nair;R.L. Bindu;K.N. Ninan .Thermal characteristics of addition-cure phenolic resins[J].Polymer Degradation and Stability,2001(2):251-257. |
[27] | Nair CPR.;Bindu RL.;Ninan KN. .Thermal characteristics of propargyl ether phenolic resins[J].Journal of Macromolecular Science. Pure and Applied Chemistry,2003(4):357-369. |
[28] | J. W. Connell;J. G. Smith Jr.;P. M. Hergenrother .Oligomers and Polymers Containing Phenylethynyl Groups[J].Journal of Macromolecular Science.Reviews in Macromolecular Chemistry and Physics,2000(2/3):207-230. |
[29] | 李战雄;王标兵;欧育湘.耐高温聚合物[M].北京:化学工业出版社,2007:42-43. |
[30] | CULBERTSON B M;TIBA O;DEVINEY M L.Bisoxazoline-phenolic resin step-growth copolymerisation:New systems for electronic,mould making and resin transfer molding[A].Reno:SAMPE,1989:2483-2497. |
[31] | 王继刚,郭全贵,刘朗,宋进仁.硅改性酚醛树脂高温粘结部件的粘接强度及导电性能[J].材料工程,2000(08):15-17. |
[32] | Mohamed O.Abdalla;Adriane Ludwick;Temisha Mitchell .Boron-modified phenolic resins for high performance applications[J].Polymer: The International Journal for the Science and Technology of Polymers,2003(24):7353-7359. |
[33] | Martin C;Ronda JC;Cadiz V .Development of novel flame-retardant thermosets based on boron-modified phenol-formaldehyde resins[J].Journal of Polymer Science, Part A. Polymer Chemistry,2006(11):3503-3512. |
[34] | 杜杨,吉法祥,刘祖亮,吕春绪.含硼硅酚醛树脂BSP的合成和性能[J].高分子材料科学与工程,2003(04):44-47. |
[35] | Liu YF.;Gao JG.;Zhang RZ. .Thermal properties and stability of boron-containing phenol-formaldehyde resin formed from paraformaldehyde[J].Polymer Degradation and Stability,2002(3):495-501. |
[36] | MCKEE D W;SPIRO C L;LAMBY E J .The effects of boron additives on the oxidation behavior of carbons[J].CARBO,1984,22(06):507-511. |
[37] | 焦扬声;王幼甫.酚三嗪树脂[J].玻璃钢/复合材料,1994(01):10-13. |
[38] | MIKS M W;SHIGLEY J K .Addition-polymerisation resin system for fibre reinforced nozzle ablative components[P].USA Patent:5645219,1997-07-08. |
[39] | 刘晓洪;苟筱辉 .钼酚醛树脂的结构与耐热性研究[J].化学世界,1998,39(06):314-316. |
[40] | HOLLY F W;COPE A C .Condensation products of aldehydes and ketones with o-aminobenzyl alcohol and o-hydroxybenzylamine[J].Journal of the American Chemical Society,1944,66(11):1875-1879. |
[41] | ISHDA H;ALLEN D J .Rheological characterization during cure of near-zero shrinkage polybenzoxazines[J].Polymeric Materials: Science and Engineering,1995,73:496-497. |
[42] | SHEN S B;ISHIDA H .Development and characterization of high-performance polybenzoxazine composites[J].Polymer Composites,1996,17(05):710-719. |
[43] | N.N.Ghosh;B.Kiskan;Y.Yagci .Polybenzoxazines-New high performance thermosetting resins:Synthesis and properties[J].Progress in Polymer Science,2007(11):1344-1391. |
[44] | Zdenka Brunovska;Hatsuo Ishida .Thermal Study on the Copolymers of Phthalonitrile and Phenylnitrile-Functional Benzoxazines[J].Journal of Applied Polymer Science,1999(14):2937-2949. |
[45] | Agag T.;Takeichi T. .Synthesis and characterization of novel benzoxazine monomers containing allyl groups and their high performance thermosets[J].Macromolecules,2003(16):6010-6017. |
[46] | 李曹,高念,顾宜.苯并恶嗪聚合物耐热性能研究进展[J].化学推进剂与高分子材料,2007(05):8-11. |
[47] | Ishida H.;Low HY. .A STUDY ON THE VOLUMETRIC EXPANSION OF BENZOXAZINE-BASED PHENOLIC RESIN[J].Macromolecules,1997(4):1099-1106. |
[48] | MAHAMUNI S;BENDRE B S;LEPPERT V J et al.ZnO nanoparticles embedded in polymeric matrices[J].Nano-Structured Materials,1996,7(06):659-666. |
[49] | 孙振亚,胡纯,雷绍民,龚文琪.纳米材料改性酚醛树脂合成闸片摩擦性能研究[J].非金属矿,2004(05):51-53. |
[50] | 喻丽华,何林,闫建伟.Al2O3和SiC纳米粒子改性酚醛树脂的热稳定性研究[J].贵州工业大学学报(自然科学版),2007(01):19-21,25. |
[51] | 钱春香,赵洪凯,熊佑明,周效谅,王辉.纳米TiO2粒子改性硼酚醛树脂的热性能分析[J].功能材料,2006(07):1114-1117. |
[52] | Ahmad Reza Bahramian;Mehrdad Kokabi;Mohammad Hossein Beheshty;Mohammad Hossein Navid Famili .Thermal Degradation Process of Resol Type Phenolic Matrix/Kaolinite Layered Silicate Nanocomposite[J].Iranian polymer journal,2007(6):375-387. |
[53] | 章永化,龚克成.有机-无机混杂纳米材料[J].高技术通讯,1995(07):56-59. |
[54] | 王继刚,郭全贵,刘朗,宋进仁.陶瓷改性酚醛树脂粘结剂的耐高温性能[J].机械工程材料,2005(02):24-26. |
[55] | Wang JG;Jiang N;Guo QG;Liu L;Song JR .Study on the structural evolution of modified phenol-formaldehyde resin adhesive for the high-temperature bonding of graphite[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2006(1/2):108-113. |
[56] | WANG J G;JIANG N;JIANG H Y .The high-temperatures bonding of graphite/ceramics by organ resin matrix adhesive[J].International Journal of Adhesion and Adhesives,2006,26(07):532-536. |
[57] | ANIKIN L T;KRARETSKII G T;KUZINA O A .Heat-resistant adhesive for joining of carbon materials[J].Plaste und Kautschuk,1992,39(02):54-56. |
[58] | Masashi Koyama;Hiroshi Hatta;Hiroshi ukuda .Effect of temperature and layer thickness on these strengths of carbon bonding for carbon/carbon composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(1):171-177. |
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