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采用磁过滤直流真空阴极弧沉积技术在单晶硅片、载玻片、不锈钢片基体上制备了含铬类金刚石(Cr-DLC)膜.用光学显微镜、椭偏仪、分光光度计、X射线光电子能谱(XPS)、X射线衍射能谱(XRD)、Raman光谱、纳米硬度计、摩擦磨损仪、洛氏硬度计检测了薄膜的组分结构、光学、力学等相关特性.结果表明,硅片上的薄膜厚度为47.6nm,碳含量为89%,s p~3键占碳含量的55.15%.不锈钢片上的薄膜具有典型的DLC膜Raman光谱特征,在空气中的摩擦系数约为0.1,耐磨性能优良,膜与基体的结合性能良好.

Cr-containing hydrogenated diamond-like carbon (Cr-DLC) films were deposited on stainless steel plate, monocrystalline silicon wafer and microscope slide glass by DC filtered cathodic vacuum arc technology. The composition, structure and properties of Cr-DLC films were investigated by spec-troscopic ellipsometer, X-ray photoelectron spectroscopy(XPS), powder X-ray diffraction(XRD), spectrophotometer, Raman spectroscopy, nanoindenter, ball-on-disk tribometer, Rockwell apparatus and optical microscope. It was shown that the content of C is 89% in the film deposited on silicon wa-fer and the content of sp~3 bonding carbon atoms in the C element is 55.15%. The Raman spectra of the film deposited on stainless steel plate has the typical characteristics of DLC. The hardness and elastic modulus of the film deposited on stainless steel plate are 16.01 GPa and 142.72 GPa. The fric-tion coefficient of the film deposited on stainless steel plate is about 0.1, the film also exhibits excel-lent wear resistance and the adhesion to substrate is very well.

参考文献

[1] DRUZ B;YEVTUKHOV Y .Diamond-like carbon overcoat for TFMH using filtered cathodic arc system with At-assisted arc discharge[J].Diamond and Related Materials,2005,14:1508-1516.
[2] ROBERTSON J .Diamond-like amorphous carbon[J].Materials Science and Engineering,2002,R37:129-281.
[3] ANDREA C F;JOHN R.Raman spectroscopy of amorphous,nanostructured,diamond-like carbon,and nanodiamond[M].The Royal Society,2004:1452.
[4] Paik N .Raman and XPS studies of DLC films prepared by a magnetron sputter-type negative ion source[J].Surface & Coatings Technology,2005(7):2170-2174.
[5] F. Atchison;T. Brys;M. Daum;P. Fierlinger;A. Foelske;M. Gupta;R. Henneck;S. Heule;M. Kasprzak;K. Kirch;R. Kotz;M. Kuzniak;T. Lippert;C.-F. Meyer;F. Nolting;A. Pichlmaier;D. Schneider;B. Schultrich;P. Siemroth;U. Straumann .Structural characterization of diamond-like carbon films for ultracold neutron applications[J].Diamond and Related Materials,2007(2):334-341.
[6] 覃礼钊,张旭,吴正龙.XPS表征类金刚石膜探讨[J].现代仪器,2005(06):18-20.
[7] HUGE O P.Handbook of Carbon,Graphite,Diamond and Fullerenes-Properties,Processing and Applications[M].William Andrew Publishing/Noyes Publications,1993
[8] LI Hongxuan;XU Tao .Annealing effect on the structure,mechanical and tribological properties of hydrogenated diamond-lke carbon films[J].Thin Solid Films,2006,515:2153-2160.
[9] Chen CC;Hong FCN .Interfacial studies for improving the adhesion of diamond-like carbon films on steel[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2005(1/4):296-303.
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