将两种颗粒增韧相与HfB2陶瓷基体按配比混料、热压制备了双相颗粒混杂增韧HfB2陶瓷复合材料,重点研究其高温压缩性能、热膨胀性能、耐烧蚀性能以及显微组织.结果表明,HfB2复合材料的室温压缩性能较高,但高温下压缩性能显著下降.随着温度升高,HfB2复合材料的体积膨胀率单调增加;平均线膨胀系数变化平缓;而瞬时线膨胀系数先减小后增大,有一个最小值,最小瞬时线膨胀系数在900℃,其值为5.65×10-6/K.该复合材料在等离子电弧加热器上烧蚀8s后,部分韧化相熔化飞出,留下孔洞.
参考文献
[1] | 李荣久.陶瓷-金属复合材料[M].北京:冶金工业出版社,2002:61-69. |
[2] | Michael Belyansky;Michael Trenary .Comparison of the surface chemical reactivity of hafnium diboride and hafnium[J].Inorganica Chimica Acta,1999(1/2):191-197. |
[3] | Mark M. Opeka;Inna G. Talmy .Mechanical, Thermal, and Oxidation Properties of Refractory Hafnium and Zirconium Compounds[J].Journal of the European Ceramic Society,1999(13/14):2405-2414. |
[4] | Wang CR.;Yang JM.;Hoffman W. .Thermal stability of refractory carbide/boride composites[J].Materials Chemistry and Physics,2002(3):272-281. |
[5] | MONTEVERDE F;BELLOSI A.Microstructure and properties of an HfB2-SiC composite for ultrahigh temperature applications[J].Advances in Engineering Materials,2004(05):331-336. |
[6] | Gasch M;Ellerby D;Irby E;Beckman S;Gusman M;Johnson S .Processing, properties and arc jet oxidation of hafnium diboride/silicon carbide ultra high temperature ceramics[J].Journal of Materials Science,2004(19):5925-5937. |
[7] | Opila E;Levine S;Lorincz J .Oxidation of ZrB2- and HfB2-based ultra-high temperature ceramics: Effect of Ta additions[J].Journal of Materials Science,2004(19):5969-5977. |
[8] | Wuchina E;Opeka M;Causey S;Buesking K;Spain J;Cull A;Routbort J;Guitierrez-Mora F .Designing for ultrahigh-temperature applications: The mechanical and thermal properties of HfB2, HfCx, HfNx, and alpha Hf(N)[J].Journal of Materials Science,2004(19):5939-5949. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%