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将两种颗粒增韧相与HfB2陶瓷基体按配比混料、热压制备了双相颗粒混杂增韧HfB2陶瓷复合材料,重点研究其高温压缩性能、热膨胀性能、耐烧蚀性能以及显微组织.结果表明,HfB2复合材料的室温压缩性能较高,但高温下压缩性能显著下降.随着温度升高,HfB2复合材料的体积膨胀率单调增加;平均线膨胀系数变化平缓;而瞬时线膨胀系数先减小后增大,有一个最小值,最小瞬时线膨胀系数在900℃,其值为5.65×10-6/K.该复合材料在等离子电弧加热器上烧蚀8s后,部分韧化相熔化飞出,留下孔洞.

参考文献

[1] 李荣久.陶瓷-金属复合材料[M].北京:冶金工业出版社,2002:61-69.
[2] Michael Belyansky;Michael Trenary .Comparison of the surface chemical reactivity of hafnium diboride and hafnium[J].Inorganica Chimica Acta,1999(1/2):191-197.
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[4] Wang CR.;Yang JM.;Hoffman W. .Thermal stability of refractory carbide/boride composites[J].Materials Chemistry and Physics,2002(3):272-281.
[5] MONTEVERDE F;BELLOSI A.Microstructure and properties of an HfB2-SiC composite for ultrahigh temperature applications[J].Advances in Engineering Materials,2004(05):331-336.
[6] Gasch M;Ellerby D;Irby E;Beckman S;Gusman M;Johnson S .Processing, properties and arc jet oxidation of hafnium diboride/silicon carbide ultra high temperature ceramics[J].Journal of Materials Science,2004(19):5925-5937.
[7] Opila E;Levine S;Lorincz J .Oxidation of ZrB2- and HfB2-based ultra-high temperature ceramics: Effect of Ta additions[J].Journal of Materials Science,2004(19):5969-5977.
[8] Wuchina E;Opeka M;Causey S;Buesking K;Spain J;Cull A;Routbort J;Guitierrez-Mora F .Designing for ultrahigh-temperature applications: The mechanical and thermal properties of HfB2, HfCx, HfNx, and alpha Hf(N)[J].Journal of Materials Science,2004(19):5939-5949.
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