使用二次合成法制备了不同钾含量的0.80Pb(Mg1/3Nb2/3)O3-0.20PbTiO3陶瓷,首先研究了掺钾对PMN基预烧粉体和陶瓷试样相组成的影响,在此基础上详细研究了掺钾对PMN基陶瓷有序微区、介电和电致伸缩性能的影响规律.掺钾对PMN基预烧粉体和陶瓷的相组成影响很小;理论计算和Raman散射光谱分析都表明掺钾使PMN基陶瓷的有序微区的尺寸稍微减小;掺钾也小幅度地减小了PMN基陶瓷的介电和电致伸缩性能,最后分析了掺钾降低介电和电致伸缩性能的原因.
参考文献
[1] | J Chen;H M Chan;M P Harmer .Ordering structure and dielectric properties of undoped and La/Na-doped Pb(Mg1/3Nb2/3)O3[J].Journal of the American Ceramic Society,1989,72(04):593-598. |
[2] | A D Hilton;D J Barber;C A Randal .TEM studies of Pb(Mg1/3Nb2/3)O3-PbTiO3 ferroelectric relaxors[J].Ferroelectrics,1989(93):379-386. |
[3] | Kyu-Mann Lee;Hyun M Jang;Woo Jin Park .Mechanism of 1∶1 nonstoichiometric short-range ordering in La-doped Pb(Mg1/2Nb2/3)O3 relaxor ferroelectrics[J].Journal of Materials Research,12(06):1603-1613. |
[4] | Kyu-Mann Lee;Hyun M Jang .Enhanced diffuse phase trsnsition and defect mechanism of Na-doped Pb(Mg1/2Nb2/3)O3 relaxor ferroelectrics[J].Journal of Materials Research,12(06):1614-1624. |
[5] | Kyu-Mann Lee;Hyun M Jang .A new mechanism of nonstoichiometric 1∶1 short-range order in NiO-doped Pb(Mg1/3Nb2/3)O3 relaxor ferroelectrics[J].Journal of the American Ceramic Society,1998,81(10):2586-2596. |
[6] | S L Swartz;T R Shrout .Fabrication of perovskite lead magne-sium niobate[J].Materials Research Bulletin,1982,17(10):1245-1250. |
[7] | O Bidault;E Husson;A Morell .Effects of Vacancies on Spontaneous Relaxor to Ferroelectric Phase Transition in Pb[J].Journal of Applied Physics,1997,82(11):5674-5679. |
[8] | Heike Idink;William B White .Raman spetroscopy study of order-disorder in magnesium niobate[J].Journal of Applied Physics,1994,76(03):1789-1793. |
[9] | I.G.Siny;R.S.Katiyar .Light Scattering and Phase Transition Dynamics in PMN[J].Ferroelectrics,1999(1/4):35-42. |
[10] | Husson E;Abello L;Morell A .Short-range order in Pb (Mg1/3Nb2/3)O3 ceramics by Raman spectroscopy[J].Materials Research Bulletin,1990(25):539-545. |
[11] | Qu Shaobo.The effective ordered micro-region model forLa3+/K+ doped Pb(Mg1/3Nb2/3)O3-typeded relaxor ceramics[J].Ferroelectrics |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%